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JEE Main 2014 (11 Apr Online)

2014 · 90 questions · First 10 Solutions Free
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Q1 mcq
An object is located in a fixed position in front of a screen. Sharp image is obtained on the screen for two positions of a thin lens separated by 10 $cm$ . The size of the images in two situations are in the ratio $3 : 3$ . What is the distance between the screen and the object?
a.
$124.5\,cm$
b.
$144.5\,cm$
c.
$65.0\,cm$
d.
$99.0\,cm$ Correct Answer

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Q2 mcq
A cone of base radius $R$ and height $h$ is located in a uniform electric field $\vec{E}$ parallel to its base. The electric flux entering the cone is:
a.
$\frac{1}{2}EhR$
b.
EhR Correct Answer
c.
$2EhR$
d.
$4EhR$

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Q3 mcq
The bulk moduli of ethanol, mercury and water are given as $0.9, 25$ and $2.2$ respectively in units of $10^{9}Nm^{-2}$ . For a given value of pressure, the fractional compression in volume is $\frac{\Delta V}{V}$ . Which of the following statements about $\frac{\Delta V}{V}$ for these three liquids is correct ?
a.
Ethanol $>$ Water $>$ Mercury Correct Answer
b.
Water $>$ Ethanol $>$ Mercury
c.
Mercury $>$ Ethanol $>$ Water
d.
Ethanol $>$ Mercury $>$ Water

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Q4 mcq
A hot body, obeying Newton's law of cooling is cooling down from its peak value $80^{\circ }C$ to an ambient temperature of $30^{\circ }C$ . It takes 5 minutes in cooling down from $80^{\circ }C$ to $40^{\circ }C$ . How much time will it take to cool down from $62^{\circ }C$ to $32^{\circ }C$ ? (Given $In 2 = 0.693$ , In $5 = 1.609$ )
a.
$3.75$ minutes
b.
$8.6$ minutes Correct Answer
c.
$9.6$ minutes
d.
$6.5$ minutes

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Q5 mcq
The average mass of rain drops is $3.0 \times 10^{-5}\,kg$ and their avarage terminal velocity is $9\,m/s$ . Calculate the energy transferred by rain to each square metre of the surface at a place which receives $100\,cm$ of rain in a year.
a.
$3.5 \times 10^{5}\,J$
b.
$4.05 \times 10^{4}\,J$ Correct Answer
c.
$3.0 \times 10^{5}\,J$
d.
$9.0 \times 10^{4}\,J$

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Q6 mcq
Match the List-I (Phenomenon associated with electromagnetic radiation) with List-II (Part of electromagnetic spectrum) and select the correct code from the choices given below this lists:
Question 6 image
a.
(I)-(A), (II)-(B), (III)-(B),,(IV)-(C)
b.
(I)-(A), (II)-(B), (III)-(C), (IV)-(C)
c.
(I)-(D), (II)-(C), (III)-(A), (IV)-(B)
d.
(I)-(B), (II)-(A), (III)-(D), (IV)-(A) Correct Answer

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Q7 mcq
Three identical bars A, B and C are made of different magnetic materials. When kept in a uniform magnetic field, the field lines around them look as follows: Make the correspondence of these bars with their material being diamagnetic ( $D)$ , ferromagnetic (F) and paramagnetic $(P)$ :
Question 7 image
a.
$A \leftrightarrow D, B \leftrightarrow P, C \leftrightarrow F$
b.
$A \leftrightarrow F, B \leftrightarrow D, C \leftrightarrow P$ Correct Answer
c.
$A \leftrightarrow P, B \leftrightarrow F, C \leftrightarrow D$
d.
$A \leftrightarrow F, B \leftrightarrow P, C \leftrightarrow D$

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Q8 mcq
An electromagnetic wave of frequency $1 \times 10^{14}$ hertz is propagating along $z$ -axis. The amplitude of electric field is $4\,V/m$ . If $\epsilon _{0} = 8.8 \times 10^{-12}C^{2}/N-m^{2}$ , then average energy density of electric field will be:
a.
$35.2 \times 10^{-10}\,J/m^{3}$
b.
$35.2 \times 10^{-11}\,J/m^{3}$
c.
$35.2 \times 10^{-12}\,J/m^{3}$ Correct Answer
d.
$35.2 \times 10^{-13}\,J/m^{3}$

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Q9 mcq
From a sphere of mass $M$ and radius $R$ , a smaller sphere of radius $\frac{R}{2}$ is carved out such that the cavity made in the original sphere is between its centre and the periphery (See figure). For the configuration in the figure where the distance between the centre of the original sphere and the removed sphere is 3R, the gravitational force between the two sphere is:
Question 9 image
a.
$\frac{41GM^{2}}{3600R^{2}}$ Correct Answer
b.
$\frac{41GM^{2}}{450R^{2}}$
c.
$\frac{59GM^{2}}{450R^{2}}$
d.
$\frac{GM^{2}}{225R^{2}}$

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Q10 mcq
A photon of wavelength $\lambda$ is scattered from an electron, which was at rest. The wavelength shift $\Delta \lambda$ is three times of $\lambda$ and the angle of scattering $\theta$ is $60^{\circ }$ . The angle at which the electron recoiled is $\phi$ . The value of $tan\phi$ is : (electron speed is much smaller than the speed of light)
a.
$0.16$
b.
$0.22$ Correct Answer
c.
$0.25$
d.
$0.28$

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Q11 mcq
An ideal monoatomic gas is confined in a cylinder by a spring loaded piston of cross section $8.0 \times 10^{-3}\,m^{2}$ . Initially the gas is at $300\,K$ and occupies a volume of $2.4 \times 10^{-3}\,m^{3}$ and the spring is in its relaxed state as shown in figure. The gas is heated by a small heater until the piston moves out slowly by $0.1\,m$ . The force constant of the spring is $8000\,N/m$ and the atmospheric pressure is $1.0 \times 10^{5}\,N/m^{2}$ . The cylinder and the piston are thermally insulated. The piston and the spring are massless and there is no friction between the piston and the cylinder. The final temperature of the gas will be: (Neglect the heat loss through the lead wires of the heater. The heat capacity of the heater coil is also negligible).
Question 11 image
a.
$300\,K$
b.
$800\,K$
c.
$500\,K$
d.
$1000\,K$
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Q12 mcq
Three straight parallel current carrying conductors are shown in the figure. The force experienced by the middle conductor of length $25\,cm$ is:
Question 12 image
a.
$3 \times 10^{-4}\,N$ toward right
b.
$6 \times 10^{-4}\,N$ toward right
c.
$9 \times 10^{-4}\,N$ toward right
d.
Zero
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Q13 mcq
The initial speed of a bullet fired from a rifle is $630\,m/s$ . The rifle is fired at the centre of a target $700\,m$ away at the same level as the target. How far above the centre of the target ?
a.
$1.0\,m$
b.
$4.2\,m$
c.
$6.1\,m$
d.
$9.8\,m$
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Q14 mcq
In terms of resistance $R$ and time $T$ , the dimensions of ratio $_{\epsilon }$ of the permeability $\mu$ and permittivity $\epsilon$ is:
a.
$[RT^{-2}]$
b.
$[R^{2}\,T^{-1}]$
c.
$[R^{2}]$
d.
$[R^{2}\,T^{2}]$
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Q15 mcq
The angular frequency of the damped oscillator is given by, $\omega =\sqrt{\,} (\frac{k}{m} - \frac{r^{2}}{4\,m^{2}})$ where $k$ is the spring constant, $m$ is the mass of the oscillator and $r$ is the damping constant. If the ratio $\frac{r^{2}}{mk}$ is $8%$ , the change in time period compared to the undamped oscillator is approximately as follows:
a.
increases by $1%$
b.
increases by $8%$
c.
decreases by $1%$
d.
decreases by $8%$
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Q16 mcq
In the circuit diagrams (A, B, C and D) shown below, $R$ is a high resistance and $S$ is a resistance of the order of galvanometer resistance G. The correct circuit, corresponding to the half deflection method for finding the resistance and figure of merit of the galvanometer, is the circuit labelled as: (a) (b) (C) (d)
Question 16 image
a.
Circuit A with $G = \frac{RS}{(R-S)}$
b.
Circuit B with $G = S$
c.
Circuit $C$ with $G = S$
d.
Circuit $D$ with $G= \frac{RS}{(R-S})$
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Q17 mcq
Two monochromatic light beams of intensity 16 and 9 units are interfering. The ratio of intensities of bright and dark parts of the resultant pattern is:
a.
$\frac{16}{9}$
b.
$\frac{4}{3}$
c.
$\frac{7}{1}$
d.
$\frac{49}{1}$
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Q18 mcq
A coil of circular cross-section having 1000 turns and $4\,cm^{2}$ face area is placed with its axis parallel to a magnetic field which decreases by $10^{-2}\,Wb m^{-2}$ in $0.01\,s$ . The e.m.f. induced in the coil is:
a.
$400mV$
b.
$200mV$
c.
$4mV$
d.
$0.4mV$
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Q19 mcq
A thin bar of length $L$ has a mass per unit length $\lambda$ , that increases linearly with distance from one end. If its total mass is $M$ and its mass per unit length at the lighter end is $\lambda _{O}$ , then the distance of the centre of mass from the lighter end is:
a.
$\frac{L}{2} - \frac{\lambda _{0}\,L^{2}}{4M}$
b.
$\frac{L}{3} + \frac{\lambda _{0}\,L^{2}}{8M}$
c.
$\frac{L}{3} + \frac{\lambda _{0}\,L^{2}}{4M}$
d.
$\frac{2\,L}{3} - \frac{\lambda _{0}\,L^{2}}{6M}$
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Q20 mcq
During an adiabatic compression, $830\,J$ of work is done on 2 moles of a diatomic ideal gas to reduce its volume by $50%$ . The change in its temperature is nearly: $(R = 8.3JK^{-1}\,mol^{-1})$
a.
$40\,K$
b.
$33\,K$
c.
$20\,K$
d.
$14\,K$
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Q21 mcq
In the circuit shown, current (in A) through $50\,V$ and $30\,V$ batteries are, respectively:
Question 21 image
a.
$2.5$ and 3
b.
$3.5$ and 2
c.
$4.5$ and 1
d.
3 and $2.5$
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Q22 mcq
Two factories are sounding their sirens at 800 $Hz$ . A man goes from one factory to other at a speed of $2\,m/s$ . The velocity of sound is $320\,m/s$ . The number of beats heard by the person in one second will be:
a.
2
b.
4
c.
8
d.
10
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Q23 mcq
A tank with a small hole at the bottom has been filled with water and kerosene (specific gravity $0.8$ ). The height of water is $3\,m$ and that of kerosene $2\,m$ . When the hole is opened the velocity of fluid coming out from it is nearly: (take $g = 10\,ms^{-2}$ and density of water $= 10^{3}\,kg\,m^{-3})$
a.
$10.7\,ms^{-1}$
b.
$9.6\,ms^{-1}$
c.
$8.5\,ms^{-1}$
d.
$7.6\,ms^{-1}$
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Q24 mcq
A parallel plate capacitor is made of two plates of length 1 , width $w$ and separated by distance $d$ . A dielectric slab (dielectric constant $K$ ) that fits exactly between the plates is held near the edge of the plates. It is pulled into the capacitor by a force $F = -\frac{∂U}{∂x}$ where $U$ is the energy of the capacitor when dielectric is inside the capacitor up to distance $x$ (See figure). If the charge on the capacitor is Q then the force on the dielectric when it is near the edge is:
Question 24 image
a.
$\frac{Q^{2}\,d}{2wl^{2}\epsilon _{o}}K$
b.
$\frac{Q^{2}\,W}{2dl^{2}\epsilon _{0}}(\,K -1)$
c.
$\frac{Q^{2}\,d}{2wl^{2}\epsilon _{o}}(K -1)$
d.
$\frac{Q^{2}w}{2dl^{2}\epsilon _{o}}K$
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Q25 mcq
A small ball of mass $m$ starts at a point $A$ with speed $v_{o}$ and moves along a frictionless track $AB$ as shown. The track $BC$ has coefficient of friction $\mu$ . The ball comes to stop at $C$ after travelling a distance $L$ which is:
Question 25 image
a.
$\frac{2\,h}{\mu} + \frac{v^{2}_{o}}{2\mu g}$
b.
$\frac{h}{\mu} + \frac{v^{2}_{0}}{2\mu g}$
c.
$\frac{h}{2\mu} + \frac{v2o}{\mu g}$
d.
$\frac{h}{2\mu} + \frac{v^{2}_{o}}{2\mu g}$
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Q26 mcq
A body of mass $5\,kg$ under the action of constant force $\vec{F} =F_{x}\hat{i}+F_{y}\hat{j}$ has velocity at $t = 0\,s$ as $\vec{v}= (6\hat{i}-2\hat{j}m/s)$ and at $t = 10\,s$ as $\vec{v}= +6\hat{j}m/s$ . The force $\vec{F}$ is:
a.
$(-3\hat{i}+ 4\hat{j})N$
b.
$(-\frac{3}{5}\hat{i}+ \frac{4}{5}\hat{j})N$
c.
$(3\hat{i}-4\hat{j})N$
d.
$(\frac{3}{5}\hat{i}- \frac{4}{5}\hat{j})N$
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Q27 mcq
A radioactive nuclei with decay constant $0.5/s$ is being produced at a constant rate of 100 nuclei/s. If at $t= 0$ there were no nuclei, the time when there are 50 nuclei is:
a.
$1\,s$
b.
$2 ln( \frac{4}{3})s$
c.
$ln 2\,s$
d.
$ln(\frac{4}{3})s$
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Q28 mcq
A Zener diode is connected to a battery and a load as show below: The currents, $I, I_{Z}$ and $I_{L}$ are respectively.
Question 28 image
a.
$15\,mA, 5\,mA, 10\,mA$
b.
$15\,mA, 7.5\,mA, 7.5\,mA$
c.
$12.5\,mA, 5\,mA, 7.5\,mA$
d.
$12.5\,mA, 7.5\,mA, 5\,mA$
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Q29 mcq
An air bubble of radius $0.1\,cm$ is in a liquid having surface tension $0.06\,N/m$ and density $10^{3}\,kg/m^{3}$ . The pressure inside the bubble is $1100Nm^{-2}$ greater than the atmospheric pressure. At what depth is the bubble below the surface of the liquid? $(g = 9.8\,ms^{-2})$
a.
$0.1\,m$
b.
$0.15\,m$
c.
$0.20\,m$
d.
$0.25\,m$
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Q30 mcq
In a compound microscope the focal length of objective lens is $1.2\,cm$ and focal length of eye piece is $3.0\,cm$ . When object is kept at $1.25\,cm$ in front of objective, final image is formed at infinity. Magnifying power of the compound microscope should be:
a.
200
b.
100
c.
400
d.
150
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Q31 mcq
Consider the coordination compound, $[Co(NH_{3})_{6}]Cl_{3}$ . In the formation of this complex, the species which acts as the Lewis acid is:
a.
$[Co(NH_{3})_{6}]^{3+}$
b.
$Cl^{-}$
c.
$Co^{3+}$
d.
$NH_{3}$
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Q32 mcq
The molar heat capacity $(C_{p})$ of $CD_{2}O$ is 10 cals at $1000\,K$ . The change in entropy associated with cooling of $32\,g$ of $CD_{2}O$ vapour from $1000\,K$ to $100\,K$ at constant pressure will be: $(D =$ deuterium, atomic mass $= 2u)$
a.
$23.03caldeg^{-1}$
b.
$-23.03caldeg^{-1}$
c.
$2.303caldeg^{-1}$
d.
$-2.303caldeg^{-1}$
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Q33 mcq
If $\lambda _{0}$ and $\lambda$ be threshold wavelength and wavelength of incident light, the velocity of photoelectron ejected from the metal surface is:
a.
$\sqrt{\frac{2h}{m}}(\lambda _{0}- \lambda )$
b.
$\sqrt{\frac{2hc}{m}}(\lambda _{o}- \lambda )$
c.
$\sqrt{\frac{2hc}{m}}(\frac{\lambda _{0}-\lambda}{\lambda \lambda _{0}})$
d.
$\sqrt{\frac{2h}{m}} (\frac{1}{\lambda _{o}} - \frac{1}{\lambda})$
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Q34 mcq
In allene $(C_{3}H_{4})$ , the type(s) of hybridization of the carbon atoms is (are) :
a.
$sp$ and $sp^{3}$
b.
$sp^{2}$ and $sp$
c.
only $sp^{2}$
d.
$sp^{2}$ and $sp^{3}$
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Q35 mcq
In the reaction of formation of sulphur trioxide by contact process $2SO_{2}+ O_{2} \rightleftharpoons 2SO_{3}$ the rate of reaction was measured as $\frac{d[O_{2}]}{dt} = -2.5 \times 10^{-4}\,mol\,L^{-1}\,s^{-1}$ . The rate of reaction is terms of $[SO_{2}]$ in $molL^{-1}\,s^{-1}$ will be:
a.
$-1.25 \times 10^{-4}$
b.
$-2.50 \times 10^{-4}$
c.
$-3.75 \times 10^{-4}$
d.
$-5.00 \times 10^{-4}$
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Q36 mcq
For the reaction, $2\,N_{2}O_{5} 4NO_{2}+ O_{2}$ , the rate equation can be expressed in two ways $- \frac{d[N_{2}O_{5}]}{dt} = k [N_{2}O_{5} ]n\vec{n}d +\frac{d[NO_{2}]}{dt} = k' [N_{2}O_{5}] k$ and $k'$ are related as:
a.
$k = k'$
b.
$2k = k'$
c.
$k = 2k'$
d.
$k = 4k'$
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Q37 mcq
The gas liberated by the electrolysis of Dipotassium succinate solution is:
a.
Ethane
b.
Ethyne
c.
Ethene
d.
Propene
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Q38 mcq
Shapes of certain interhalogen compounds are stated below. Which one of them is not correctly stated?
a.
$IF_{7}$ : pentagonal bipyramid
b.
$BrF_{5}$ : trigonal bipyramid
c.
$BrF_{3}$ : planar T-shaped
d.
$ICI_{3}$ : planar dimeric
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Q39 mcq
Complete reduction of benzene-diazonium chloride with $Zn/HCl$ gives:
a.
Aniline
b.
Phenylhydrazine
c.
Azobenzene
d.
Hydrazobenzene
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Q40 mcq
Given $Fe^{3+}(aq) + e^{-} \rightarrow Fe\rightarrow^{2+}(aq); E^{0} = +0.77\,V$ $Al^{3+}(aq) + 3e^{-} \rightarrow Al(s); E\rightarrow^{0} = -1.66\,V$ $Br_{2}(aq) + 2e^{-} \rightarrow 2Br\rightarrow^{-}; E^{0} = +1.09\,V$ Considering the electrode potentials, which of the following represents the correct order of reducing power?
a.
$Fe^{2+} < Al< Br^{-}$
b.
$Br^{-} < Fe^{2+} < Al$
c.
$Al < Br^{-} < Fe^{2+}$
d.
$Al < Fe^{2+} < Br^{-}$
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Q41 mcq
Based on the equation: $\Delta E = -2.0 \times 10^{-18}\,J(\frac{1}{n^{2}} - \frac{1}{n^{2}})$ $2 1$ the wavelength of the light that must be absorbed to excite hydrogen electron from level $n= 1$ to level $n = 2$ will be: $(h = 6.625 \times 10^{-34}Js, C = 3 \times 10^{8}\,ms^{-1})$
a.
$1.325 \times 10^{-7}\,m$
b.
$1.325 \times 10^{-10}\,m$
c.
$2.650 \times 10^{-7}\,m$
d.
$5.300 \times 10^{-10}\,m$
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Q42 mcq
The initial volume of a gas cylinder is $750.0\,mL$ . If the pressure of gas inside the cylinder changes from $840.0\,mmHg$ to $360.0\,mmHg$ , the final volume the gas will be:
a.
$1.750\,L$
b.
$3.60\,L$
c.
$4.032\,L$
d.
$7.50\,L$
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Q43 mcq
Consider the following equilibrium $AgCl ↓+2NH_{3} \rightleftharpoons [Ag(NH_{3}2_{2}]^{+} + Cl^{-}$ White precipitate of $AgCl$ appears on adding which of the following?
a.
$NH_{3}$
b.
aqueous $NaCl$
c.
aqueous $HNO_{3}$
d.
aqueous $NH_{4}Cl$
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Q44 mcq
Which one of the following statements is not correct?
Question 44 image
a.
Alcohols are weaker acids than water
b.
Acid strength of alcohols decreases in the following $RCH_{2}OH > R_{2}CHOH > R_{3}COH$
c.
Carbon-oxygen bond length in methanol, $CH_{3}OH$ is shorter than that of $C -O$ bond length in phenol.
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Q45 mcq
A gaseous compound of nitrogen and hydrogen contains $12.5%$ (by mass) of hydrogen. The density of the compound relative to hydrogen is 16. The molecular formula of the compound is:
a.
$NH_{2}$
b.
$N_{3}H$
c.
$NH_{3}$
d.
$N_{2}H_{4}$
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Q46 mcq
Chlorobenzne reacts with trichloro acetaldehyde in the presence of $H_{2}SO_{4}$ . The major product formed is:
Question 46 image
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Q47 mcq
An organic compound $A, C_{5}H_{8}O$ ; reacts with $H_{2}O, NH_{3}$ and $CH_{3}COOH$ as described below:
Question 47 image
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Q48 mcq
Which of the following statements about the depletion of ozone layer is correct?
a.
The problem of ozone depletion is less serious at The problem of ozone depletion is more serious poles because $NO_{2}$ solidifies and is not available at poles because ice crystals in the clouds over for consuming $CIO^{\circ }$ radicals. poles act as catalyst for photochemical reactions involving the decomposition of ozone of $Cl^{\cdot }$ and $CIO^{\cdot }$ radicals.
c.
Freons, chlorofluorocarbons, are inert. Oxides of nitrogen also do not react with ozone Chemically, they do not react with ozone in in stratosphere. stratosphere.
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Q49 mcq
Which of the following name formula combinations is not correct?
a.
$K_{2}[Pt(CN)_{4}]$ - Potassium tetracyanoplatinate (II)
b.
$[Mn(CN)_{5}]^{2-}$ - Pentacyanomagnate (II) ion
c.
$K [Cr(NH_{3})_{2}Cl_{4}]$ - Potassium diammine tetrachlorochromate (III)
d.
$[Co(NH_{3})_{4}(H_{2}O)I]SO_{4}$ - Magnetron value.
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Q50 mcq
Assuming that the degree of hydrolysis is small, the $pH$ of $0.1M$ solution of sodium acetate $(K_{a} = 1.0 \times 10^{-5})$ will be:
a.
$5.0$
b.
$6.0$
c.
$8.0$
d.
$9.0$
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Q51 mcq
Which of the following series correctly represents relations between the elements from $X$ to $Y$ ? $X \rightarrow Y\rightarrow$
a.
$_{3}Li \rightarrow \rightarrow_{19}\,K$ Ionization enthalpy increases
b.
$_{9}\,F \rightarrow \rightarrow_{35}Br$ Electron gain enthalpy (negative sign) increases
c.
$_{6}C \rightarrow \rightarrow_{32}Ge$ Atomic radii increases
d.
$_{18}Ar \rightarrow \rightarrow_{54}Xe$ Noble character increases
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Q52 mcq
The following reaction is known as:
a.
Perkin reaction
b.
Gatterman-Koch Formylation
c.
Kolbe's reaction
d.
Gattermann reaction
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Q53 mcq
The correct order of bond dissociation energy among $N_{2}, O_{2}, O^{-}_{2}$ is shown in which of the following arrangements?
a.
$N_{2} > O^{-}_{2} > O_{2}$
b.
$O^{-}_{2} > O_{2} > N_{2}$
c.
$N_{2} > O_{2} > O^{-}_{2}$
d.
$O_{2} > O^{-}_{2} > N_{2}$
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Q54 mcq
Which of the following statements about $Na_{2}O_{2}$ is not correct?
a.
It is diamagnetic in nature
b.
It is derivative of $H_{2}O_{2}$
c.
$Na_{2}O_{2}$ oxidises $Cr^{3+}$ to $CrO^{2-}_{4}$ in acid medium.
d.
It is the super oxide of sodium
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Q55 mcq
Which one of the following is used as Antihistamine?
a.
Omeprazole
b.
Chloranphenicol
c.
Diphenhydramine
d.
Norethindrone
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Q56 mcq
The appearance of colour in solid alkali metal halides is generally due to:
a.
Schottky defect
b.
Frenkel defect
c.
Interstitial position
d.
F-centres
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Q57 mcq
The reagent needed for converting
a.
Cat. Hydrogenation
b.
$H_{2}$ /Lindlar Cat.
c.
$Li/NH_{3}$
d.
$LiAlH_{4}$
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Q58 mcq
In some solutions, the concentration of $H_{3}O^{+}$ remains constant even when small amounts of strong acid or strong base are added to them. These solutions are known as:
a.
Ideal solutions
b.
Colloidal solutions
c.
True solutions
d.
Buffer solutions
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Q59 mcq
Tischenko reaction is a modification of:
a.
Aldol condensation
b.
Claisen condensation
c.
Cannizzaro reaction
d.
Pinacol-pinacolon reaction
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Q60 mcq
Which one of the following does not have a pyramidal shape?
a.
$(CH_{3})_{3}\,N$
b.
$(SiH_{3})_{3}\,N$
c.
$P(CH_{3})_{3}$
d.
$P(SiH_{3})_{3}$
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Q61 mcq
Let $f$ be an odd function defined on the set of real numbers such that for $x \geq 0$ , $f(x) = 3 sinx+ 4 cosx$ . Then $f(x)$ at $x = -\frac{11\pi}{6}$ is equal to:
a.
$\frac{3}{2} + 2\sqrt{3}$
b.
$- \frac{3}{2} + 2\sqrt{3}$
c.
$\frac{3}{2} -2\sqrt{3}$
d.
$- \frac{3}{2} -2\sqrt{3}$
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Q62 mcq
Two ships A and B are sailing straight away from a fixed point $O$ along routes such that $\angle AOB$ is always $120^{\circ }$ . At a certain instance, $OA = 8\,km, OB = 6\,km$ and the ship $A$ is sailing at the rate of $20\,km/hr$ while the ship B sailing at the rate of $30\,km/hr$ . Then the distance between $A$ and $B$ is changing at the rate (in $km/hr$ ):
a.
$\frac{260}{\sqrt{37}}$
b.
$\frac{260}{37}$
c.
$\frac{80}{\sqrt{37}}$
d.
$\frac{80}{37}$
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Q63 mcq
If $X$ has a binomial distribution, $B(n,p)$ with parameters $n$ and $p$ such that $P(X = 2) =P(X = 3)$ , then $E(X)$ , the mean of variable $X$ , is
a.
$2 -p$
b.
$3 - p$
c.
$\frac{p}{2}$
d.
$\frac{p}{3}$
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Q64 mcq
The set of all real values of $\lambda$ for which exactly two common tangents can be drawn to the circles $x^{2} +y^{2} -4x-4y+ 6 = 0$ and $x^{2} + y^{2} -10x -10y +\lambda = 0$ is the interval:
a.
$(12, 32)$
b.
$(18, 42)$
c.
$(12, 24)$
d.
$(18, 48)$
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Q65 mcq
If the general solution of the differential equation $y' = \frac{y}{x} + Φ(\frac{x}{y})$ , for some function $Φ$ , is given by $yln |cx| =x$ , where $c$ is an arbitrary constant, then $Φ(2)$ is equal to:
a.
4
b.
$\frac{1}{4}$
c.
$-4$
d.
$- \frac{1}{4}$
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Q66 mcq
The plane containing the line $\frac{x-1}{1} = \frac{y-2}{2} = \frac{z-3}{3}$ and parallel to the line $\frac{x}{1} = \frac{y}{1} = \frac{z}{4}$ passes through the point:
a.
$(1, -2, 5)$
b.
$(1, 0, 5)$
c.
$(0, 3, -5)$
d.
$(-1, -3, 0)$
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Q67 mcq
If $2 cos\theta + sin\theta = 1(\theta \neq \frac{\pi}{2})$ , then $7 cos\theta + 6 sin\theta$ is equal to:
a.
$\frac{1}{2}$
b.
2
c.
$\frac{11}{2}$
d.
$\frac{46}{5}$
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Q68 mcq
The angle of elevation of the top of a vertical tower from a point $P$ on the horizontal ground was observed to be $\alpha$ . After moving a distance 2 metres from $P$ towards the foot of the tower, the angle of elevation changes to $\beta$ . Then the height (in metres) of the tower is:
a.
$\frac{2 sin\alpha sin\beta}{sin(\beta -\alpha )}$
b.
$\frac{sin\alpha sin\beta}{cos(\beta -\alpha )}$
c.
$\frac{2 sin(\beta -\alpha )}{sin\alpha sin\beta}$
d.
$\frac{cos(\beta -\alpha )}{sin\alpha sin\beta}$
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Q69 mcq
If $lim_{x\rightarrow 2\rightarrow } \frac{tan(x-2{x^{2}+k+2x-2k}}{x^{2}-4x+4} = 5$ , then $k$ is equal to:
a.
0
b.
1
c.
2
d.
3
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Q70 mcq
Let $L_{1}$ be the length of the common chord of the curves $x^{2} +y^{2} = 9$ and $y^{2} = 8x$ , and $L_{2}$ be the length of the latus rectum of $y^{2} = 8x$ , then:
a.
$L_{1} > L_{2}$
b.
$L_{1} = L_{2}$
c.
$L_{1} < L_{2}$
d.
$\frac{L_{1}}{\,L_{2}} = \sqrt{2}$
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Q71 mcq
The sum of the first 20 terms common between the series $3 + 7 + 11 + 15+$ and $1 + 6 + 11+ 16 + … .$ . is
a.
4000
b.
4020
c.
4200
d.
4220
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Q72 mcq
If $\alpha$ and $\beta$ are roots of the equation, $x^{2} -4\sqrt{2}kx+ 2e^{4 lnk} -1 = 0$ for some $k$ , and $\alpha ^{2} +\beta ^{2} = 66$ , then $\alpha ^{3} +\beta ^{3}$ is equal to:
a.
$248\sqrt{2}$
b.
$280\sqrt{2}$
c.
$-32\sqrt{2}$
d.
$-280\sqrt{2}$
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Q73 mcq
If $z_{1}, z_{2}$ and $z_{3}, z_{4}$ are 2 pairs of complex conjugate numbers, then $arg(\frac{z_{1}}{z_{4}} )+ arg(\frac{z_{2}}{z_{3}})$ equals:
a.
0
b.
$\frac{\pi}{2}$
c.
$\frac{3\pi}{2}$
d.
$\pi$
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Q74 mcq
If for $n \geq 1, P_{n} =\int _{1}^{e} (log x^{n})dx$ , then $P_{10}-90P_{8}$ is equal to:
a.
$-9$
b.
$10e$
c.
$-9e$
d.
10
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Q75 mcq
Let $A(2, 3, 5), B(-1, 3, 2)$ and $C(\lambda , 5,\mu )$ be the vertices of a $\triangle ABC$ . If the median through $A$ is equally inclined to the coordinate axes, then:
a.
$5\lambda -8\mu = 0$
b.
$8\lambda -5\mu = 0$
c.
$10\lambda -7\mu = 0$
d.
$7\lambda -10\mu = 0$
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Q76 mcq
An eight digit number divisible by 9 is to be formed using digits from 0 to 9 without repeating the digits. The number of ways in which this can be done is:
a.
$72(7!)$
b.
$18(7!)$
c.
$40(7!)$
d.
$36(7!)$
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Q77 mcq
A stair-case of length $l$ rests against a vertical wall and a floor of a room. Let $P$ be a point on the stair-case, nearer to its end on the wall, that divides its length in the ratio $1 : 2$ . If the staircase begins to slide on the floor, then the locus of $P$ is:
a.
an ellipse of eccentricity $\frac{1}{2}$
b.
an ellipse of eccentricity $\frac{\sqrt{3}}{2}$
c.
a circle of radius $\frac{1}{2}$
d.
a circle of radius $\frac{\sqrt{3}}{2}l$
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Q78 mcq
The coefficient of $x^{50}$ in the binomial expansion of $(1 +x)^{1000} +x(1 +x)^{999} +x^{2}(1 +x)^{998} + … +x^{1000}$ is:
a.
$\frac{(1000)!}{(50)(!95\phi !}$
b.
$\frac{(1000)!}{(49)(!95)!}$
c.
$\frac{(1001)!}{(51)(!95\phi !}$
d.
$\frac{(1001)!}{(50)(!95)!}$
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Q79 mcq
In a geometric progression, if the ratio of the sum of first 5 terms to the sum of their reciprocals is 49 , and the sum of the first and the third term is 35. Then the first term of this geometric progression is:
a.
7
b.
21
c.
28
d.
42
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Q80 mcq
Let A be a $3 \times 3$ matrix such that $1 2 3 0 0 1$ $[ ] [ ]$ $A 0 2 3 = 1 0 0$ $[ ] [ ]$ $0 1 1 0 1 0$ Then $A^{-1}$ is:
a.
$3 1 2$ $3 0 2$ $[ ]$ $1 0 1$ $[ ]$
b.
$3 2 1$ $[ ] [ ]$ $3 2 0$ $[ ]$ $1 1 0$ $[ ]$
c.
$0 1 3$ $0 2 3$ $[ ]$ $1 1 1$
d.
$1 2 3$ $0 1 1$ $[ ]$ $0 2 3$
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Q81 mcq
For the curve $y = 3 sin\theta cos\theta , x = e^{\theta } sin\theta$ , $0 \leq \theta \leq \pi$ , the tangent is parallel to $x$ -axis when $\theta$ is:
a.
$\frac{3\pi}{4}$
b.
$\frac{\pi}{2}$
c.
$\frac{\pi}{4}$
d.
$\frac{\pi}{6}$
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Q82 mcq
The volume of the largest possible right circular cylinder that can be inscribed in a sphere of radius $= \sqrt{3}$ is:
a.
$\frac{4}{3}\sqrt{3}\pi$
b.
$\frac{8}{3}\sqrt{3}\pi$
c.
$4\pi$
d.
$2\pi$
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Q83 mcq
Let for $i = 1, 2, 3, p_{i}(x)$ be a polynomial of degree 2 in $x,p'_{i}(x)$ and $p''_{i}(x)$ be the first and second order derivatives of $p_{i}(x)$ respectively. Let, $p (x) p' (x) p''x($ $[^{1}^{1}^{1} ])$ $A(x) = p_{2}(x) p'_{2}(x) p''_{2}($ $[''' ])$ $p_{3}(x) p_{3}(x) p_{3}(x$ and $B(x) = [A(x)]^{T}A(x)$ . Then determinant of $B(x)$ :
a.
is a polynomial of degree 6 in $x$ .
b.
is a polynomial of degree 3 in $x$ .
c.
is a polynomial of degree 2 in $x$ .
d.
does not depend on $x$ .
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Q84 mcq
Let $f(x) =x|x|,g(x) = sinx$ and $h(x) = (g^{\circ} f)(x)$ . Then
a.
$h(x)$ is not differentiable at $x = 0$ .
b.
$h(x)$ is differentiable at $x = 0$ , but $h'(x)$ is not continuous at $x= 0$
c.
$h'(x)$ is continuous at $x = 0$ but it is not differentiable at $x= 0$
d.
$h'(x)$ is differentiable at $x = 0$
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Q85 mcq
The integral $\int xcos^{-1} ( \frac{1-x^{2}}{1+x^{2}})dx(x> 0)$ is equal to:
a.
$-x+(1 +x^{2})tan^{-1} x+c$
b.
$x- (1 +x^{2})cot^{-1} x+c$
c.
$-x+(1 +x^{2})cot^{-1} x+c$
d.
$x- (1 +x^{2})tan^{-1} x+c$
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Q86 mcq
A set $S$ contains 7 elements. A non-empty subset $A$ of $S$ and an element $x$ of $S$ are chosen at random. Then the probability that $x \in A$ is:
a.
$\frac{1}{2}$
b.
$\frac{64}{127}$
c.
$\frac{63}{128}$
d.
$\frac{31}{128}$
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Q87 mcq
The base of an equilateral triangle is along the line given by $3x+ 4y= 9$ . If a vertex of the triangle is $(1, 2)$ , then the length of a side of the triangle is:
a.
$\frac{2\sqrt{3}}{15}$
b.
$\frac{4\sqrt{3}}{15}$
c.
$\frac{4\sqrt{3}}{5}$
d.
$\frac{2\sqrt{3}}{5}$
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Q88 mcq
$\rightarrow \rightarrow$ If $|\vec{c}|^{2} = 60$ and $\vec{c}\times (\hat{i}+ 2\hat{j}+ 5\hat{k}) = 0$ , then a value of $\vec{c}\cdot (-7\hat{i}+ 2\hat{j}+ 3\hat{k})$ is:
a.
$4\sqrt{2}$
b.
12
c.
24
d.
$12\sqrt{2}$
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Q89 mcq
The proposition $\sim (p\vee \sim q)\vee \sim (p\vee q)$ is logically equivalent to:
a.
$p$
b.
$q$
c.
$\sim p$
d.
$\sim q$
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Q90 mcq
Let $P(3 sec\theta , 2 tan\theta )$ and $Q(3 sec\phi , 2 tan\phi )$ where $\theta +\phi = \frac{\pi}{2}$ , be two distinct points on the hyperbola $\frac{x^{2}}{9} - \frac{y^{2}}{4} = 1$ . Then the ordinate of the point of intersection of the normals at $P$ and $Q$ is:
a.
$\frac{11}{3}$
b.
$- \frac{11}{3}$
c.
$\frac{13}{2}$
d.
$- \frac{13}{2}$
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