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JEE Main 2008

2008 · 105 questions · First 10 Solutions Free
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Q1 mcq
The dimension of magnetic field in $M, L, T$ and $C$ (Coulomb) is given as
a.
$MLT^{-1}C^{-1}$
b.
$MT^{2}C^{-2}$
c.
$MT^{-1}C^{-1}$ Correct Answer
d.
$MT^{-2}C^{-1}$

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Q2 mcq
This question contains Statement $-1$ and Statement-2. Of the four choices given after the statements, choose the one that best describes the two statements. Statement - I: Energy is released when heavy nuclei undergo fission or light nuclei undergo fusion. and Statement - II For heavy nuclei, binding energy per nucleon increases with increasing $Z$ while for light nuclei it decrease with increasing $Z$ .
a.
Statement $-1$ is false, Statement $-2$ is true.
b.
Statement - 1is true, Statement $-2$ is true; Statement $-2$ is correct explanation for Statement-1.
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement-1.
d.
Statement $-1$ is true, Statement $-2$ is False. Correct Answer

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Q3 mcq
A body is at rest at $x= 0$ . At $t= 0$ , it starts moving in the positive $x$ -direction with a constant acceleration. At the same instant another body passes through $x= 0$ moving in the positive $x$ direction with a constant speed. The position of the first body is given by $x_{1}(t)$ after time ' $t$ ' and that of the second body by $x_{2}(t)$ after the same time interval. Which of the following graphs correctly describes $(x_{1}- x_{2})$ as a function of time ' $t$ '?
Question 3 image

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Q4 mcq
A $5\,V$ battery with internal resistance $2\Omega$ and a $2\,V$ battery with internal resistance $1\Omega$ are connected to a $10\Omega$ resistor as shown in the figure. The current in the $10\Omega$ resistor is
Question 4 image
a.
$0.27AP_{2}$ to $P_{1}$
b.
$0.03AP_{1}$ to $P_{2}$
c.
$0.03AP_{2}$ to $P_{1}$ Correct Answer
d.
$0.27\,APP_{1}$ to $P_{2}$

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Q5 mcq
A working transistor with its three legs marked $P,Q$ and $R$ is tested using a multimeter. No conduction is found between $P$ and $Q$ . By connecting the common (negative) terminal of the multimeter to $R$ and the other (positive) terminal to $P$ or $Q$ , some resistance is seen on the multimeter. Which of the following is true for the transistor?
a.
It is an npn transistor with $R$ as base
b.
It is a pnp transistor with $R$ as collector Correct Answer
c.
It is a pnp transistor with $R$ as emitter
d.
It is an npn transistor with $R$ as collector

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Q6 mcq
A thin spherical shell of radius $R$ has charge $Q$ spread uniformly over its surface. Which of the following graphs most closely represents the electric field $E(r)$ produced by the shell in the range $0 \leq r< \infty$ , where $r$ is the distance from the centre of the shell?
Question 6 image

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Q7 mcq
While measuring the speed of sound by performing a resonance column experiment, a student gets the first resonance condition at a column length of $18\,cm$ during winter. Repeating the same experiment during summer, she measures the column length to be $xcm$ for the second resonance. Then
a.
$18 >x$
b.
$x> 54$ Correct Answer
c.
$54 >x> 36$
d.
$36 >x> 18$

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Q8 mcq
Paragraph:Wave property of electrons implies that they will show diffraction effects. Davisson and Germer demonstrated this by diffracting electrons from crystals. The law governing the diffraction from a crystal is obtained by requiring that electron waves reflected from the planes of atoms in a crystal interfere constructively (see in figure). Question:If a strong diffraction peak is observed when electrons are incident at an angle 'i' from the normal to the crystal planes with distance ' $d$ ' between them (see figure), de Broglie wavelength $\lambda _{dB}$ of electrons can be calculated by the relationship ( $n$ is an integer)
Question 8 image
a.
$dsini=n\lambda _{dB}$
b.
$2dcosi=n\lambda _{dB}$
c.
$2dsini=n\lambda _{dB}$
d.
$dcosi=n\lambda _{dB}$ Correct Answer

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Q9 mcq
Suppose an electron is attracted towards the origin by a force $k/r$ where ' $k$ ' is a constant and ' $r$ ' is the distance of the electron from the origin. By applying Bohr model to this system, the radius of the $n^{th\,}$ orbital of the electron is found to be ' $r_{n}$ ' and the kinetic energy of the electron to be $T_{n}$ . Then which of the following is true?
a.
$T_{n} \propto 1/n^{2}, r_{n} \propto n^{2}$
b.
$T_{n}$ independent of $n,r_{n} \propto n$ Correct Answer
c.
$T_{n} \propto 1/n, r_{n} \propto n$
d.
$T_{n} \propto 1/n, r_{n} \propto n^{2}$

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Q10 mcq
Paragraph:Consider a block of conducting material of resistivity ' $\rho$ ' shown in the figure. Current 'l' enters at 'A' and leaves from ' $D$ '. We apply superposition principle to find voltage ' $\Delta V$ ' developed between ' $B$ ' and ' $C$ '. The calculation is done in the following steps: (i) Take current 'l' entering from 'A' and assume it to spread over a hemispherical surface in the block. (ii) Calculate field $E(r)$ at distance ' $r$ ' from $A$ by using Ohm's law $E =\rho j$ , where $j$ is the current per unit area at ' $r$ '. (iii) From the ' $r$ ' dependence of $E(r)$ , obtain the potential $V(r)$ at $r$ . (iv) Repeat (i), (ii) and (iii) for current 'l' leaving ' $D$ ' and superpose results for ' $A$ ' and ' $D$ '. Question: $\Delta V$ measured between $B$ and $C$ is
Question 10 image
a.
$\frac{\rho l}{\pi a} - \frac{\rho l}{\pi (a+b)}$
b.
$\frac{\rho l}{a} - \frac{\rho l}{(a+b)}$
c.
$\frac{\rho l}{2\pi a} - \frac{\rho l}{2\pi (a+b)}$ Correct Answer
d.
$\frac{\rho l}{2\pi (a-b)}$

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Q11 mcq
A wave travelling along the $x$ -axis is described by the equation $y(x,t) = 0.005 cos(\alpha x- \beta t)$ . If the wavelength and the time period of the wave are $0.08\,m$ and $2.0\,s$ , respectively, then $\alpha$ and $\beta$ in appropriate units are
a.
$\alpha = 25.00\pi ,\beta =\pi$
b.
$\alpha = \frac{0.08}{\pi} , \frac{2.0}{\pi}$
c.
$\alpha = \frac{0.04}{\pi},\beta = \frac{1.0}{\pi}$
d.
$\alpha = 12.50\pi ,\beta = \frac{\pi}{2.0}$
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Q12 mcq
Two full turns of the circular scale of a screw gauge cover a distance of $1\,mm$ on its main scale. The total number of divisions on the circular scale is 50 . Further, it is found that the screw gauge has a zero error of $-0.03\,mm$ while measuring the diameter of a thin wire, a student notes the main scale reading of $3\,mm$ and the number of circular scale divisions in line with the main scale as 35 . The diameter of the wire is
a.
$3.32\,mm$
b.
$3.73\,mm$
c.
$3.67\,mm$
d.
$3.38\,mm$
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Q13 mcq
A horizontal overhead power line is at a height of $4\,m$ from the ground and carries a current of $100\,A$ from east to west. The magnetic field directly below it on the ground is $(\mu _{0} = 4\pi \times 10^{-7}\,T\,m\,A^{-1})$
a.
$2.5 \times 10^{-7}\,T$ southward
b.
$5 \times 10^{-6}\,T$ northward
c.
$5 \times 10^{-6}$ T southward
d.
$2.5 \times 10^{-7}$ northward
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Q14 mcq
Consider a uniform square plate of side ' $a$ ' and mass ' $m$ '. The moment of inertia of this plate about an axis perpendicular to its plane and passing through one of its corners is
a.
$\frac{5}{6}ma^{2}$
b.
$\frac{1}{12}ma^{2}$
c.
$\frac{7}{12}ma^{2}$
d.
$\frac{2}{3}ma^{2}$
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Q15 mcq
An athlete in the olympic games covers a distance of $100\,m$ in $10\,s$ . His kinetic energy can be estimated to be in the range
a.
$200\,J -500\,J$
b.
$2 \times 10^{5}\,J -3 \times 10^{5}\,J$
c.
$20, 000\,J -50, 000\,J$
d.
$2, 000\,J -5, 000\,J$
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Q16 mcq
This question contains Statement $-1$ and Statement-2. Of the four choices given after the statements, choose the one that best describes the two statements. Statement - I: For a mass $M$ kept at the centre of a cube of side ' $a$ ', the flux of gravitational field passing through its sides is $4\pi$ GM. and Statement - II If the direction of a field due to a point source is radial and its dependence on the distance ' $r$ ' for the source is given as $1/r^{2}$ , its flux through a closed surface depends only on the strength of the source enclosed by the surface and not on the size or shape of the surface
a.
Statement $-1$ is false, Statement $-2$ is true.
b.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is correct explanation for Statement-1.
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement-1.
d.
Statement $-1$ is true, Statement $-2$ is False.
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Q17 mcq
A block of mass $0.50\,kg$ is moving with a speed of $2.00\,m/s$ on a smooth surface. It strikes another mass of $1.00\,kg$ and then they move together as a single body. The energy loss during the collision is
a.
$0.16\,J$
b.
$1.00\,J$
c.
$0.67\,J$
d.
$0.34\,J$
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Q18 mcq
Paragraph:Consider a block of conducting material of resistivity ' $\rho$ ' shown in the figure. Current 'l' enters at 'A' and leaves from ' $D$ '. We apply superposition principle to find voltage ' $\Delta V$ ' developed between ' $B$ ' and ' $C$ '. The calculation is done in the following steps: (i) Take current 'l' entering from 'A' and assume it to spread over a hemispherical surface in the block. (ii) Calculate field $E(r)$ at distance ' $r$ ' from $A$ by using Ohm's law $E =\rho j$ , where $j$ is the current per unit area at ' $r$ '. (iii) From the ' $r$ ' dependence of $E(r)$ , obtain the potential $V(r)$ at $r$ . (iv) Repeat (i), (ii) and (iii) for current 'l' leaving ' $D$ ' and superpose results for ' $A$ ' and ' $D$ '. Question:For current entering at $A$ , the electric field at a distance ' $r$ ' from $A$ is
Question 18 image
a.
$\frac{\rho l}{8\pi r^{2}}$
b.
$\frac{\rho l}{r^{2}}$
c.
$\frac{\rho l}{2\pi r^{2}}$
d.
$\frac{\rho l}{4\pi r^{2}}$
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Q19 mcq
Paragraph:Wave property of electrons implies that they will show diffraction effects. Davisson and Germer demonstrated this by diffracting electrons from crystals. The law governing the diffraction from a crystal is obtained by requiring that electron waves reflected from the planes of atoms in a crystal interfere constructively (see in figure). Question:Electrons accelerated by potential $V$ are diffracted from a crystal. If $d= 1$ Åand $i= 30^{\circ },V$ should be about $(h = 6.6 \times 10^{-34}Js, m_{e} = 9.1 \times 10^{-31}\,kg, e = 1.6 \times 10^{-19}C)$
a.
$2000\,V$
b.
$50\,V$
c.
$500\,V$
d.
$1000\,V$
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Q20 mcq
A parallel plate capacitor with air between the plates has a capacitance of $9pF$ . The separation between its plates is ' $d$ '. The space between the plates is now filled with two dielectrics. One of the dielectrics has dielectric constant $k_{1} = 3$ and thickness $\frac{d}{3}$ while the other one has dielectric constant $k_{2} = 6$ and thickness $\frac{2\,d}{3}$ . Capacitance of the capacitor is now
a.
$1.8pF$
b.
$45pF$
c.
$40.5pF$
d.
$20.25pF$
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Q21 mcq
Relative permittivity and permeability of a material are $\epsilon _{r}$ and $\mu _{r}$ , respectively. Which of the following values of these quantities are allowed for a diamagnetic material?
a.
$\epsilon _{r} = 0.5,\mu _{r} = 1.5$
b.
$\epsilon _{r} = 1.5,\mu _{r} = 0.5$
c.
$\epsilon _{r} = 0.5,\mu _{r} = 0.5$
d.
$\epsilon _{r} = 1.5,\mu _{r} = 1.5$
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Q22 mcq
In the circuit below, $A$ and $B$ represent two inputs and $C$ represents the output. The circuit represents
Question 22 image
a.
NOR gate
b.
AND gate
c.
NAND gate
d.
OR gate
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Q23 mcq
The speed of sound in oxygen $(O_{2})$ at a certain temperature is $460\,ms^{-1}$ . The speed of sound in helium (He) at the same temperature will be (assumed both gases to be ideal)
a.
$460\,ms^{-1}$
b.
$500\,ms^{-1}$
c.
$650\,ms^{-1}$
d.
None of these
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Q24 mcq
A jar filled with two non mixing liquids 1 and 2 having densities $\rho _{1}$ and $\rho _{2}$ respectively. A solid ball, made of a material of density $\rho _{3}$ , is dropped in the jar. It comes to equilibrium in the position shown in the figure. Which of the following is true for $\rho _{1},\rho _{2}$ and $\rho _{3}$ ?
a.
$\rho _{3} <\rho _{1} <\rho _{2}$
b.
$\rho _{1} <\rho _{3} <\rho _{2}$
c.
$\rho _{1} <\rho _{2} <\rho _{3}$
d.
$\rho _{1} <\rho _{3} <\rho _{2}$
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Q25 mcq
A body of mass $m= 3.513\,kg$ is moving along the $x$ -axis with a speed of $5.00\,ms^{-1}$ . The magnitude of its momentum is recorded as
a.
$17.6\,kg\,ms^{-1}$
b.
$17.565\,kg\,ms^{-1}$
c.
$17.56\,kg\,ms^{-1}$
d.
$17.57\,kg\,ms^{-1}$
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Q26 mcq
An experiment is performed to find the refractive index of glass using a travelling microscope. In this experiment distance are measured by
a.
a vernier scale provided on the microscope
b.
a standard laboratory scale
c.
a meter scale provided on the microscope
d.
a screw gauage provided on the microscope
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Q27 mcq
A capillary tube $(A)$ is dropped in water. Another identical tube $(B)$ is dipped in a soap water solution. Which of the following shows the relative nature of the liquid columns in the two tubes?
Question 27 image
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Q28 mcq
Paragraph:Wave property of electrons implies that they will show diffraction effects. Davisson and Germer demonstrated this by diffracting electrons from crystals. The law governing the diffraction from a crystal is obtained by requiring that electron waves reflected from the planes of atoms in a crystal interfere constructively (see in figure). Question:In an experiment, electrons are made to pass through a narrow slit of width 'd' comparable to their de Broglie wavelength. They are detected on a screen at a distance ' $D$ ' from the slit (see figure). Which of the following graph can be expected to represent the number of electrons ' $N$ ' detected as a function of the detector position ' $y$ ' $(y= 0$ corresponds to the middle of the slit)?
Question 28 image
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Q29 mcq
An insulated container of gas has two chambers separated by an insulating partition. One of the chambers has volume $V_{1}$ and contains ideal gas at pressure $P_{1}$ and temperature $T_{1}$ . The other chamber has volume $V_{2}$ and contains ideal gas at pressure $P_{2}$ and temperature $T_{2}$ . If the partition is removed without doing any work on the gas, the final equilibrium temperature of the gas in the container will be
a.
$\frac{T_{1}T_{2}(P_{1}V_{1}+P_{2}V_{2})}{P_{1}V_{1}T_{2}+P_{2}V_{2}T_{1}}$
b.
$\frac{P_{1}V_{1}T_{1}+P_{2}V_{2}T_{2}}{P_{1}V_{1}+P_{2}V_{2}}$
c.
$\frac{P_{1}V_{1}T_{2}+P_{2}V_{2}T_{1}}{P_{1}V_{1}+P_{2}V_{2}}$
d.
$\frac{T_{1}T_{2}(P_{1}V_{1}+P_{2}V_{2})}{P_{1}V_{1}T_{1}+P_{2}V_{2}T_{2}}$
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Q30 mcq
Two coaxial solenoids are made by winding thin insulated wire over a pipe of cross sectional area $A= 10\,cm^{2}$ and length $= 20\,cm$ . If one of the solenoids has 300 turns and the other 400 turns, their mutual inductance is $(\mu _{0} = 4\pi \times 10^{-7}TmA^{-1})$
a.
$2.4\pi \times 10^{-5}H$
b.
$4.8\pi \times 10^{-4}H$
c.
$4.8\pi \times 10^{-5}H$
d.
$2.4\pi \times 10^{-4}H$
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Q31 mcq
Shown in the figure below is a meter-bridge set up with null deflection in the galvanometer. The value of the unknown resistor $R$ is
Question 31 image
a.
$13.75\Omega$
b.
$220\Omega$
c.
$110\Omega$
d.
$55\Omega$
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Q32 mcq
A thin rod of length ' $L$ ' is lying along the $x$ -axis with its ends at $x= 0$ and $x=L$ . Its linear density (mass/length) varies with $x$ ask $(\frac{x}{L} )^{n}$ , where $n$ can be zero or any positive number. If the position $x_{CM}$ of the centre of mass of the rod is plotted against ' $n$ ', which of the following graphs best approximates the dependence of $x_{CM}$ on $n$ ?
Question 32 image
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Q33 mcq
A planet in a distant solar system is 10 times more massive than the earth and its radius is 10 times smaller. Given that the escape velocity from the earth is $11kms^{-1}$ , the escape velocity from the surface of the planet would be
a.
$1.1kms^{-1}$
b.
$11kms^{-1}$
c.
$110kms^{-1}$
d.
$0.11kms^{-1}$
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Q34 mcq
A student measures the focal length of convex lens by putting an object pin at a distance 'u' from the lens and measuring the distance ' $v$ ' of the image pin. The graph between ' $u$ ' and ' $v$ ' plotted by the student should look like
Question 34 image
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Q35 mcq
A spherical solid ball of volume $V$ is made of a material of density $\rho _{1}$ . It is falling through a liquid of density $\rho _{2}(\rho _{2} <\rho _{1})$ . Assume that the liquid applies a viscous force on the ball that is proportional to the square of its speed v, i.e., $_{viscous\,} = -kv^{2}(k> 0)$ . The terminal speed of the ball is
a.
$\frac{F}{Vg(\rho _{1}-\rho _{2})}$ $\sqrt{\,}$
b.
$\frac{Vg\rho _{1}}{k}$
c.
$\frac{k}{V g\rho _{1}}$ $\sqrt{\,} _{k}$
d.
$\frac{Vg(\rho _{1}-\rho _{2})}{k}$
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Q36 mcq
Larger number of oxidation states are exhibited by the actinoids than those by the lanthanoids, the main reason being
a.
4 f orbitals more diffused than the $5f$ orbitals
b.
lesser energy difference between $5f$ and $6d$ than between $4f$ and $5d$ orbitals
c.
more energy difference between $5f$ and $6d$ than between $4f$ and $5d$ orbitals
d.
more reactive nature of the actinoids than the lanthanoids
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Q37 mcq
The coordination number and the oxidation state of the element ' $E$ ' in the complex $[E(en)_{2}(C_{2}O_{4})]NO_{2}$ (where (en) is ethylene diamine) are, respectively,
a.
6 and 2
b.
4 and 2
c.
4 and 3
d.
6 and 3
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Q38 mcq
The vapour pressure of water at $20^{\circ }C$ is $17.5\,mmHg$ . If $18\,g$ of glucose $(C_{6}H_{12}O_{6})$ is added to $178.2\,g$ of water at $20^{\circ }C$ , the vapour pressure of the resulting solution will be
a.
$17.675\,mmHg$
b.
$15.750\,mmHg$
c.
$16.500\,mmHg$
d.
$17.325\,mmHg$
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Q39 mcq
For a reaction $\frac{1}{2} A\rightarrow 2\rightarrow B$ , rate of disappearance of ' $A$ ' is related to the rate of appearance of 'B' by the expression
a.
$-\frac{d[A]}{dt} = \frac{1}{2} \frac{d[B]}{dt}$
b.
$-\frac{d[A]}{dt} = \frac{1}{4} \frac{d[B]}{dt}$
c.
$-\frac{d[A]}{dt} = \frac{d[B]}{dt}$
d.
$-\frac{d[A]}{dt} = 4\frac{d[B]}{dt}$
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Q40 mcq
In which of the following octahedral complexes of Co (at. no. 27), will the magnitude of $\Delta _{\circ }$ be the highest?
a.
$[Co(CN)_{6}]^{3-}$
b.
$[Co(C_{2}O_{4})_{3}]^{3-}$
c.
$[Co(H_{2}O)_{6}]^{3+}$
d.
$[Co(NH_{3})_{6}]^{3+}$
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Q41 mcq
Four species are listed below i. $HCO^{-}_{3}$ ii. $H_{3}O^{+}$ iii. $HSO^{-}_{4}$ iv. $HSO_{3}\,F$ Which one of the following is the correct sequence of their acid strength?
a.
iv $<$ ii $<$ iii $<$ i
b.
ii $<$ iii $<i<$ iv
c.
i $<$ iii $<$ ii $<$ iv
d.
iii $<$ i $<$ iv $<$ ii
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Q42 mcq
The $pK_{a}$ of a weak acid, $HA$ , is $4.80$ . The $pK_{b}$ of a weak base, $BOH$ , is $4.78$ . The $pH$ of an aqueous solution of the corresponding salt, BA, will be
a.
$9.58$
b.
$4.79$
c.
$7.01$
d.
$9.22$
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Q43 mcq
The organic chloro compound, which shows complete stereochemical inversion during a $S_{N}2$ reaction, is
a.
$(C_{2}H_{5})_{2}CHCl$
b.
$(CH_{3})_{3}CCl$
c.
$(CH_{3})_{2}CHCl$
d.
$CH_{3}Cl$
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Q44 mcq
In a compound atoms of element $Y$ from ccp lattice and those of element $X$ occupy $2/3^{rd\,}$ of tetrahedral voids. The formula of the compound will be
a.
$X_{4}Y_{3}$
b.
$X_{2}Y_{3}$
c.
$X_{2}Y$
d.
$X_{3}Y_{4}$
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Q45 mcq
In the following sequence of reactions, the alkene affords the compound ' $B$ ' $CH_{3}CH = CHCH_{3} \longrightarrow ^{O_{3}} A^{H}Zn^{_{2}O} B$ . The compound $B$ is
a.
$CH_{3}CH_{2}CHO$
b.
$CH_{3}COCH_{3}$
c.
$CH_{3}CH_{2}COCH_{3}$
d.
$CH_{3}CHO$
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Q46 mcq
For the following three reactions $a,b$ and $c$ , equilibrium constants are given: a. $CO(g) + H_{2}O(g)\rightleftharpoons CO_{2}(\,g) + H_{2}(\,g); K_{1}$ b. $CH_{4}(\,g) + H_{2}O(g)\rightleftharpoons CO(g) + 3H_{2}(\,g); K_{2}$ c. $CH_{4}(\,g) + 2H_{2}O(g)\rightleftharpoons CO_{2}(\,g) + 4H_{2}(\,g); K_{3}$ Which of the following relations is correct?
a.
$K_{1}\sqrt{K}_{2} = K_{3}$
b.
$K_{2}\,K_{3} = K_{1}$
c.
$K_{3} = K_{1}\,K_{2}$
d.
$K_{3}\cdot K^{3}_{2} = K^{2}_{1}$
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Q47 mcq
The equilibrium constants $K_{P_{1}}$ and $K_{P_{2}}$ for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P +Q$ , respectively are in the ratio of $1 : 9$ . If the degree of dissociation of $X$ and $Z$ be equal then the ratio of total pressure at these equilibria is
a.
$1 : 36$
b.
$1 : 1$
c.
$1 : 3$
d.
$1 : 9$
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Q48 mcq
At $80^{\circ }C$ , the vapour pressure of pure liquid ' $A$ ' is $520\,mmHg$ and that of pure liquid ' $B$ ' is $1000\,mm Hg$ . If a mixture solution of ' $A$ ' and ' $B$ ' boils at $80^{\circ }C$ and $1\,atm$ pressure, the amount of ' $A$ ' in the mixture is $(1\,atm = 760\,mmHg)$
a.
52 mol percent
b.
34 mol percent
c.
48 mol percent
d.
50 mol percent
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Q49 mcq
Which one of the following pairs of species have the same bond order?
a.
$CN^{-}$ and $NO^{+}$
b.
$CN^{-}$ and $CN^{+}$
c.
$O^{-}_{2}$ and $CN^{-}$
d.
$NO^{+}$ and $CN^{+}$
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Q50 mcq
Which one of the following is the correct statement?
a.
Boric acid is a protonic acid
b.
Beryllium exhibits coordination number of six
c.
Chlorides of both beryllium and aluminium have bridged chloride structures in solid phase
d.
$B_{2}H_{6}.2NH_{3}$ is known as 'inorganic benzene'
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Q51 mcq
Amount of oxalic acid present in a solution can be determined by its titration with $KMnO_{4}$ solution in the presence of $H_{2}SO_{4}$ . The titration gives unsatisfactory result when carried out in the presence of $HCl$ , because $HCl$
a.
gets oxidised by oxalic acid to chlorine
b.
furnishes $H^{+}$ ions in addition to those from oxalic acid
c.
reduces permanganate to $Mn^{2+}$
d.
oxidises oxalic acid to carbon dioxide and water
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Q52 mcq
In context with the industrial preparation of hydrogen from water gas $(CO + H_{2})$ , which of the following is the correct statement?
a.
$CO$ and $H_{2}$ are fractionally separated using differences in their densities
b.
$CO$ is removed by absorption in aqueous $Cu_{2}Cl_{2}$ solution
c.
$H_{2}$ is removed through occlusion with $Pd$
d.
$CO$ is oxidised to $CO_{2}$ with steam in the presence of a catalyst followed by absorption of $CO_{2}$ in alkali
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Q53 mcq
Given $E^{\circ }_{Cr^{3}+/Cr} = -0.72\,V, E^{\circ }_{Fe^{2+//Fe}} = -0.42\,V$ . The potential for the cell $Cr Cr^{3+}(0.1M) Fe^{2+}(0.01M) Fe$ is
a.
$0.26\,V$
b.
$0.399\,V$
c.
$-0.339\,V$
d.
$-0.26\,V$
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Q54 mcq
$|||$ Which of the following factors is of no significance for roasting sulphide ores to the oxides and not subjecting the sulphide ores to carbon reduction directly?
a.
Metal sulphides are thermodynamically more stable than $CS_{2}$
b.
$CO_{2}$ is thermodynamically more stable than $CS_{2}$
c.
Metal sulphides are less stable than the corresponding oxides
d.
$CO_{2}$ is more volatile than $CS_{2}$
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Q55 mcq
Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains
a.
mixture of $o-$ and p-bromotoluenes
b.
mixture of $o-$ and p-dibromobenzenes
c.
mixture of $o$ - and p-bromoanilines
d.
mixture of 0 - and $m$ -bromotoluenes
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Q56 mcq
Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives
a.
2,4,6-trinitrobenzene
b.
o-nitrophenol
c.
p-nitrophenol
d.
nitrobenzene
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Q57 mcq
Gold numbers of protective colloids $A,B,C$ and $D$ are $0.50, 0.01, 0.10$ and $0.005$ , respectively. The correct order of their protective powers is
a.
$D<A<C <B$
b.
C $<$ B $<D<A$
c.
$A<C <B<D$
d.
B $<D<A<C$
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Q58 mcq
The treatment of $CH_{3}MgX$ with $CH_{3}C \equiv C -H$ produces
Question 58 image
a.
$CH_{3}-CH = CH_{2}$
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Q59 mcq
The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system of nomenclature is
a.
$-COOH, -SO_{3}H, -CONH_{2}, -CHO$
b.
$-SO_{3}H, -COOH, -CONH_{2}, -CHO$
c.
$-CHO, -COOH, -SO_{3}H, -CONH_{2}$
d.
$-CONH_{2}, -CHO, -SO_{3}H, -COOH$
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Q60 mcq
$\alpha - D-(+)$ -glucose and $\beta - D-(+) - glucose are$
a.
conformers
b.
epimers
c.
anomers
d.
enantiomers
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Q61 mcq
The hydrocarbon which can react with sodium in liquid ammonia is
a.
$CH_{3}CH_{2}CH_{2}C \equiv CCH_{2}CH_{2}CH_{3}$
b.
$CH_{3}CH_{2}C \equiv CH$
c.
$CH_{3}CH = CHCH_{3}$
d.
$CH_{3}CH_{2}C \equiv CCH_{2}CH_{3}$
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Q62 mcq
Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is
a.
$R_{4}Si$
b.
$RSiCl_{3}$
c.
$R_{2}SiCl_{2}$
d.
$R_{3}SiCl$
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Q63 mcq
Standard entropy of $X_{2},Y_{2}$ and $XY_{3}$ are 60,40 and $50JK^{-1}\,mol^{-1}$ , respectively. For the reaction, $\frac{1}{2}X_{2}+ \frac{3}{2} Y_{2} \rightarrow \rightarrow XY_{3}, \Delta H = -30\,kJ$ , to be at equilibrium, the temperature will be
a.
$1250\,K$
b.
$500\,K$
c.
$750\,K$
d.
$1000\,K$
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Q64 mcq
Which one of the following constitutes a group of the isoelectronic species?
a.
$C^{2-}_{2} , O^{-}_{2} , CO, NO$
b.
$NO^{+}, C^{2-}_{2} , CN^{-}, N_{2}$
c.
$CN^{-}, N_{2}, O^{2-}_{2} , C^{2-}_{2}$
d.
$N_{2}, O^{-}_{2} , NO^{+}, CO$
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Q65 mcq
Identify the wrong statements in the following:
a.
Chlorofluorocarbons are responsible for ozone layer depletion
b.
Greenhouse effect is responsible for global warming
c.
Ozone layer does not permit infrared radiation from the sun to reach the earth
d.
Acid rains is mostly because of oxides of nitrogen and sulphur
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Q66 mcq
The absolute configuration of is
a.
$S,S$
b.
R, R
c.
$R,S$
d.
$S,R$
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Q67 mcq
Bakelite is obtained from phenol by reacting with
a.
$(CH_{2}OH)_{2}$
b.
$CH_{3}CHO$
c.
$CH_{3}COCH_{3}$
d.
$HCHO$
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Q68 mcq
The ionization enthalpy of hydrogen atom is $1.312 \times 10^{6}Jmol^{-1}$ . The energy required to excite the electron in the atom from $n= 1$ to $n= 2$ is
a.
$8.51 \times 10^{5}Jmol^{-1}$
b.
$6.56 \times 10^{5}Jmol^{-1}$
c.
$7.56 \times 10^{5}Jmol^{-1}$
d.
$9.84 \times 10^{5}Jmol^{-1}$
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Q69 mcq
The electrophile, $E^{\oplus }$ attacks the benzene ring to generate the intermediate $\sigma$ -complex. Of the following, which $\sigma$ -complex is of lowest energy?
Question 69 image
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Q70 mcq
Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below: $\frac{1}{2}Cl_{2}(\,g) \frac{1}{2}^{\Delta }\longrightarrow ^{_{ass}H^{\ominus }} Cl(g)^{\Delta }\longrightarrow ^{egH\ominus } Cl^{-}(g)^{\Delta }\longrightarrow ^{\longrightarrow monH\ominus } Cl^{-}(aq).$ The energy involved in the conversion of $\frac{1}{2}Cl_{2}(\,g)$ to $Cl^{-}(g)$ (using the data, $\Delta _{diss\,}H_{Cl}^{\ominus }_{2} = 240kJmol^{-1}, \Delta _{eg}H^{\ominus }_{cl} = -349kJmol^{-1}, \Delta _{hyd}H^{\ominus }_{Cl} = -381kJmol^{-1})$ will be
a.
$+152kJmol^{-1}$
b.
$-610kJmol^{-1}$
c.
$-850kJmol^{-1}$
d.
$+120kJmol^{-1}$
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Q71 mcq
The first two terms of a geometric progression add up to 12. The sum of the third and the fourth terms is 48. If the terms of the geometric progression are alternately positive and negative, then the first term is
a.
$-4$
b.
$-12$
c.
12
d.
4
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Q72 mcq
$AB$ is a vertical pole with $B$ at the ground level and $A$ at the top. $A$ man finds that the angle of elevation of the point $A$ from a certain point $C$ on the ground is $60^{\circ }$ . He moves away from the pole along the line $BC$ to a point $D$ such that $CD= 7\,m$ . From $D$ the angle of elevation of the point $A$ is $45^{\circ }$ . Then the height of the pole is
a.
$\frac{7\sqrt{3}}{2} \cdot \frac{1}{\sqrt{3}-1}m$
b.
$\frac{7\sqrt{3}}{2} \cdot (\sqrt{3}+ 1)m$
c.
$\frac{7\sqrt{3}}{2} \cdot (\sqrt{3}-1)m$
d.
$\frac{7\sqrt{3}}{2} \cdot \frac{1}{\sqrt{3}+1}$
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Q73 mcq
In a shop there are five types of ice-creams available. A child buys six ice-creams. Statement -1: The number of different ways the child can buy the six ice-creams is $^{10}C_{5}$ . Statement $-2$ : The number of different ways the child can buy the six ice-creams is equal to the number of different ways of arranging $6\,A^{'s\,}$ and 4 B's in a row.
a.
Statement $-1$ is false, Statement $-2$ is true
b.
Statement $-1$ is true, Statement $-2$ is true, Statement $-2$ is a correct explanation for Statement $-1$
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement $-1$ .
d.
Statement $-1$ is true, Statement $-2$ is false.
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Q74 mcq
The point diametrically opposite to the point $P(1, 0)$ on the circle $x^{2} +y^{2} + 2x+ 4y-3 = 0$ is
a.
$(3, -4)$
b.
$(-3, 4)$
c.
$(-3, -4)$
d.
$(3, 4)$
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Q75 mcq
The value of $cot(cosec^{-1} \frac{5}{3} + tan^{-1} \frac{2}{3} )$ is
a.
$\frac{6}{17}$
b.
$\frac{3}{17}$
c.
$\frac{4}{17}$
d.
$\frac{5}{17}$
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Q76 mcq
Let $A$ be a $2 \times 2$ matrix with real entries. Let I be the $2 \times 2$ identity matrix. Denote by $tr(A)$ , the sum of diagonal entries of $A$ . Assume that $A^{2} = 1$ . Statement -1: If $A\neq 1$ and $A\neq -1$ , then $detA= -1$ . Statement $-2$ : If $A\neq 1$ and $A\neq -1$ , then $tr(A) \neq 0$ .
a.
Statement $-1$ is false, Statement $-2$ is true
b.
Statement $-1$ is true, Statement $-2$ is true, Statement $-2$ is a correct explanation for Statement $-1$
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement $-1$
d.
Statement $-1$ is true, Statement $-2$ is false.
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Q77 mcq
How many real solutions does the equation $x^{7} + 14x^{5} + 16x^{3} + 30x-560 = 0$ have?
a.
7
b.
1
c.
3
d.
5
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Q78 mcq
Suppose the cube $x^{3} - px+q$ has three distinct real roots where $p> 0$ and $q> 0$ . Then which one of the following holds?
a.
The cubic has minima at $\sqrt{\frac{p}{3}}$ and maxima at $-\sqrt{\frac{p}{3}}$
b.
The cubic has minima at $-\sqrt{\frac{p}{3}}$ and maxima at $\sqrt{\frac{p}{3}}$
c.
The cubic has minima at both $\sqrt{\frac{p}{3}}$ and $-\sqrt{\frac{p}{3}}$
d.
The cubic has maxima at both $\sqrt{\frac{p}{3}}$ and $-\sqrt{\frac{p}{3}}$
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Q79 mcq
$(x-1) sin( \frac{1}{x-1}), \,if\,x\neq 1$ Let $f(x) ={$ . Then which one of the following is true? $0, \,if\,x= 1$
a.
$f$ is neither differentiable at $x= 0$ nor at $x= 1$
b.
$f$ is differentiable at $x= 0$ and at $x= 1$
c.
$f$ is differentiable at $x = 0$ but not at $x = 1$
d.
$f$ is differentiable at $x = 1$ but not at $x = 0$
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Q80 mcq
A focus of an ellipse is at the origin. The directrix is the line $x= 4$ and the eccentricity is $1/2$ . Then the length of the semi-major axis is
a.
$\frac{8}{3}$
b.
$\frac{2}{3}$
c.
$\frac{4}{3}$
d.
$\frac{5}{3}$
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Q81 mcq
The differential equation of the family of circles with fixed radius 5 units and centre on the line $y= 2$ is
a.
$(x-2)y^{'2} = 25 -(y-2)^{2}$
b.
$(y-2)y^{'2} = 25 -(y-2)^{2}$
c.
$(y-2)^{2}y^{'2} = 25 -(y-2)^{2}$
d.
$(x-2)^{2}y^{'2} = 25 -(y-2)^{2}$
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Q82 mcq
Let $I =\int _{0}^{1} \frac{sin x}{\sqrt{x}}dx$ and $J =\int _{0}^{1} \frac{cos x}{\sqrt{x}} dx$ . Then which one of the following is true?
a.
$I > \frac{2}{3}$ and $J > 2$
b.
$I < \frac{2}{3}$ and $J < 2$
c.
$I < \frac{2}{3}$ and $J > 2$
d.
$I > \frac{2}{3}$ and $J < 2$
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Q83 mcq
Let $A$ be a square matrix all of whose entries are integers. Then which one of the following is true?
a.
If $detA= \pm 1$ , then $A^{-1}$ exists but all its entries are not necessarily integers
b.
If $detA\neq \pm 1$ , then $A^{-1}$ exists and all its entries are non-integers
c.
If $detA= \pm 1$ , then $A^{-1}$ exists and all its entries are integers
d.
If $detA= \pm 1$ , then $A^{-1}$ need not exist
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Q84 mcq
The vector $\vec{a}=\alpha \hat{i}+ 2\hat{j}+\beta \hat{k}$ lies in the plane of the vectors $\vec{b}= \hat{i}+ \hat{j}$ and $\vec{c}= \hat{j}+ \hat{k}$ and bisects the angle between $\vec{b}$ and $\vec{c}$ . Then which one of the following gives possible values of $\alpha$ and $\beta$ ?
a.
$\alpha = 2,\beta = 2$
b.
$\alpha = 1,\beta = 2$
c.
$\alpha = 2,\beta = 1$
d.
$\alpha = 1,\beta = 1$
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Q85 mcq
The mean of the numbers $a,b, 8, 5, 10$ is 6 and the variance is $6.80$ . Then which one of the following gives possible values of $a$ and $b$ ?
a.
$a= 0,b= 7$
b.
$a= 5,b= 2$
c.
$a= 1,b= 6$
d.
$a= 3,b= 4$
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Q86 mcq
The conjugate of a complex number is $\frac{1}{i-1}$ . Then the complex number is
a.
$\frac{-1}{i-1}$
b.
$\frac{1}{i+1}$
c.
$\frac{-1}{i+1}$
d.
$\frac{1}{i-1}$
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Q87 mcq
The area of the plane region bounded by the curves $x+ 2y^{2} = 0$ and $x+ 3y^{2} = 1$ is equal to
a.
$\frac{5}{3}$
b.
$\frac{1}{3}$
c.
$\frac{2}{3}$
d.
$\frac{4}{3}$
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Q88 mcq
It is given that the events $A$ and $B$ are such that $P(A) = \frac{1}{4} ,P(\frac{A}{B})= \frac{1}{2}$ and $P(\frac{B}{A} )= \frac{2}{3}$ . Then $P(B)$ is
a.
$\frac{1}{6}$
b.
$\frac{1}{3}$
c.
$\frac{2}{3}$
d.
$\frac{1}{2}$
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Q89 mcq
How many different words can be formed by jumbling the letters in the word MISSISSIPPI in which no two $S$ are adjacent?
a.
$8 \cdot ^{6}C_{4}\cdot ^{7}C_{4}$
b.
$6.8 \cdot ^{7}C_{4}$
c.
$6 \cdot 7 \cdot ^{8}C_{4}$
d.
$7 \cdot ^{6}C_{4}\cdot ^{8}C_{4}$
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Q90 mcq
A parabola has the origin as its focus and the line $x= 2$ as the directrix. Then the vertex of the parabola is at
a.
$(0, 2)$
b.
$(1, 0)$
c.
$(0, 1)$
d.
$(2, 0)$
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Q91 mcq
$|| ||$ $|| ||$ The line passing through the points $(5, 1,a)$ and $(3,b, 1)$ crosses the $yz-$ plane at the point $(0, \frac{17}{2}, \frac{-13}{2})$ . Then
a.
$a= 2,b= 8$
b.
$a= 4,b= 6$
c.
$a= 6,b= 4$
d.
$a= 8,b= 2$
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Q92 mcq
The perpendicular bisector of the line segment joining $P(1, 4)$ and $Q(k, 3)$ has $y$ -intercept - 4. Then a possible value of $k$ is
a.
1
b.
2
c.
$-2$
d.
$-4$
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Q93 mcq
If the straight lines $\frac{x-1}{k} = \frac{y-2}{2} = \frac{z-3}{3}$ and $\frac{x-2}{3} = \frac{y-3}{k} = \frac{z-1}{2}$ intersect at a point, then the integer $k$ is equal to
a.
$-5$
b.
5
c.
2
d.
$-2$
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Q94 mcq
Let $R$ be the real line. Consider the following subsets of the plane $R\times R$ . $S = {(x,y) :y=x+ 1$ and $0 <x< 2},T = {(x,y) :x- y$ is an integer $}$ . Which one of the following is true?
a.
neither $S$ nor $T$ is an equivalence relation on $R$
b.
both $S$ and $T$ are equivalence relations on $R$
c.
$S$ is an equivalence relation on $R$ but $T$ is not
d.
$T$ is an equivalence relation on $R$ but $S$ is not
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Q95 mcq
Statement-1: $\sum ^{n}_{r=0}(r+ 1)^{n}C_{r} = (n+ 2)2^{n-1}$ Statement -2: $\sum ^{n}_{r=0}(r+ 1)^{n}C_{r}x^{r} = (1 +x)^{n}+nx(1 +x)^{n-1}$ .
a.
Statement $-1$ is false, Statement $-2$ is true
b.
Statement $-1$ is true, Statement $-2$ is true, Statement $-2$ is a correct explanation for Statement $-1$
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement $-1$ .
d.
Statement $-1$ is true, Statement $-2$ is false.
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Q96 mcq
The statement $p\rightarrow (\rightarrow q\rightarrow \rightarrow p)$ is equivalent to
a.
$p\rightarrow (\rightarrow p\rightarrow \rightarrow q)$
b.
$p\rightarrow (\rightarrow p\vee q)$
c.
$p\rightarrow (\rightarrow p\wedge q)$
d.
$p\rightarrow (\rightarrow p\leftrightarrow q)$
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Q97 mcq
Let $p$ be the statement " $x$ is an irrational number", $q$ be the statement " $y$ is a transcendental number", and $r$ be the statement " $x$ is a rational number iff $y$ is a transcendental number". Statement $-1$ : $r$ is equivalent to either $q$ or $p$ Statement $-2 :r$ is equivalent to $\sim (p\leftrightarrow \sim q)$ .
a.
Statement $-1$ is false, Statement $-2$ is true
b.
Statement $-1$ is true, Statement $-2$ is true, Statement $-2$ is a correct explanation for Statement $-1$
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement $-1$ .
d.
Statement $-1$ is true, Statement $-2$ is false.
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Q98 mcq
The value of $\sqrt{2}\int \frac{sinxdx}{sin(x-^{\pi }_{4})}$ is
a.
$x+ log cos(x- \frac{\pi}{4}) +c$
b.
$x-log sin(x- \frac{\pi}{4}) +c$
c.
$x+ log sin(x- \frac{\pi}{4}) +c$
d.
$x-log cos(x- \frac{\pi}{4}) +c$
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Q99 mcq
Let $f :N Y$ be a function defined as $f(x) = 4x+ 3$ , where $Y = {y\in N :y= 4x+ 3$ for some $x\in N}$ . Show that $\vec{f}$ is invertible and its inverse is
a.
$g(y) = \frac{3y+4}{3}$
b.
$g(y) = 4 + \frac{y+3}{4}$
c.
$g(y) = \frac{y+3}{4}$
d.
$g(y) = \frac{y-3}{4}$
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Q100 mcq
The quadratic equations $x^{2} -6x+a= 0$ and $x^{2} - cx+ 6 = 0$ have one root in common. The other roots of the first and second equations are integers in the ratio $4 : 3$ . Then the common root is
a.
1
b.
4
c.
3
d.
2
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Q101 mcq
The solution of the differential equation $\frac{dy}{dx} = \frac{x+y}{x}$ satisfying the condition $y(1) = 1$ is
a.
$y= lnx+x$
b.
$y=xlnx+x^{2}$
c.
$y=xe^{(x-1)}$
d.
$y=xlnx+x$
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Q102 mcq
The non-zero verctors $\vec{a}, \vec{b}$ and $\vec{c}$ are related by $\vec{a}= 8\vec{b}$ and $\vec{c}= -7\vec{b}$ . Then the angle between $\vec{a}$ and $\vec{c}$ is
a.
0
b.
$\pi /4$
c.
$\pi /2$
d.
$\pi$
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Q103 mcq
A die is thrown. Let $A$ be the event that the number obtained is greater than 3 . Let $B$ be the event that the number obtained is less than 5 . Then $P(A\cup B)$ is
a.
$\frac{3}{5}$
b.
0
c.
1
d.
$\frac{2}{5}$
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Q104 mcq
Statement - 1: For every natural number $n\geq 2, \frac{1}{\sqrt{1}} + \frac{1}{\sqrt{2}} + … + \frac{1}{\sqrt{n}} > \sqrt{n}$ . Statement $-2$ : For every natural number $n\geq 2,\sqrt{n(n+ 1)}<n+ 1$ .
a.
Statement $-1$ is false, Statement $-2$ is true
b.
Statement $-1$ is true, Statement $-2$ is true, Statement $-2$ is a correct explanation for Statement $-1$
c.
Statement $-1$ is true, Statement $-2$ is true; Statement $-2$ is not a correct explanation for Statement $-1$ .
d.
Statement $-1$ is true, Statement $-2$ is false.
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Q105 mcq
Let $a,b,c$ be any real numbers. Suppose that there are real numbers $x,y,z$ not all zero such that $x=$ $cy+bz,y=az+cx$ and $z=bx+ay$ . Then $a^{2} +b^{2} +c^{2} + 2abc$ is equal to
a.
2
b.
$-1$
c.
0
d.
1
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