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JEE Main 2025 (29 Jan Shift 1)

2025 · 75 questions · First 10 Solutions Free
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Q1 mcq
Define a relation R on the interval $[0, \frac{\pi}{2})$ by $xRy$ if and only if $sec^{2} x-tan^{2} y= 1$ . Then R is :
a.
both reflexive and transitive but not symmetric
b.
an equivalence relation Correct Answer
c.
reflexive but neither symmetric not transitive
d.
both reflexive and symmetric but not transitive

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Q2 nat
Let $S ={x: cos^{-1} x=\pi + sin^{-1} x+ sin^{-1}(2x+ 1)}$ . Then $\sum _{x\in \,S}(2x-1)^{2}$ is equal to ______.
✓ Accepted Answer: 5

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Q3 nat
Let $f : (0, \infty ) \rightarrow \rightarrow R$ be a twice differentiable function. If for some $a \neq 0,\int _{0}^{1} f(\lambda x)d\lambda = af(x),f(1) = 1$ and $f(16) = \frac{1}{8}$ , then $16 - f' (\frac{1}{16} )$ is equal to _______.
✓ Accepted Answer: 112

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Q4 mcq
Let $|z_{1}-8 -2i| \leq 1$ and $|z_{2}-2 + 6i| \leq 2,z_{1},z_{2} \in C$ . Then the minimum value of $|z_{1}- z_{2}|$ is :
a.
13
b.
10
c.
3
d.
7 Correct Answer

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Q5 nat
$_{2} 2 -1$ Let $S ={m \in Z: A^{m} + A^{m} = 3I -A^{-6}}$ , where $A =[ ]$ . Then $n(S)$ is equal to ______. $1 0$
✓ Accepted Answer: 2

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Q6 mcq
Let $\vec{a}= 2\hat{i}- \hat{j}+ 3\hat{k}, \,\vec{b}= 3\hat{i}-5\hat{j}+ \hat{k}$ and $\vec{c}$ be a vector such that $\vec{a}\times \vec{c}= \vec{c}\times \vec{b}$ and $(\vec{a}+ \vec{c}) \cdot (\vec{b}+ \vec{c}) = 168$ . Then the maximum value of $|\vec{c}|^{2}$ is :
a.
462
b.
77
c.
154
d.
308 Correct Answer

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Q7 mcq
Let the line $x+y= 1$ meet the circle $x^{2} +y^{2} = 4$ at the points A and B . If the line perpendicular to $AB$ and passing through the mid point of the chord $AB$ intersects the circle at $C$ and $D$ , then the area of the quadrilateral ADBC is equal to :
a.
$\sqrt{14}$
b.
$3\sqrt{7}$
c.
$2\sqrt{14}$ Correct Answer
d.
$5\sqrt{7}$

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Q8 mcq
Let $ABC$ be a triangle formed by the lines $7x-6y+ 3 = 0,x+ 2y-31 = 0$ and $9x-2y-19 = 0$ . Let the point $(h,k)$ be the image of the centroid of $\Delta ABC$ in the line $3x+ 6y-53 = 0$ . Then $h^{2} +k^{2} +hk$ is equal to:
a.
47
b.
37 Correct Answer
c.
36
d.
40

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Q9 mcq
$| |$ The least value of n for which the number of integral terms in the Binomial expansion of $(\sqrt{7}^{3} +^{12}\sqrt{11})^{n}$ is 183, is :
a.
2184 Correct Answer
b.
2196
c.
2148
d.
2172

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Q10 mcq
The number of solutions of the equation $(\frac{9}{x} - \frac{9}{\sqrt{x}} + 2) (\frac{2}{x} - \frac{7}{\sqrt{x}} + 3)= 0$ is:
a.
2
b.
3
c.
1
d.
4 Correct Answer

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Q11 mcq
Let $L_{1} : \frac{x-1}{1} = \frac{y-2}{-1} = \frac{z-1}{2}$ and $L_{2} : \frac{x+1}{-1} = \frac{y-2}{2} = \frac{z}{1}$ be two lines. Let $L_{3}$ be a line passing through the point $(\alpha ,\beta ,\gamma )$ and be perpendicular to both $L_{1}$ and $L_{2}$ . If $L_{3}$ intersects $L_{1}$ , then $|5\alpha -11\beta -8\gamma |$ equals :
a.
20
b.
18
c.
25
d.
16
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Q12 nat
The number of 6-letter words, with or without meaning, that can be formed using the letters of the word MATHS such that any letter that appears in the word must appear at least twice, is _______.
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Q13 mcq
Let M and m respectively be the maximum and the minimum values of $1 + sin^{2} x cos^{2} x 4 sin 4x$ $f(x) = sin^{2} x 1 + cos^{2} x 4 sin 4x ,x\in R$ Then $M^{4} - m^{4}$ is equal to : $sin^{2} x cos^{2} x 1 + 4 sin 4x$
a.
1280
b.
1295
c.
1215
d.
1040
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Q14 mcq
Let the ellipse $E_{1} : \frac{x^{2}}{a^{2}} + \frac{y^{2}}{\,b^{2}} = 1, a > b$ and $E_{2} : \frac{x^{2}}{\,A^{2}} + \frac{y^{2}}{\,B^{2}} = 1, \,A < B$ have same eccentricity $\frac{1}{\sqrt{3}}$ . Let the product of their lengths of latus rectums be $\frac{32}{\sqrt{3}}$ , and the distance between the foci of $E_{1}$ be 4. If $E_{1}$ and $E_{2}$ meet at $A,B,C$ and $D$ , then the area of the quadrilateral $ABCD$ equals :
a.
$\frac{12\sqrt{6}}{5}$
b.
$6\sqrt{6}$
c.
$\frac{18\sqrt{6}}{5}$
d.
$\frac{24\sqrt{6}}{5}$
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Q15 mcq
Consider an A. P. of positive integers, whose sum of the first three terms is 54 and the sum of the first twenty terms lies between 1600 and 1800. Then its $11^{th\,}$ term is :
a.
90
b.
84
c.
122
d.
108
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Q16 mcq
Let the area of the region ${(x,y) : 2y\leq x^{2} + 3,y+ |x| \leq 3,y⩾ |x-1|}$ be A. Then 6 A is equal to :
a.
16
b.
12
c.
14
d.
18
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Q17 mcq
Let P be the set of seven digit numbers with sum of their digits equal to 11 . If the numbers in P are formed by using the digits 1,2 and 3 only, then the number of elements in the set $P$ is :
a.
173
b.
164
c.
158
d.
161
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Q18 mcq
Let $x_{1},x_{2}, … ,x_{10}$ be ten observations such that $\sum _{i=1} (x_{i}-2) = 30,\sum _{i=1} (x_{i}- \beta ) = 98,\beta > 2$ , and their variance is $\frac{4}{5}$ . If $\mu$ and $\sigma ^{2}$ are respectively the mean and the variance of $2 (x_{1}-1) + 4\beta$ , $2 (x_{2}-1) + 4\beta , … . , 2 (x_{10}-1) + 4\beta$ , then $\frac{\beta \mu}{\sigma ^{2}}$ is equal to :
a.
100
b.
120
c.
110
d.
90
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Q19 nat
Let [t] be the greatest integer less than or equal to t. Then the least value of $p \in N$ for which $lim_{x\rightarrow 0\rightarrow }_{+}(x([\frac{1}{x} ]+[\frac{2}{x} ]+ … +[\frac{p}{x}])- x^{2}([\frac{1}{x^{2}}]+[\frac{2^{2}}{x^{2}}]+ … +[\frac{9^{2}}{x^{2}}]))\geq 1$ is equal to ________.
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Q20 mcq
The integral $80\int _{0}\frac{\pi}{4} (\frac{sin\theta +cos\theta}{9+16 sin 2\theta})d\theta$ is equal to :
a.
$3 log_{e}4$
b.
$4 log_{e}3$
c.
$6 log_{e}4$
d.
$2 log_{e}3$
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Q21 mcq
The value of $lim_{n\rightarrow \infty \rightarrow } (\sum ^{n}_{k=1} \frac{k^{3}+6k^{2}+11k+5}{(k+3)!})$ is:
a.
$4/3$
b.
2
c.
$7/3$
d.
$5/3$
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Q22 mcq
Two parabolas have the same focus $(4, 3)$ and their directrices are the $x$ -axis and the $y$ -axis, respectively. If these parabolas intersects at the points $A$ and $B$ , then $(AB)^{2}$ is equal to :
a.
392
b.
384
c.
192
d.
96
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Q23 mcq
Let $\vec{a}= \hat{i}+ 2\hat{j}+ \hat{k}$ and $\vec{b}= 2\hat{i}+ 7\hat{j}+ 3\hat{k}.$ Let $L_{1} : \vec{r}= (-\hat{i}+ 2\hat{j}+ \hat{k}) +\lambda \vec{a},\lambda \in R$ and $L_{2} : \vec{r}= (\hat{j}+ \hat{k}) +\mu \vec{b},\mu \in R$ be two lines. If the line $L_{3}$ passes through the point of intersection of $L_{1}$ and $L_{2}$ , and is parallel to $\vec{a}+ \vec{b}$ , then $L_{3}$ passes through the point :
a.
$(5, 17, 4)$
b.
$(2, 8, 5)$
c.
$(8, 26, 12)$
d.
$(-1, -1, 1)$
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Q24 mcq
Let $y=y(x)$ be the solution of the differential equation $cosx(log_{e}(cosx))^{2}dy + (sinx-3ysinxlog_{e}(cosx))dx= 0,x\in (0, \frac{\pi}{2})$ . If $y( \frac{\pi}{4})= \frac{-1}{log_{e}2}$ , then $y( \frac{\pi}{6})$ is equal to :
a.
$\frac{1}{log_{e}(3)-log_{e}(4)}$
b.
$\frac{2}{log_{e}(3)-log_{e}(4)}$
c.
$\frac{1}{log_{e}(4)-log_{e}(3)}$
d.
$-\frac{1}{log_{e}(4)}$
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Q25 mcq
$log_{5}128 log_{4}5_{2}$ Let $A = [a_{ij}] =[ ]$ . If $A_{ij}$ is the cofactor of $a_{ij}, C_{ij} =\sum _{k=1} a_{ik}A_{jk}, 1 \leq i,j\leq 2$ , and $log_{5}8 log_{4}25$ $C = [C_{ij}]$ , then $8|C|$ is equal to :
a.
288
b.
222
c.
242
d.
262
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Q26 mcq
At the interface between two materials having refractive indices $n_{1}$ and $n_{2}$ , the critical angle for reflection of an em wave is $\theta _{1C}$ . The $n_{2}$ material is replaced by another material having refractive index $n_{3}$ such that the critical angle at the interface between $n_{1}$ and $n_{3}$ materials is $\theta _{2C}$ . If $n_{3} > n_{2} > n_{1}; \frac{n_{2}}{n_{3}} = \frac{2}{5}$ and $sin\theta _{2C}-sin\theta _{1C} = \frac{1}{2}$ , then $\theta _{1C}$ is
a.
$sin^{-1} (\frac{1}{6} )$
b.
$sin^{-1} ( \frac{1}{3})$
c.
$sin^{-1} (\frac{-5}{6} )$
d.
$sin^{-1} ( \frac{2}{3})$
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Q27 mcq
The fractional compression $(\frac{\Delta V}{V})$ of water at the depth of 2.5 km below the sea level is ______ $%$ . Given, the Bulk modulus of water $= 2 \times 10^{9}\,N\,m^{-2}$ , density of water $= 10^{3} kgm^{-3}$ , acceleration due to gravity $= g = 10\,m\,s^{-2}$ .
a.
1.25
b.
1.0
c.
1.75
d.
1.5
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Q28 nat
The maximum speed of a boat in still water is $27\,km/h$ . Now this boat is moving downstream in a river flowing at $9\,km/h$ . A man in the boat throws a ball vertically upwards with speed of $10\,m/s$ . Range of the ball as observed by an observer at rest on the river bank, is _______ cm. (Take $g = 10\,m/s^{2}$ )
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Q29 mcq
A body of mass ' $m$ ' connected to a massless and unstretchable string goes in verticle circle of radius ' $R$ 'under gravity $g$ . The other end of the string is fixed at the center of circle. If velocity at top of circular path is $n\sqrt{gR}$ , where, $n⩾ 1$ , then ratio of kinetic energy of the body at bottom to that at top of the circle is
a.
$\frac{n^{2}}{n^{2}+4}$
b.
$\frac{n^{2}+4}{n^{2}}$
c.
$\frac{n+4}{n}$
d.
$\frac{n}{n+4}$
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Q30 mcq
Two projectiles are fired with same initial speed from same point on ground at angles of $(45^{\circ } - \alpha )$ and $(45^{\circ } +\alpha )$ , respectively, with the horizontal direction. The ratio of their maximum heights attained is :
a.
$\frac{1-tan\alpha}{1+tan\alpha}$
b.
$\frac{1-sin 2\alpha}{1+sin 2\alpha}$
c.
$\frac{1+sin 2\alpha}{1-sin 2\alpha}$
d.
$\frac{1+sin\alpha}{1-sin\alpha}$
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Q31 mcq
An electric dipole of mass m, charge q, and length $l$ is placed in a uniform electric field $\vec{E}= E_{0}\hat{i}$ . When the dipole is rotated slightly from its equilibrium position and released, the time period of its oscillations will be:
a.
$\frac{1}{2\pi}\sqrt{\,} \frac{ml}{2qE_{0}}$
b.
$2\pi \sqrt{\,} \frac{\,ml}{qE_{0}}$
c.
$\frac{1}{2\pi}\sqrt{\,} \frac{2\,ml}{qE_{0}}$
d.
$2\pi \sqrt{\,} \frac{\,ml}{2qE_{0}}$
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Q32 mcq
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Choke coil is simply a coil having a large inductance but a small resistance. Choke coils are used with fluorescent mercury-tube fittings. If household electric power is directly connected to a mercury tube, the tube will be damaged. Reason (R): By using the choke coil, the voltage across the tube is reduced by a factor $(R/\sqrt{R^{2}+\omega ^{2}L^{2}})$ , where $\omega$ is frequency of the supply across resistor $R$ and inductor L . If the choke coil were not used, the voltage across the resistor would be the same as the applied voltage. In the light of the above statements, choose the most appropriate answer from the options given below :
a.
$(A)$ is true but (R) is false
b.
Both (A) and (R) are true and (R) is the correct explanation of (A)
c.
(A) is false but (R) is true
d.
Both $(A)$ and $(R)$ are true but $(R)$ is not the correct explanation of $(A)$
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Q33 mcq
$\,List - I\, \,List - II\,$ $\,Electric field inside (distance\,r> 0\,from center)\,$ $\,(A)\,\,of a uniformly charged spherical shell with\, \,(I)\,\sigma /\epsilon _{0}$ $\,surface charge density\,\sigma , and radius R.\,$ $\,Electric field at distance r>0 from a uniformly\,$ $\,(B)\,\,charged infinite plane sheet with surface\, \,(II)\,\sigma /2\epsilon _{0}$ Match List - I with List - II. $\,charge density\,\sigma .$ Choose $\,Electric field outside (distance r>0 from center)\,$ $\,(C)\,\,of a uniformly charged spherical shell with\, \,(III)\,0$ $\,surface charge density\,\sigma , and radius R.\,$ $\,Electric field between\,2\,oppositely charged\,$ $\,(D)\,\,infinite plane parallel sheets with uniform\, \,(IV)\, \frac{\sigma R^{2}}{\epsilon _{0}r^{2}}$ $\,surface charge density\,\sigma .$ the correct answer from the options given below :
a.
(A)-(III), (B)-(II), (C)-(IV), (D)-(I)
b.
(A)-(IV), (B)-(II), (C)-(III), (D)-(I)
c.
(A)-(II), (B)-(I), (C)-(IV), (D)-(III)
d.
(A)-(IV), (B)-(I), (C)-(III), (D)-(II)
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Q34 mcq
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Emission of electrons in photoelectric effect can be suppressed by applying a sufficiently negative electron potential to the photoemissive substance. Reason (R) : A negative electric potential, which stops the emission of electrons from the surface of a photoemissive substance, varies linearly with frequency of incident radiation. In the light of the above statements, choose the most appropriate answer from the options given below :
a.
(A) is false but (R) is true
b.
(A) is true but (R) is false
c.
Both $(A)$ and $(R)$ are true and $(R)$ is the correct explanation of $(A)$
d.
Both $(A)$ and $(R)$ are true but $(R)$ is not the correct explanation of $(A)$
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Q35 mcq
Let u and $v$ be the distances of the object and the image from a lens of focal length $f$ . The correct graphical representation of $u$ and $v$ for a convex lens when $|u| >$ , is
Question 35 image
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Q36 mcq
For the circuit shown above, equivalent GATE is :
a.
OR gate
b.
NAND gate
c.
NOT gate
d.
AND gate
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Q37 mcq
The workdone in an adiabatic change in an ideal gas depends upon only :
a.
change in its temperature
b.
change in its volume
c.
change in its pressure
d.
change in its specific heat
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Q38 mcq
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Electromagnetic waves carry energy but not momentum. Reason ( $R$ ): Mass of a photon is zero. In the light of the above statements, choose the most appropriate answer from the options given below :
a.
Both (A) and (R) are true and (R) is the correct explanation of $(A)$
b.
Both $(A)$ and $(R)$ are true but $(R)$ is not the correct explanation of $(A)$
c.
(A) is false but (R) is true
d.
(A) is true but ( $R$ ) is false
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Q39 mcq
The expression given below shows the variation of velocity $(v)$ with time (t), $v= At^{2} + \frac{Bt}{C+t}$ . The dimension of ABC is :
a.
$[M^{0}\,L^{1}\,T^{-3}]$
b.
$[M^{0}\,L^{2}\,T^{-2}]$
c.
$[M^{0}\,L^{1}\,T^{-2}]$
d.
$[M^{0}\,L^{2}\,T^{-3}]$
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Q40 nat
The coordinates of a particle with respect to origin in a given reference frame is $(1, 1, 1)$ meters. If a force of $\vec{F}= \hat{i}- \hat{j}+ \hat{k}$ acts on the particle, then the magnitude of torque (with respect to origin) in z-direction is ______.
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Q41 nat
Two light beams fall on a transparent material block at point 1 and 2 with angle $\theta _{1}$ and $\theta _{2}'$ respectively, as shown in figure. After refraction, the beams intersect at point 3 which is exactly on the interface at other end of the block. Given : the distance between 1 and 2, $d = 4\,cm\sqrt{3}$ and $\theta _{1} =\theta _{2} = cos^{-1} (\frac{n_{2}}{2n_{1}})$ , where refractive index of the block $n_{2} >$ refractive index of the outside medium $n_{1}$ , then the thickness of the block is ________ cm.
Question 41 image
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Q42 nat
In a hydraulic lift, the surface area of the input piston is $6\,cm^{2}$ and that of the output piston is $1500\,cm^{2}$ . If 100 N force is applied to the input piston to raise the output piston by 20 cm, then the work done is _______ kJ.
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Q43 mcq
Consider a long straight wire of a circular cross-section (radius a) carrying a steady current I. The current is uniformly distributed across this cross-section. The distances from the centre of the wire's cross-section at which the magnetic field [inside the wire, outside the wire] is half of the maximum possible magnetic field, any where due to the wire, will be
a.
$[a/4, 3a/2]$
b.
$[a/4, 2a]$
c.
$[a/2, 2a]$
d.
$[a/2, 3a]$
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Q44 nat
A container of fixed volume contains a gas at $27^{\circ }C$ . To double the pressure of the gas, the temperature of gas should be raised to ______ $^{\circ }C$ .
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Q45 mcq
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Time period of a simple pendulum is longer at the top of a mountain than that at the base of the mountain. Reason (R): Time period of a simple pendulum decreases with increasing value of acceleration due to gravity and vice-versa. In the light of the above statements, choose the most appropriate answer from the options given below :
a.
Both $(A)$ and $(R)$ are true and $(R)$ is the correct explanation of $(A)$
b.
(A) is true but (R) is false
c.
(A) is false but (R) is true
d.
Both $(A)$ and $(R)$ are true but $(R)$ is not the correct explanation of $(A)$
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Q46 mcq
As shown below, bob $A$ of a pendulum having massless string of length ' $R$ ' is released from $60^{\circ }$ to the vertical. It hits another bob $B$ of half the mass that is at rest on a friction less table in the center. Assuming elastic collision, the magnitude of the velocity of bob A after the collision will be (take g as acceleration due to gravity.)
Question 46 image
a.
$\frac{4}{3}\sqrt{Rg}$
b.
$\frac{2}{3}\sqrt{Rg}$
c.
$\sqrt{Rg}$
d.
$\frac{1}{3}\sqrt{Rg}$
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Q47 mcq
A coil of area A and N turns is rotating with angular velocity $\omega$ in a uniform magnetic field $\vec{B}$ about an axis perpendicular to $\vec{B}$ . Magnetic flux $\phi$ and induced $emf\epsilon$ across it, at an instant when $\vec{B}$ is parallel to the plane of coil, are :
a.
$\phi = AB,\epsilon = 0$
b.
$\phi = 0,\epsilon = 0$
c.
$\phi = 0,\epsilon = NAB\omega$
d.
$\phi = AB,\epsilon = NAB\omega$
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Q48 mcq
If $\lambda$ and $K$ are de Broglie wavelength and kinetic energy, respectively, of a particle with constant mass. The correct graphical representation for the particle will be
Question 48 image
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Q49 mcq
Consider $I_{1}$ and $I_{2}$ are the currents flowing simultaneously in two nearby coils 1 & 2, respectively. If $L_{1} =$ self inductance of coil $1, M_{12} =$ mutual inductance of coil 1 with respect to coil 2, then the value of induced emf in coil 1 will be Options
a.
$\epsilon _{1} = -L_{1} \frac{dI_{2}}{dt} -M_{12} \frac{dI_{1}}{dt}$
b.
$\epsilon _{1} = -L_{1} \frac{dI_{1}}{dt} -M_{12} \frac{dI_{2}}{dt}$
c.
$\epsilon _{1} = -L_{1} \frac{dI_{1}}{dt} -M_{12} \frac{dI_{1}}{dt}$
d.
$\epsilon _{1} = -L_{1} \frac{dI_{1}}{dt} + M_{12} \frac{dI_{2}}{dt}$
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Q50 mcq
The pair of physical quantities not having same dimensions is :
a.
Pressure and Young's modulus
b.
Surface tension and impulse
c.
Torque and energy
d.
Angular momentum and Planck's constant
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Q51 nat
$|||$ Given below are some nitrogen containing compounds Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume _______ mg of HCl. (Given molar mass in $gmol^{-1}C : 12, H : 1, O : 16, Cl : 35.5$ )
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Q52 mcq
The correct increasing order of stability of the complexes based on $\Delta _{o}$ value is : I. $[Mn(CN)_{6}]^{3-}$ II. $[Co(CN)_{6}]^{4-}$ III. $[Fe(CN)_{6}]^{4-}$ IV. $[Fe(CN)_{6}]^{3-}$
a.
$IV < III < II < I$
b.
$I < II < IV <$ III
c.
III $<$ II $<$ IV $<$ I
d.
II $<$ III $<$ I $<$ IV
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Q53 nat
The sum of sigma $(\sigma )$ and pi $(\pi )$ bonds in Hex-1,3-dien-5-yne is _______.
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Q54 mcq
Total number of nucleophiles from the following is : $NH_{3}, PhSH, (H_{3}C)_{2}\,S, H_{2}C = CH_{2}, O H, H^{\ominus }_{3}O^{\oplus }, (CH_{3})_{2}CO,\rightleftharpoons NCH_{3}$
a.
7
b.
4
c.
6
d.
5
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Q55 nat
0.1 mole of compound ' S ' will weigh _______ g. (Given molar mass in $gmol^{-1}C : 12, H : 1, O : 16$ )
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Q56 mcq
The steam volatile compounds among the following are : (A) (B) (C) (D) Choose the correct answer from the options given below :
Question 56 image
a.
(B) and (D) Only
b.
(A) and (C) Only
c.
(A), (B) and (C) Only
d.
(A) and (B) Only
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Q57 mcq
$\,List - I\, \,List - II\,$ $\frac{\,(Carbohydrate)\,}{\,Amylose\,} \,(Linkage Source)\,$ $\,(A)\, \,(I)\,\beta - C_{1}- C_{4}, plant\,$ Match List - I with List - II. Choose the $\,(B)\, \,Cellulose\, \,(II)\,\alpha - C_{1}- C_{4}, \,animal\,$ $\,(C)\, \,Glycogen\, \,(III)\,\alpha - C_{1}- C_{4},\alpha - C_{1}- C_{6}, \,plant\,$ $\,(D)\, \,Amylopectin\, \,(IV)\,\alpha - C_{1}- C_{4}, \,plant\,$ correct answer from the options given below :
a.
(A)-(IV), (B)-(I), (C)-(III), (D)-(II)
b.
(A)-(III), (B)-(II), (C)-(I), (D)-(IV)
c.
(A)-(II), (B)-(III), (C)-(I), (D)-(IV)
d.
(A)-(IV), (B)-(I), (C)-(II), (D)-(III)
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Q58 mcq
Given below are two statements : Statement ( $I$ ): The radii of isoelectronic species increases in the order. $Mg^{2+} < Na^{+} < F^{-} < O^{2-}$ Statement (II): The magnitude of electron gain enthalpy of halogen decreases in the order. $Cl > F > Br > I$ In the light of the above statements, choose the most appropriate answer from the options given below :
a.
Statement I is incorrect but Statement II is correct
b.
Statement I is correct but Statement II is incorrect
c.
Both Statement I and Statement II are incorrect
d.
Both Statement I and Statement II are correct
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Q59 mcq
An element ' $E'$ has the ionisation enthalpy value of $374\,kJ\,mol^{-1}$ . ' $E$ ' reacts with elements $A, B, C$ and D with electron gain enthalpy values of $-328, -349, -325$ and $-295\,kJ\,mol^{-1}$ , respectively. The correct order of the products EA, EB, EC and ED in terms of ionic character is :
a.
$ED > EC > EB > EA$
b.
$EA > EB > EC > ED$
c.
$EB > EA > EC > ED$
d.
$ED > EC > EA > EB$
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Q60 mcq
Choose the correct statements. (A) Weight of a substance is the amount of matter present in it. (B) Mass is the force exerted by gravity on an object. (C) Volume is the amount of space occupied by a substance. (D) Temperatures below $0^{\circ }C$ are possible in Celsius scale, but in Kelvin scale negative temperature is not possible. (E) Precision refers to the closeness of various measurements for the same quantity. Choose the correct answer from the options given below :
a.
(A), (D) and (E) Only
b.
(C), (D) and (E) Only
c.
(A), (B) and (C) Only
d.
(B), (C) and (D) Only
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Q61 mcq
If $a_{0}$ is denoted as the Bohr radius of hydrogen atom, then what is the de-Broglie wavelength $(\lambda )$ of the electron present in the second orbit of hydrogen atom? [n : any integer]
a.
$\frac{8\pi a_{0}}{n}$
b.
$\frac{2a_{0}}{n\pi}$
c.
$\frac{4n}{\pi a_{0}}$
d.
$\frac{4\pi a_{0}}{n}$
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Q62 nat
If $A_{2}B$ is $30%$ ionised in an aqueous solution, then the value of van't Hoff factor (i) is ______ $\times 10^{-1}$ .
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Q63 mcq
At temperature T, compound $AB_{2(\,g)}$ dissociates as $AB_{2(\,g)} \rightleftharpoons AB_{(g)}+ \frac{1}{2}\,B_{2(\,g)}$ having degree of dissociation $x$ (small compared to unity). The correct expression for $x$ in terms of $K_{p}$ and p is
a.
$\sqrt{\,} ^{4} \frac{2K_{p}}{p}$
b.
$\sqrt{\,} ^{3} \frac{2K_{p}}{p}$
c.
$\sqrt{\,} ^{3} \frac{2\,K^{2}_{p}}{p}$
d.
$\sqrt{K}_{p}$
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Q64 mcq
$A_{2}k_{1}\,A + A\,(fast)\,$ $k_{-1}$ The reaction $A_{2}+ B_{2} \rightarrow 2AB\rightarrow$ follows the mechanism $k_{2}$ The overall order of the $-A + B_{2} \rightarrow \rightarrow AB+ B\,(slow)\,$ $A + B \rightarrow AB\,(fast)\,\rightarrow$ reaction is :
a.
2
b.
2.5
c.
3
d.
1.5
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Q65 mcq
The correct option with order of melting points of the pairs $(Mn, Fe), (Tc, Ru)$ and $(Re, Os)$ is :
a.
$Fe < Mn, Ru < Tc$ and $Re < Os$
b.
$Mn < Fe, Tc < Ru$ and $Os < Re$
c.
$Mn < Fe, Tc < Ru$ and $Re < Os$
d.
$Fe < Mn, Ru < Tc$ and $Os < Re$
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Q66 mcq
Match List - I with List - II. Choose the correct answer from the options given below :
a.
(A)-(II), (B)-(III), (C)-(IV), (D)-(I)
b.
(A)-(II), (B)-(III), (C)-(I), (D)-(IV)
c.
(A)-(III), (B)-(II), (C)-(I), (D)-(IV)
d.
(A)-(III), (B)-(II), (C)-(IV), (D)-(I)
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Q67 mcq
The product $(P)$ formed in the following reaction is :
Question 67 image
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Q68 mcq
The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.
a.
$E^{\ominus }_{Pb^{4+}/Pb^{2+}} = +1.67\,V$
b.
$E^{\ominus }_{Sn^{4+}/Sn^{2+}} = +1.15\,V$
c.
$E^{\ominus }_{Al^{3+}/Al} = -1.66\,V$
d.
$E^{\ominus }_{T1}/Tl/2.26\,V$
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Q69 mcq
In the following substitution reaction: product $'P'$ formed is :
Question 69 image
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Q70 nat
The molar mass of the water insoluble product formed from the fusion of chromite ore $(FeCr_{2}O_{4})$ with $Na_{2}CO_{3}$ in presence of $O_{2}$ is _______ $gmol^{-1}$ .
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Q71 mcq
$\,List - I\, \,List - II\,$ $\,(Complex)\, \,(Hybridisation & Magnetic characters)\,$ $(A) [MnBr_{4}]^{2-} (I) d^{2}s^{3}\,& diamagnetic$ Match List - I with List - II. $(B) [FeF_{6}]^{3-} (II) sp^{3}\,d^{2}\,& paramagnetic$ $(C) [Co(C_{2}O_{4})_{3}]^{3-} (III) sp^{3}\,& diamagnetic$ $(D) [Ni(CO)_{4}] (IV) sp^{3}\,& paramagnetic$ Choose the correct answer from the options given below :
a.
(A) $-(IV), (B) -(II), (C) -(I), (D) -(III)$
b.
$(A) -(III), (B) -(I), (C) -(II), (D) -(IV)$
c.
(A) $-(IV), (B) -(I), (C) -(II), (D) -(III)$
d.
$(A) -(III), (B) -(II), (C) -(I), (D) -(IV)$
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Q72 mcq
The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed ?
a.
A small decrease in molar conductivity is observed at infinite dilution.
b.
Molar conductivity decreases sharply with increase in concentration.
c.
A small increase in molar conductivity is observed at infinite dilution.
d.
Molar conductivity increases sharply with increase in concentration.
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Q73 mcq
J of energy is transferred as heat to 0.5 mol of Argon gas at 298 K and 1.00 atm. The final temperature and the change in internal energy respectively are: Given : $R = 8.3\,J\,K^{-1}\,mol^{-1}$
a.
378 K and 500 J
b.
368 K and 500 J
c.
348 K and 300 J
d.
378 K and 300 J
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Q74 mcq
For a $Mg Mg^{2+}(aq) Ag^{+}(aq) Ag$ the correct Nernst Equation is :
a.
$E_{cell\,} = E^{o}_{cell\,} - \frac{RT}{2\,F} ln \frac{[Ag^{+}]}{[Mg^{2+}]}$
b.
$2$ $E_{cell\,} = E^{o}_{cell\,} + \frac{RT}{2\,F}ln \frac{[Ag^{+}]}{[Mg^{2+}]}$
c.
$E_{cell\,} = E^{o}_{cell\,} - \frac{RT}{2\,F} ln \frac{[Ag^{+}]^{2}}{[Mg^{2+}]}$
d.
$E_{cell\,} = E^{o}_{cell\,} - \frac{RT}{2\,F}ln \frac{[Mg^{2+}]}{[Ag^{+}]}$
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Q75 mcq
1.24 g of $AX_{2}$ (molar mass $124\,g\,mol^{-1}$ ) is dissolved in 1 kg of water to form a solution with boiling point of $100.0156^{\circ }C$ , while $25.4\,g^{\circ }$ of $AY_{2}$ (molar mass $250\,g\,mol^{-1}$ ) in 2 kg of water constitutes a solution with a boiling point of $100.0260^{\circ }C$ . $K_{b}(H_{2}O) = 0.52\,K\,kg\,mol^{-1}$ Which of the following is correct ?
a.
$AX_{2}$ is fully ionised while $AY_{2}$ is completely unionised.
b.
$AX_{2}$ is completely unionised while $AY_{2}$ is fully ionised.
c.
$AX_{2}$ and $AY_{2}$ (both) are completely unionised.
d.
$AX_{2}$ and $AY_{2}$ (both) are fully ionised.
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