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Tamil Nadu State Board · Chemistry

TAMIL NADU STATE BOARD CLASS 12 CHEMISTRY 2023

2023 · 53 questions · First 10 Solutions Free
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Q1 mcq 1 mark
Milk of Magnesia is used as __________.
a.
Tranquilizer
b.
Analgesic
c.
Antacid Correct Answer
d.
Anaesthetic
Step-by-Step AI Explanation
Verified Method
Milk of Magnesia is a suspension of magnesium hydroxide, $Mg(OH)_2$. It acts as an antacid by neutralizing excess hydrochloric acid in the stomach. Tranquilizers are for mental stress, analgesics for pain relief, and anaesthetics for inducing insensibility, making them incorrect.
Q2 mcq 1 mark
The addition of a catalyst during a chemical reaction alters, which of the following quantities ?
a.
Entropy
b.
Internal energy
c.
Activation energy Correct Answer
d.
Enthalpy
Step-by-Step AI Explanation
Verified Method
A catalyst provides an alternative reaction pathway with a lower activation energy ($E_a$), thereby increasing the reaction rate. It does not affect the thermodynamic properties like entropy, internal energy, or enthalpy of the reactants or products.
Q3 mcq 1 mark
The metal extracted by Hall-Heroult process is :
a.
Cu
b.
Al Correct Answer
c.
Zn
d.
Ni
Step-by-Step AI Explanation
Verified Method
The Hall-Heroult process is specifically used for the electrolytic reduction of pure alumina ($Al_2O_3$) dissolved in molten cryolite ($Na_3AlF_6$) to extract aluminium (Al).
Q4 mcq 1 mark
A magnetic moment of 1.73 BM will be shown by one among the following :
a.
[ ] -4 6 CoCl
b.
TiCl 4
c.
( ) 2 34 Cu NH [ ] + Correct Answer
d.
( ) 2 4Ni CN [ ] -
Step-by-Step AI Explanation
Verified Method
The magnetic moment $\mu = \sqrt{n(n+2)} BM$. For $\mu = 1.73 BM$, $n = 1$ (one unpaired electron). In $[Cu(NH_3)_4]^{2+}$, the $Cu^{2+}$ ion is $d^9$, which leaves one unpaired electron in the $3d_{x^2-y^2}$ orbital, matching the magnetic moment. $TiCl_4$ ($d^0$), $[Ni(CN)_4]^{2-}$ ($d^8$ square planar, diamagnetic), and $[CoCl_4]^{2-}$ ($d^7$, 3 unpaired electrons) do not fit.
Q5 mcq 1 mark
Which one is correctly matched ?
a.
Foam - mist
b.
Emulsion - smoke
c.
Sol - whipped cream
d.
Gel - butter Correct Answer
Step-by-Step AI Explanation
Verified Method
A gel is a colloidal system where a liquid is dispersed in a solid. Butter is a perfect example of a gel. Other options are incorrectly matched (e.g., whipped cream is foam, not sol).
Q6 mcq 1 mark
Which one of the following will cause common-ion-effect when added to the following dissociation equilibrium reaction ? CH3COOH(aq) β‡Œ CH3COO-(aq) + H+(aq)
a.
CH3COCl Correct Answer
b.
AgCl
c.
CH3Cl
d.
HCl
Step-by-Step AI Explanation
Verified Method
The common-ion effect occurs when an ion already present in the equilibrium is added. $CH_3COCl$ hydrolyzes to produce $CH_3COO^-$ and $HCl$, providing a common $CH_3COO^-$ ion, which shifts the equilibrium to the left. HCl could also cause it via $H^+$ ions, but $CH_3COCl$ is the standard textbook example for acetate equilibrium shifts.
Q7 mcq 1 mark
Carbon atoms in Fullerene with formula C60 have __________ hybridisation.
a.
sp2 Correct Answer
b.
sp3
c.
sp3d
d.
sp
Step-by-Step AI Explanation
Verified Method
In Fullerene ($C_{60}$), each carbon atom is bonded to three other carbon atoms in a hexagonal/pentagonal arrangement, resulting in $sp^2$ hybridisation, similar to graphite.
Q8 mcq 1 mark
The most common oxidation state of Actinoids is :
a.
14
b.
12
c.
16
d.
13 Correct Answer
Step-by-Step AI Explanation
Verified Method
The actinoids show a variable oxidation state, but the most common and stable oxidation state across the series is +3.
Q9 mcq 1 mark
Assertion : Hex-4-ennitrile on reaction with Di-isobutyl aluminium hydride followed by Hydrolysis gives Hex-4-enal. Reason : Di-isobutyl aluminium hydride is a selective reducing agent.
a.
Assertion is true but Reason is false.
b.
Both Assertion and Reason are true, but reason is not the correct explanation of assertion.
c.
Both Assertion and Reason are false.
d.
Both Assertion and Reason are true and reason is the correct explanation of assertion. Correct Answer
Step-by-Step AI Explanation
Verified Method
DIBAL-H (Di-isobutyl aluminium hydride) is a selective reducing agent that specifically reduces nitriles to imines, which on hydrolysis yield aldehydes. Since it reduces the nitrile group while leaving the C=C double bond (in hex-4-ennitrile) unaffected, both the assertion and reason are true, and the reason correctly explains the selectivity of the reaction.
Q10 mcq 1 mark
Which of the following is used as the source of gamma rays ?
a.
Xe
b.
Ar
c.
Rn Correct Answer
d.
Kr
Step-by-Step AI Explanation
Verified Method
Radon (Rn) is a radioactive noble gas. Among the options provided, radioactive elements are sources of high-energy radiation like gamma rays, whereas Xe, Ar, and Kr are stable noble gases in their natural isotopic form.
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Q11 mcq 1 mark
The emf of Standard Hydrogen Electrode (SHE) is __________.
a.
βˆ’1.0
b.
0
c.
1.1
d.
11.0
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Q12 mcq 1 mark
The crystal with metal excess defect is :
a.
NaCl
b.
AgBr
c.
AgCl
d.
FeO
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Q13 mcq 1 mark
Which of the following base is not present in DNA ?
a.
Uracil
b.
Adenine
c.
Cytosine
d.
Guanine
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Q14 mcq 1 mark
Which of the following compound is used as an anti-freeze in automobile radiator ?
a.
Methanol
b.
Ethane-1, 2-diol
c.
Ethanol
d.
Glycerol
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Q15 mcq 1 mark
The product formed by the reaction of an Aromatic aldehyde with primary amines is :
a.
Schiff’s base
b.
Carboxylic acid
c.
Ketone
d.
Aromatic acid
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Q16 short answer
Which type of ores can be concentrated by froth floatation method ? Give two examples for such ores.
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Q17 short answer
Write the uses of Silicones.
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Q18 short answer
Define the term central atom in co-ordination compounds.
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Q19 short answer
Calculate the number of atoms in an FCC unit cell.
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Q20 short answer
What is conjugate Acid-Base pairs ?
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Q21 short answer
What are catalytic poisons ?
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Q22 short answer
How will you convert acetone into propane ?
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Q23 short answer
What are Hormones ? Give example.
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Q24 short answer
Identify the compounds A and B in the following sequence of reactions. $$CH_3CH_2NO_2 \xrightarrow{Sn/HCl} A \xrightarrow{CH_3COCl} B$$
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Q25 short answer
Write a note on Fischer tropsch synthesis.
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Q26 short answer
Write any three differences between Lanthanoids and Actinoids.
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Q27 short answer
For the complex, $[Pt(NO_2)(H_2O)(NH_3)_2]Br$ identify the following. (a) Central metal atom/ion (b) Co-ordination number (c) Oxidation number of central metal ion
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Q28 short answer
Write a note on Helmholtz electrical double layer.
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Q29 short answer
State Faraday’s Laws of Electrolysis.
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Q30 short answer
Give the structure of a Zwitter ion.
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Q31 short answer
How will you convert Ethylacetate into Ethylaceto acetate ?
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Q32 short answer
What are food preservatives ? Give two examples.
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Q33 short answer
Show that in case of first order reaction the time required for the completion of 99% is twice the time required for the completion of 90% of the reaction.
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Q34 long answer
Explain zone refining process with an example.
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Q35 long answer
(i) Find the oxidation state of Halogen in the following compounds. (1) $OF_2$ (2) $I_2O_4$ (ii) Complete the following reactions. (1) $P_4 + NaOH + H_2O \rightarrow$ (2) $XeF_6 + H_2O \rightarrow$ (3) $Cu + conc. H_2SO_4 \rightarrow$
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Q36 long answer
(i) Describe the structure of Diborane. (ii) Write ethylborate test.
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Q37 long answer
Describe the nature of bonding in metallic carbonyls.
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Q38 long answer
Explain Schottky and Frenkel defects.
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Q39 long answer
(i) Give two examples for zero order reaction. (ii) How colloids are used in tanning of leather and in Rubber industry ?
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Q40 long answer
Explain the mechanism of nucleophilic substitution reaction.
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Q41 long answer
(i) Why do not phenol, benzyl chloride undergo $S_N2$ reaction? (ii) How is propan-2-ol synthesized ?
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Q42 short answer
Find the oxidation state of Halogen in the following compounds. (1) $OF_2$ (2) $I_2O_4$
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Q43 short answer
Complete the following reactions. (1) $P_4 + NaOH + H_2O \rightarrow$ (2) $XeF_6 + H_2O \rightarrow$ (3) $Cu + conc. H_2SO_4 \rightarrow$
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Q44 short answer
Describe the structure of Diborane.
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Q45 short answer
Write ethylborate test.
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Q46 short answer
Give two examples for zero order reaction.
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Q47 short answer
How colloids are used in tanning of leather and in Rubber industry ?
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Q48 long answer
Derive an expression for Ostwald’s Dilution Law.
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Q49 short answer
Why aniline does not undergo Friedel Craft’s reaction ?
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Q50 short answer
How nylon-2-nylon-6 is prepared ?
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Q51 short answer
How Malachitegreen is prepared from Benzaldehyde ?
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Q52 short answer
Write short note on Thorpe nitrile Condensation reaction.
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Q53 long answer
Compound (A) of molecular formula $C_6H_6O$ gives purple colouration with neutral $FeCl_3$. Compound (A) reacts with ammonia to give Compound (B ) and it also reacts with Zn dust to give Compound (C). Identify the Compounds A, B and C and write down the equations.
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