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TRB Chemistry 2009

2009 · 153 questions · First 10 Solutions Free
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Q1 mcq
Who was the Viceroy of India, when the Rowlatt Act was passed?
a.
Lord Irwin
b.
Lord Chelmsford Correct Answer
c.
Lord Wavell
d.
Lord Wellington
Step-by-Step AI Explanation
Verified Method
The Rowlatt Act was passed in 1919, when Lord Chelmsford was the Viceroy of India. Lord Irwin came later.
Q2 mcq
Which one of the following is the softest?
a.
Sodium Correct Answer
b.
Aluminium
c.
Iron
d.
Lithium
Step-by-Step AI Explanation
Verified Method
Among the given metals, sodium is the softest. It is an alkali metal with very low hardness and can be cut easily with a knife.
Q3 mcq
As a non-member who can participate in the proceedings of either House of Parliament?
a.
Vice-President
b.
Chief Justice
c.
Attorney General Correct Answer
d.
Chief Election Commissioner
Step-by-Step AI Explanation
Verified Method
The Attorney General of India is a non-member who has the right to participate in the proceedings of either House of Parliament, though without voting rights.
Q4 mcq
Which is the river on which Indira Sagar Dam is planned to be constructed?
a.
Mahanadi
b.
Godavari
c.
Krishna
d.
Narmada Correct Answer
Step-by-Step AI Explanation
Verified Method
The Indira Sagar Dam is built on the Narmada River in Madhya Pradesh.
Q5 mcq
The first astronomer who gave the idea, 'The earth rotates on its axis', is
a.
Bhaskara
b.
Aryabhatta Correct Answer
c.
Varahamihira
d.
Kalpana Chawla
Step-by-Step AI Explanation
Verified Method
Aryabhatta is credited with the early idea that the Earth rotates on its axis.
Q6 mcq
Which one of the following angles cannot be constructed using an unmarked ruler and compass only?
a.
75°
b.
90°
c.
50° Correct Answer
d.
22 1/2°
Step-by-Step AI Explanation
Verified Method
Angles like 90°, 75°, and 22.5° can be constructed using standard geometric constructions, but 50° cannot be constructed exactly with only an unmarked ruler and compass.
Q7 mcq
For a frequency polygon, the points are plotted against
a.
mid-point of the class interval vs frequency Correct Answer
b.
lower limit of the class interval vs frequency
c.
upper limit of the class interval vs frequency
d.
real limit of the class interval vs frequency
Step-by-Step AI Explanation
Verified Method
A frequency polygon is drawn by plotting class mid-points on the x-axis against their frequencies on the y-axis.
Q8 mcq
AICTE was established in
a.
November, 1945
b.
November, 1955
c.
November, 1985 Correct Answer
d.
November, 1975
Step-by-Step AI Explanation
Verified Method
AICTE was established in November 1985.
Q9 mcq
One of the main publications of John Dewey is
a.
Secrets of Childhood
b.
Education Today Correct Answer
c.
Education of Man
d.
The Social Contract
Step-by-Step AI Explanation
Verified Method
Education Today is associated with John Dewey among the given options. The Social Contract is by Rousseau, not Dewey.
Q10 mcq
According to David Ausubel, 'Verbal Learning' is
a.
learning a new language
b.
oral practice
c.
understanding verbal information Correct Answer
d.
passive learning experience
Step-by-Step AI Explanation
Verified Method
Ausubel's verbal learning refers to meaningful learning of verbal information, not mere repetition or passive exposure.
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Q11 mcq
The Southern Regional Office of UGC is in
a.
Hyderabad
b.
Bangalore
c.
Chennai
d.
Mumbai
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Q12 mcq
National Population Policy was evolved in the year
a.
1976
b.
1979
c.
1986
d.
1977
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Q13 mcq
According to Abraham Maslow, 'Self-Actualisation' in the hierarchy is
a.
first step
b.
final step
c.
third step
d.
fourth step
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Q14 mcq
Who is the author of 'Emile'?
a.
Dewey
b.
Bertrand Russell
c.
Froebel
d.
Rousseau
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Q15 mcq
The university that has no affiliated colleges is
a.
Madras University
b.
Madurai Kamaraj University
c.
Thanjavur Tamil University
d.
Manonmanium Sundaranar University
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Q16 mcq
Human Rights Day is
a.
December 10
b.
December 7
c.
December 26
d.
July 17
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Q17 mcq
Which one of the following models is not on curriculum development?
a.
The Tylor model
b.
The Ausubel's model
c.
The Taba model
d.
The Hunkin's model
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Q18 mcq
The chief objective of pre-primary education is to promote .................. of the child.
a.
physical development
b.
mental development
c.
social development
d.
overall development
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Q19 mcq
If the teacher finds in learner's activities something new or original, then the child is supposed to be
a.
intelligent
b.
creative
c.
critical
d.
motivated
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Q20 mcq
Which one of the following is not a learning domain?
a.
Cognitive domain
b.
Psychomotor domain
c.
Physiological domain
d.
Affective domain
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Q21 mcq
An example of anthraquinone dye is
a.
alizarin
b.
methyl orange
c.
methylene blue
d.
phenolphthalein
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Q22 mcq
Among the following which one is not the correct match?
a.
Silk - Polyamide
b.
Indigo - Azo dye
c.
Lipase - Ester
d.
Keratin - Protein
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Q23 mcq
Acid rain water contains
a.
acetic acid
b.
sulphuric acid
c.
carbonic acid
d.
nitric acid
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Q24 mcq
The common name of this compound is $\mathrm{(CH_3C=NOH)_2}$
a.
Methyl carboxhydroxide
b.
Dimethyl carbene hydroxide
c.
N-hydroxy 1 methyl ethane
d.
Dimethyl glyoxime
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Q24 mcq
The common name of this compound is
a.
Methyl carbohydroxide
b.
Dimethyl carbene hydroxide
c.
N-hydroxy 1 methyl ethane
d.
Dimethylglyoxime
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Q25 mcq
In human body, carbohydrates are stored as
a.
starch
b.
cellulose
c.
glycogen
d.
fructose
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Q26 mcq
Riboflavin is an example for
a.
Coenzyme
b.
Antacid drug
c.
Nucleoside
d.
Antimicrobial drug
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Q27 mcq
For obtaining golden yellow spangles which reagent is used on a lead salt?
a.
Mercury iodide
b.
Zinc iodide
c.
Potassium iodide
d.
Ammonium iodide
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Q28 mcq
What is the enthalpy change for the reaction $\mathrm{H_2 + I_2 \rightarrow 2HI}$ if the bond energies of H–H, I–I and H–I are 433, 151 and 299 kJ mol$^{-1}$ respectively?
a.
28 kJ
b.
-28 kJ
c.
-14 kJ
d.
14 kJ
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Q29 mcq
Selection rule of rotational spectrum expects transitions between rotational energy levels $(J)$, where
a.
$\Delta J = \pm 3$
b.
$\Delta J = 0$
c.
$\Delta J = \pm 1$
d.
$\Delta J = \pm 2$
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Q30 mcq
The acid radicals mainly responsible for increasing BOD levels are
a.
Sulphates and bicarbonates
b.
Carbonates and bisulphites
c.
Nitrates and phosphates
d.
Thiosulphates and fluorides
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Q32 mcq
The $R_f$ factor if in thin layer chromatography the solvent front moves to 5.4 cm and solution front moves to 0.9 cm, is
a.
6
b.
0.9
c.
1.7
d.
0.17
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Q33 mcq
Mutarotation does not occur in
a.
D-glucose
b.
L-glucose
c.
D-fructose
d.
Sucrose
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Q34 mcq
Nessler's reagent contains
a.
tri-iodomercurate (II)
b.
tetraiodomercurate (II)
c.
tri-iodomercury nitrate (I)
d.
tetraiodomercury nitrate (I)
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Q35 mcq
$\alpha$-glucose and $\beta$-glucose differ in the orientation of the -OH group at carbon,
a.
$C_1$
b.
$C_2$
c.
$C_3$
d.
$C_4$ or $C_5$
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Q37 mcq
BHC is sparingly soluble in .................. solvent.
a.
water
b.
benzene
c.
diethyl ether
d.
ethanol
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Q38 mcq
Observe $\Delta H$ and $\Delta S$ values of the following processes and choose which one will not proceed spontaneously?
a.
$\Delta H$ = positive and $\Delta S$ = 0
b.
$\Delta H$ = negative and $\Delta S$ = negative
c.
$\Delta H$ = positive and $\Delta S$ = negative
d.
$\Delta H$ = negative and $\Delta S$ = positive
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Q39 mcq
Lanthanide contraction is observed in
a.
Gd
b.
At
c.
Xe
d.
Ac
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Q40 mcq
The number of possible alkynes with molecular formula $C_5H_8$ is
a.
2
b.
3
c.
4
d.
5
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Q41 mcq
The group with $-I$ effect is
a.
-$C_6H_5$
b.
-$CH_3$
c.
-$CH_2CH_3$
d.
-$C(CH_3)_3$
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Q42 mcq
Phenol is less acidic than which of the following?
a.
o-nitrophenol
b.
Methanol
c.
Ethanol
d.
p-methyl phenol
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Q43 mcq
The first order rate constant $k$ is related to temperature (kelvin) as $\log k = 15.0 - \frac{10^6}{T}$. Then the values of Arrhenius frequency factor $A$ and energy of activation $E_a$ are
a.
$A = 10^{15};\ E_a = 1.9 \times 10^4\ \text{kJ}$
b.
$A = 10^{-15};\ E_a = 40\ \text{kJ}$
c.
$A = 10^{15};\ E_a = 40\ \text{kJ}$
d.
$A = 10^{-15};\ E_a = 1.9 \times 10^4\ \text{kJ}$
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Q44 mcq
How many fundamental modes of vibration are possible in water molecule?
a.
0
b.
1
c.
2
d.
3
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Q45 mcq
Two moles of an ideal gas expand isothermally and reversibly from 1 litre to 10 litres at 27°C. The enthalpy change in this process is
a.
11.4 kJ
b.
-11.4 kJ
c.
0 kJ
d.
4.8 kJ
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Q46 mcq
The number of nodal planes, a 4d orbital has is
a.
zero
b.
one
c.
two
d.
three
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Q47 mcq
Match List I correctly with List II and select your answer using the codes given below: List I Substrate a) Aliphatic primary amine b) Aromatic primary amine c) Aliphatic secondary amine d) Aromatic tertiary amine List II Product on treatment with HNO$_2$ 1. p-nitroso compound 2. N-nitroso compound 3. alcohol + N$_2$ 4. diazonium salt Codes: a b c d
a.
4 3 1 2
b.
4 2 1 3
c.
1 2 3 4
d.
3 4 2 1
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Q48 mcq
Maximum number of unpaired $d$-electrons are present in
a.
$\mathrm{Zn}^{2+}$
b.
$\mathrm{Fe}^{2+}$
c.
$\mathrm{Ni}^{2+}$
d.
$\mathrm{Cu}^{+}$
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Q49 mcq
The spin magnetic moment of cobalt in Hg$[\mathrm{Co}(\mathrm{SCN})_4]$ is
a.
$\sqrt{2}$
b.
$\sqrt{3}$
c.
$\sqrt{8}$
d.
$\sqrt{15}$
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Q50 mcq
Propene undergoes electrophilic addition with HBr, but not with HCN because
a.
$\mathrm{Br}^-$ is better nucleophile than $\mathrm{CN}^-$
b.
HBr is stronger acid than HCN
c.
HCN attacks preferentially through lone pair of nitrogen
d.
$\mathrm{C-Br}$ bond is stronger than $\mathrm{C-CN}$ bond
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Q51 mcq
Both $sp$ and $sp^2$ hybridisations are present in
a.
acetylene
b.
vinyl acetylene
c.
methyl acetylene
d.
dimethyl acetylene
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Q52 mcq
Geometrical isomerism is shown by
a.
glycerol
b.
glyceric acid
c.
crotonic acid
d.
malonic acid
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Q53 mcq
Hydrogen shows negative Joule-Thomson effect at room temperature because
a.
it is the smallest molecule
b.
it is the lightest gas
c.
it has hydrogen bonds
d.
it has very low inversion temperature
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Q54 mcq
Which of the following can be the units for cell constant of a conductivity cell?
a.
cm2
b.
s cm-1
c.
cm-1
d.
cm2 eq-1
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Q55 mcq
The shape of a graph with atomic number of elements against electronegativity of elements is given in the diagram. Identify P, Q, R and S.
Question 54 image
a.
P = H; Q = F; R = Cl; S = Br
b.
P = He; Q = Ne; R = Ar; S = Kr
c.
P = Li; Q = Na; R = K; S = Rb
d.
P = Li; Q = Be; R = B; S = C
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Q56 mcq
Which is not correct about $K_3[Co(NO_2)_6]$?
a.
Diamagnetic in nature
b.
The complex is derived from Co2+
c.
$d^2sp^3$ hybridisation is involved
d.
Charge on coordination sphere is - 3.
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Q57 mcq
Both morphine and heroin have the same molecular structure, except, morphine has
a.
methyl group in the place of acetyl group in heroin
b.
methoxy group in the place of hydroxyl group in heroin
c.
hydroxyl group in the place of CH3COO group in heroin
d.
acetyl group in the place of hydroxyl group in heroin
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Q58 mcq
DDT is prepared by the reaction of chlorobenzene with
a.
acetaldehyde
b.
chloral
c.
acetone
d.
trichloroacetic acid
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Q59 mcq
Among the following which is sulphadiazine?
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Q60 mcq
The sequence arranged in decreasing magnitude of crystal lattice energy is
a.
NaBr > NaCl > NaF > NaI
b.
NaCl > NaI > NaF > NaBr
c.
NaI > NaBr > NaCl > NaF
d.
NaF > NaCl > NaBr > NaI
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Q61 mcq
Choose the correct order of increasing bond lengths:
a.
O–H < C–C < C=O < C–S
b.
O–H < C=O < C–C < C–S
c.
C–S < C=O < C–C < O–H
d.
C–C < C=O < C–S < O–H
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Q62 mcq
The efficiency of Carnot heat engine working between 273°C and 546°C is
a.
0.1
b.
0.3
c.
2
d.
0.5
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Q63 mcq
Water gas is a mixture of
a.
CO and N2
b.
CO2 and H2O
c.
CO and H2
d.
CO and H2O
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Q64 mcq
The general formula for energy of a rigid rotor with rotational quantum number J is
a.
$BJ(J+1)$
b.
$BJ+1$
c.
$BJ-1$
d.
$BJ(J-1)$
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Q65 mcq
The energy profile for a hypothetical reaction is given in the graph. The mechanism for the reaction is: Step 1: A + B → C Step 2: C + B → D Step 3: D + A → F Overall 2A + 2B → F Which is true about the system?
a.
Step 3 is the fastest step
b.
A catalyst would affect the potential energy of each step equally
c.
The rate law is rate = k[A][B]^2
d.
The rate law is rate = k[A]^2[B]^2
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Q66 mcq
Four litres of a gas are contained under a pressure of 1140 mm/Hg and a temperature of 273°C. The volume of this gas (in litres) at S.T.P. will be
a.
1.5
b.
3
c.
4.5
d.
9
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Q67 mcq
The binding energy of the $^4_2$He nucleus from the following data is
a.
0.03040 MeV
b.
0.03040 × 3.0 × 10^10 MeV
c.
0.03040 × 931 MeV
d.
0.03040 × 6.02 × 10^23 MeV
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Q68 mcq
Which one of the following is an anti-knock compound of petrol?
a.
n-heptane
b.
2,2,4-triethyl octane
c.
tetraethyl lead
d.
2,2,4-triethyl hexane
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Q69 mcq
To what total volume must 20.0 mL of 0.1 M HCl be diluted with water, so that the pH of the solution becomes 1.3?
a.
23 mL
b.
110 mL
c.
50 mL
d.
40 mL
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Q70 mcq
Which of the following is not an interfering anion?
a.
$\mathrm{CO_3^{2-}}$
b.
$\mathrm{F^-}$
c.
$\mathrm{C_2O_4^{2-}}$
d.
$\mathrm{PO_4^{3-}}$
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Q71 mcq
The percentage of nitrogen in urea is
a.
28.8
b.
34.3
c.
46.6
d.
52.2
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Q72 mcq
An organic compound P on reduction gives compound Q which on reaction with chloroform and potassium hydroxide gives R. The compound R on catalytic reduction gives N-methyl aniline. P is
a.
nitrobenzene
b.
aniline
c.
methylamine
d.
nitromethane
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Q73 mcq
Which base is present in RNA but not in DNA?
a.
Cytosine
b.
Guanine
c.
Thymine
d.
Uracil
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Q74 mcq
The following compound is used as what type of medicine?
Question 73 image
a.
Antipyretic
b.
Analgesic
c.
Insecticide
d.
Anaesthetic
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Q75 mcq
Equal weights of radioactive substances X and Y with half-life 5 hours and 1 hour respectively are taken separately. At what time will the weight of X be four times that of Y?
a.
5.6 hours
b.
2.5 hours
c.
2.9 hours
d.
3.9 hours
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Q76 mcq
Which vitamin is 1,4-naphthaquinone derivative?
a.
K1
b.
D
c.
E1
d.
B2
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Q77 mcq
A person is hurt on kicking a stone due to
a.
reaction
b.
mass
c.
velocity
d.
momentum
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Q78 mcq
Which of the following harbours is not a natural harbour?
a.
Cochin
b.
Chennai
c.
Mumbai
d.
Paradwip
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Q79 mcq
Recently one Indian cricket player has become the Sixth Batsman to score 10,000 runs in Test Cricket. The name of the player is
a.
Sachin Tendulkar
b.
Virender Sehwag
c.
Sourav Ganguly
d.
Rahul Dravid
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Q80 mcq
The battle of Wandiwash was fought between
a.
Marathas and Portuguese
b.
the English and the French
c.
the English and Portuguese
d.
Marathas and the English
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Q81 mcq
Linear programming is designed by
a.
B. F. Skinner
b.
E. L. Thorndike
c.
L. P. Pavlov
d.
Clark L. Hull
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Q82 mcq
Which of the following first identified the Secondary Education as a weak link and suggested improvement?
a.
The Tarachand Committee (1948)
b.
The Secondary Education Commission (1954)
c.
The University Education Commission (1949)
d.
The Education Commission (1966)
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Q83 mcq
Intelligence test scores are reasonably stable after the age of
a.
one
b.
two
c.
five
d.
twenty
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Q84 mcq
Which one is not an S-R theory with reinforcement?
a.
E. L. Thorndike's theory
b.
Hull's theory
c.
B. F. Skinner's theory
d.
Tolman's theory of learning
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Q85 mcq
The emphasis of National Board for Adult Education on Curriculum is that it must be
a.
need-based
b.
functional
c.
job-oriented
d.
production-oriented
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Q86 mcq
World First Aid Day is
a.
September 11
b.
September 12
c.
September 10
d.
September 9
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Q87 mcq
For the following scores 10, 11, 13, 10, 15, 17, 18, 15, 10 the value of mode is
a.
10
b.
13
c.
15
d.
18
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Q88 mcq
Educational Technology means
a.
Technology in Education
b.
Technology of Education
c.
both of these
d.
none of these
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Q89 mcq
Which one of the following is not a cause for forgetting?
a.
When something learned and not used repeatedly
b.
Interference with present learning
c.
Lack of reorganisation of the learning material
d.
Learning on the basis of short-term remembrance
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Q90 mcq
When the reason for acting is in the action, motivation is said to be
a.
extrinsic
b.
intrinsic
c.
extrinsic & intrinsic
d.
none of these
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Q91 mcq
National Integration Day is
a.
November 19
b.
December 19
c.
September 19
d.
May 19
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Q92 mcq
The importance of Teacher Education was first emphasized by
a.
the Woods Dispatch
b.
the Hunter Commission
c.
Calcutta University Commission
d.
the White Paper
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Q93 mcq
Taxonomy of educational objectives was first developed by
a.
Mager
b.
Skinner
c.
Bloom
d.
Thorndike
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Q94 mcq
SSA is established for achievement of
a.
Elementary Education
b.
Secondary Education
c.
Higher Education
d.
Vocational Education
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Q95 mcq
Whose philosophy is characterised as 'Naturalistic in its setting, Idealistic in its aim and Pragmatic in its method and Programme of work'?
a.
Sri Aurobindo
b.
Gandhiji
c.
Rousseau
d.
Tagore
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Q96 mcq
Multi-factor theory of Intelligence was developed by
a.
Charles Spearman
b.
E. L. Thorndike
c.
L. L. Thurstone
d.
Dr. J. P. Guilford
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Q97 mcq
Benzocaine is a/an
a.
antifungal drug
b.
hypoglycemic drug
c.
cardiovascular drug
d.
anaesthetic drug
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Q98 mcq
Presently used antacid is
a.
norethindrone
b.
diphenylhydramine
c.
promethazine
d.
omeprazole
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Q99 mcq
What is the enthalpy of OH$^-$ ions if the enthalpy of formation of H$_2$O is $-284.5\ \text{kJ mol}^{-1}$?
a.
$-341.8\ \text{kJ mol}^{-1}$
b.
$-227.2\ \text{kJ mol}^{-1}$
c.
$-57.3\ \text{kJ mol}^{-1}$
d.
$-34.8\ \text{kJ mol}^{-1}$
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Q99 mcq
What is the enthalpy of OH− ions if the enthalpy of formation of H2O is −284.5 kJ mol−1?
a.
−341.8 kJ mol−1
b.
−227.2 kJ mol−1
c.
−57.3 kJ mol−1
d.
−34.8 kJ mol−1
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Q100 mcq
On dilution of the electrolyte, what happens to equivalent conductance?
a.
Decreases
b.
Increases
c.
Fluctuates
d.
Unpredictable
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Q101 mcq
$\Delta C_p = \dfrac{\Delta H_2 - \Delta H_1}{T_2 - T_1}$, this equation is known as
a.
Kirchhoff's equation
b.
Gibbs-Helmholtz equation
c.
Gibbs-Duhem equation
d.
Maxwell's equation
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Q102 mcq
Sodalime glass is made from which of the following?
a.
Mixture of sodium silicates
b.
Sodium carbonate and silica
c.
Sodium tartrate and limestone
d.
Sodium amalgam and quicklime
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Q103 mcq
Carrier gases used in gas chromatography are
a.
H2 and Cl2
b.
He and N2
c.
O2 and CH4
d.
F2 and H2.
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Q104 mcq
The mathematical equation for Beer-Lambert's law is
a.
$A = \log\dfrac{I_0}{I}$
b.
$\varepsilon = \log\dfrac{I_0}{I}$
c.
$A = \log\dfrac{I}{I_0}$
d.
$\varepsilon = \log\dfrac{I}{I_0}$
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Q105 mcq
In qualitative analysis, the cation that precipitates as its sulphide when H2S is passed through alkaline salt solution is
a.
Mn2+
b.
Bi3+
c.
Sn4+
d.
Cu2+
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Q106 mcq
The reaction $2\,\mathrm{NO(g)} + \mathrm{Cl_2(g)} \to 2\,\mathrm{NOCl(g)}$ has the rate law $\text{Rate} = k[\mathrm{NO}]^2[\mathrm{Cl_2}]$. The possible mechanism is
a.
i) $2\,\mathrm{NO} \rightleftharpoons \mathrm{N_2O_2}$ (slow equilibrium) ii) $\mathrm{N_2O_2} + \mathrm{Cl_2} \to 2\,\mathrm{NOCl}$ (fast)
b.
i) $2\,\mathrm{NO} \rightleftharpoons \mathrm{N_2O_2}$ (fast equilibrium) ii) $\mathrm{N_2O_2} \to \mathrm{NO_2} + \mathrm{N}$ (slow) iii) $\mathrm{NO_2} + \mathrm{N} + \mathrm{Cl_2} \to 2\,\mathrm{NOCl}$ (fast)
c.
i) $\mathrm{Cl_2} \to 2\,\mathrm{Cl}$ (slow) ii) $2\,\mathrm{NO} \rightleftharpoons \mathrm{N_2O_2}$ (fast equilibrium) iii) $\mathrm{N_2O_2} + 2\,\mathrm{Cl} \to 2\,\mathrm{NOCl}$ (fast)
d.
i) $\mathrm{NO} + \mathrm{Cl_2} \rightleftharpoons \mathrm{NOCl_2}$ (fast equilibrium) ii) $\mathrm{NO} + \mathrm{NOCl_2} \to 2\,\mathrm{NOCl}$ (slow)
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Q106 mcq
The reaction $2\,NO(g) + Cl_2(g) \rightarrow 2\,NOCl(g)$ has the rate law $\text{Rate} = k[NO]^2[Cl_2]$. The possible mechanism is
a.
i) $2\,NO \rightleftharpoons N_2O_2$ (slow equilibrium) ii) $N_2O_2 + Cl_2 \rightarrow 2\,NOCl$ (fast)
b.
i) $2\,NO \rightleftharpoons N_2O_2$ (fast equilibrium) ii) $N_2O_2 \rightarrow NO_2 + N$ (slow) iii) $NO_2 + N + Cl_2 \rightarrow 2\,NOCl$ (fast)
c.
i) $Cl_2 \rightarrow 2\,Cl$ (slow) ii) $2\,NO \rightleftharpoons N_2O_2$ (fast equilibrium) iii) $N_2O_2 + 2\,Cl \rightarrow 2\,NOCl$ (fast)
d.
i) $NO + Cl_2 \rightleftharpoons NOCl_2$ (fast equilibrium) ii) $NO + NOCl_2 \rightarrow 2\,NOCl$ (slow)
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Q107 mcq
The molecule which can show pure rotational microwave spectrum is
a.
HCl
b.
Cl$_2$
c.
N$_2$
d.
CO$_2$
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Q108 mcq
The following compound is commonly known as
Question 109 image
a.
DDT
b.
Aspirin
c.
DDE
d.
BHC
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Q109 mcq
Nylon-66 refers to a synthetic fibre produced by the combination of
a.
hexamethyl benzene and hexachlorobenzene
b.
hexachloroethane and n-hexane
c.
hexaminobenzene and malonic acid
d.
hexamethylene diamine and adipic acid
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Q110 mcq
The nucleic acid having binary basic binding sites is
a.
thymine
b.
guanine
c.
cytosine
d.
adenine
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Q111 mcq
Barbituric acid derivatives are used as
a.
antibiotics
b.
antihistamines
c.
non-narcotics
d.
tranquilizers
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Q112 mcq
Female sex hormone among the following is
a.
adrenaline
b.
estrogen
c.
cortisone
d.
testosterone
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Q113 mcq
The product obtained when bromine water reacts with ethene is
Question 114 image
a.
1,2-ethanediol
b.
bromoethane
c.
2-bromoethanol
d.
1,2-dibromoethane
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Q114 mcq
The compound which will be most easily attacked by an electrophile is
a.
chlorobenzene
b.
benzene
c.
phenol
d.
toluene
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Q115 mcq
At cathode, the electrolysis of aqueous Na$_2$SO$_4$ gives
a.
Na
b.
H$_2$
c.
SO$_3$
d.
SO$_2$
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Q116 mcq
The least stable among the following is
a.
Li$^-$
b.
Be$^-$
c.
B$^-$
d.
C$^-$
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Q117 mcq
Radiation that can be stopped by air is
a.
$\alpha$-ray
b.
$\beta$-ray
c.
$\gamma$-ray
d.
X-ray
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Q118 mcq
The reaction of ammonia with silver is used for identifying silver ions. The final stage in the reaction is $2\,NH_3(aq) + Ag^+(aq) \rightarrow [Ag(NH_3)_2]^+(aq)$. The Lewis acid and Lewis base in this reaction respectively are
a.
$Ag^+$ ; $NH_3$
b.
$NH_3$ ; $Ag^+$
c.
$[Ag(NH_3)_2]^+$ ; $OH^-$
d.
$H_3O^+$ ; $[Ag(NH_3)_2]^+$
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Q119 mcq
If radium and chlorine combine to form radium chloride, the compound is
a.
not radioactive
b.
twice radioactive as radium
c.
half radioactive as radium
d.
as radioactive as radium
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Q120 mcq
In the compound shown, electrophilic substitution occurs at
Question 121 image
a.
ortho/para at the first ring
b.
ortho/para at the second ring
c.
meta at the first ring
d.
meta at the second ring
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Q120 mcq
In $\mathrm{PhCOOPh}$ electrophilic substitution occurs at
Question 122 image
a.
ortho/para at the first ring
b.
ortho/para at the second ring
c.
meta at first ring
d.
meta at second ring
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Q121 mcq
The most reactive towards elimination reaction among the following is
Question 123 image
a.
RCOO-
b.
CN-
c.
NO3-
d.
RO-
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Q122 mcq
$2HCHO + NaOH \rightarrow CH_3OH + HCOONa$ This is an example of
Question 124 image
a.
Benzoin condensation
b.
Cannizzaro reaction
c.
Tischenko reaction
d.
Schiff's reaction
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Q123 mcq
When optically active $\alpha$-phenyl ethyl alcohol is reacted with thionyl chloride, the product obtained is
Question 125 image
a.
racemic mixture of $\alpha$-phenylethyl chloride
b.
$\alpha$-phenylethyl chloride with opposite optical activity
c.
$\alpha$-phenylethyl chloride with retention of same optical activity
d.
optically active $\beta$-phenylethyl chloride
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Q124 mcq
How many isomers are possible in $[Co(en)_2Cl_2]$?
Question 126 image
a.
1
b.
2
c.
3
d.
4
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Q125 mcq
Butyne-1 and butene-2 can be distinguished by the chemical test,
Question 127 image
a.
Molisch test
b.
Azo dye test
c.
Tollen's test
d.
Schiff's test
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Q126 mcq
The decreasing order of stability of the following hydrides is
Question 128 image
a.
$PH_3 > BH_3 > SbH_3 > AsH_3$
b.
$SbH_3 > AsH_3 > BH_3 > PH_3$
c.
$AsH_3 > PH_3 > SbH_3 > BH_3$
d.
$PH_3 > AsH_3 > SbH_3 > BH_3$
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Q127 mcq
Lithium hydride reacts with aluminium trichloride to give
Question 129 image
a.
lithium chlorohydride
b.
aluminium lithium chloride
c.
lithium aluminium hydride
d.
aluminium hydrochloride
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Q128 mcq
The geometries of Ni(CO)4 and Ni(PPh3)2Cl2 are
a.
both square planar
b.
tetrahedral and square planar respectively
c.
both tetrahedral
d.
square planar and tetrahedral respectively
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Q129 mcq
If n/p ratio is high, the nucleus tends to stabilise by
a.
neutron capture
b.
losing positron
c.
α-ray emission
d.
β-ray emission
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Q130 mcq
Uranium isotope used in atom bomb is having mass number
a.
231
b.
233
c.
234
d.
235
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Q131 mcq
The transition element which has all its d-orbitals filled in the ground state is
a.
Sn
b.
Ag
c.
Cr
d.
Fe
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Q132 mcq
Talc used in Talcum powder [Mg3Si4O10(OH)2] is the softest mineral silicate. This is because
a.
of layer structures held by van der Waals' forces
b.
Mg is a very soft element
c.
Si-O bonds are very weak
d.
the presence of OH gives softness
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Q133 mcq
The vapour pressures of ethoxy ethane, propanone, n-heptane and n-hexane respectively are (in kPa) 57.855, 23.541, 4.655 and 16.093. Their boiling points (in °C) in the same order are
a.
34.7 ; 56.4 ; 68 ; 98
b.
34.7 ; 56.4 ; 98 ; 68
c.
68 ; 98 ; 56.4 ; 34.7
d.
56.4 ; 34.7 ; 68 ; 98
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Q134 mcq
The density of a solution of 20% (by weight) KI (mol. wt. 166.03) solution in water is 1.166 kg L^-1. Its molality is
a.
1.40 M
b.
1.45 M
c.
1.50 M
d.
1.55 M
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Q135 mcq
Vitamin, which is not soluble in water, is
a.
Phylloquinone
b.
Ascorbic acid
c.
Thiamine
d.
Cyanocobalamin
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Q136 mcq
The reagent that does not react with glucose is
a.
Fehling's
b.
Hydroxylamine
c.
Phenyl hydrazine
d.
Sodium bisulphite
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Q137 mcq
In the SN2 reaction mechanism, the most reactive among the following is
a.
C6H6
b.
CH3CH2Br
c.
CH3Br
d.
(CH3)3CBr
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Q138 mcq
Match List I correctly with List II and select your answer using the codes given below: List I Acids a) HCOOH b) CH2=CH-COOH c) CH3CH2COOH d) CH3COOH List II pKa values 1. 4.76 2. 4.88 3. 4.25 4. 3.77
a.
4 3 2 1
b.
1 2 3 4
c.
2 3 1 4
d.
3 4 2 1
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Q139 mcq
Pyrrole is less basic than pyridine because pyrrole has a
a.
pair of electrons as a part of aromatic sextet
b.
proton that can be donated
c.
smaller ring than pyridine
d.
cyclic diene system
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Q140 mcq
Blue colour obtained as a result of borax bead test indicates the presence of
a.
Al
b.
Co
c.
Ni
d.
Mg
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Q141 mcq
The compound which gives the most stable carbocation on dehydration is
a.
(CH3)2CHCH2OH
b.
(CH3)3COH
c.
CH3CH2CH2CH2OH
d.
CH3CHOHCH2CH3
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Q142 mcq
Observe the molecular structure below and name the compound:
Question 144 image
a.
Sulphadiazine
b.
Sulphapyridine
c.
Urcil
d.
Protosil
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Q143 mcq
The set that will form a buffer when dissolved in water to make 1 litre of solution is
a.
0.2 mole of NaOH and 0.2 mole of HCl
b.
0.2 mole of NaCl and 0.2 mole of HNO3
c.
0.4 mole of CH3COOH and 0.4 mole of NaOH
d.
0.4 mole of NH3 and 0.2 mole of HCl
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Q144 mcq
Benzolic acid is 1.0% ionised in a 0.01 M solution as $\mathrm{C_6H_5COOH(aq) \rightleftharpoons H^+(aq) + C_6H_5COO^-(aq)}$ Its $K_a$ value is
a.
$1.0 \times 10^{-8}$
b.
$1.0 \times 10^{-6}$
c.
$1.0 \times 10^{-4}$
d.
$1.0 \times 10^{-3}$
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Q144 mcq 1 mark
Benzoic acid is 1.0% ionised in a 0.01 M solution as C6H5COOH(aq) ⇌ H+(aq) + C6H5COO−(aq). Its $K_a$ value is
a.
1.0 × 10^-8
b.
1.0 × 10^-6
c.
1.0 × 10^-4
d.
1.0 × 10^-3
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Q145 mcq 1 mark
Electrophilic addition reaction of H3C-CH=CH-C(CH3)2-CH3 with HBr gives only H3C-CH(Br)-CH2-C(CH3)2-CH3. This is because of
a.
Inductive effect
b.
resonance effect
c.
steric effect
d.
hyperconjugative effect
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Q146 mcq 1 mark
Which of the following has four significant figures?
a.
0.0011
b.
6.023 × 10^23
c.
23.200
d.
3.8 × 10^10
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Q147 mcq 1 mark
Benzene diazonium chloride on reaction with phenol in weakly basic medium gives
a.
p-hydroxy azobenzene
b.
chlorobenzene
c.
benzene
d.
diphenyl ether
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Q148 mcq 1 mark
Match List I correctly with List II and select your answer using the codes given below: List I — Co-ordination compound of Pt (a) Pt(CO)2(PPh3)2 (b) [(CH3)3Pt(H2O)3]Cl (c) K[Pt(C2H4)Cl3] List II — Oxidation state of Pt 1. +2 2. 0 3. +4
a.
a b c = 1 2 3
b.
a b c = 2 1 3
c.
a b c = 2 3 1
d.
a b c = 3 2 1
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Q149 mcq 1 mark
Assign correct configuration of the molecule
Question 152 image
a.
2R, 3R
b.
2S, 3S
c.
2R, 3S
d.
2S, 3R
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Q150 mcq 1 mark
Which one of the following sets of quantum numbers is incorrect?
a.
n = 1, l = 1, m = 0, s = -1/2
b.
n = 2, l = 1, m = +2, s = -1/2
c.
n = 2, l = 1, m = +1, s = +1/2
d.
n = 3, l = 0, m = 0, s = -1/2
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