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JEE Main 2007

2007 · 120 questions · First 10 Solutions Free
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Q1 mcq
An electric charge $10^{-3}\mu C$ is placed at the origin $(0, 0)$ of $X- Y$ co-ordinate system. Two points $A$ and $B$ are situated at $(\sqrt{2}, \sqrt{2})$ and $(2, 0)$ respectively. The potential difference between the points $A$ and $B$ will be
a.
$9\,volt$
b.
zero Correct Answer
c.
$2\,volt$
d.
$4.5\,volt$

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Q2 mcq
Charges are placed on the vertices of a square as shown. Let $E$ be the electric field and $V$ the potential at the centre. If the charges on $A$ and $B$ are interchanged with those on $D$ and $C$ respectively, then
a.
$\vec{E}$ remains unchanged, $V$ changes
b.
Both $\vec{E}$ and $V$ change
c.
$\vec{E}$ and $V$ remains unchanged
d.
$\vec{E}$ changes, $V$ remains unchanged Correct Answer

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Q3 mcq
Which of the following transitions in hydrogen atoms emit photons of highest frequency?
a.
$n= 2$ to $n= 6$
b.
$n= 6$ to $n= 2$
c.
$n= 2$ to $n= 1$ Correct Answer
d.
$n= 1$ to $n= 2$

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Q4 mcq
Two springs, of force constants $k_{1}$ and $k_{2}$ , are connected to a mass $m$ as shown. The frequency of oscillation of the mass is $f$ . If both $k_{1}$ and $k_{2}$ are made four times their original values, the frequency of oscillation becomes
Question 4 image
a.
$f/2$
b.
$f/4$
c.
$4f$
d.
$2f$ Correct Answer

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Q5 mcq
Two lenses of power $-15\,D$ and $+5\,D$ are in contact with each other. The focal length of the combination is
a.
$-20\,cm$
b.
$-10\,cm$ Correct Answer
c.
$+20\,cm$
d.
$+10\,cm$

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Q6 mcq
If $M_{o}$ is the mass of an oxygen isotope $_{8}O^{17}, M_{p}$ and $M_{N}$ are the masses of a proton and a neutron respectively, the nuclear binding energy of the isotope is
a.
$(M_{o}-8M_{p})C^{2}$
b.
$(M_{o}-8M_{p}-9M_{N})C^{2}$ Correct Answer
c.
$M_{o}C^{2}$
d.
$(M_{o}-17M_{N})C^{2}$

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Q7 mcq
An ideal coil of $10H$ is connected in series with a resistance of $5\Omega$ and a battery of $5\,V$ . $2$ second after the connection is made the current flowing in amperes in the circuit is
a.
$(1 -e)$
b.
$e$
c.
$e^{-1}$
d.
$(1 -e^{-1})$ Correct Answer

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Q8 mcq
The displacement of an object attached to a spring and executing simple harmonic motion is given by $x= 2 \times 10^{-2} cos\pi t$ metres. The time at which the maximum speed first occurs is
a.
$0.5\,s$ Correct Answer
b.
$0.75\,s$
c.
$0.125\,s$
d.
$0.25\,s$

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Q9 mcq
A body weighing $13\,kg$ is suspended by two strings $5\,m$ and $12\,m$ long, their other ends being fastened to the extremities of a rod $13\,m$ long. If the rod be so held that the body hangs immediately below the middle point. The tensions in the strings are
a.
$12\,kg$ and $13\,kg$
b.
$5\,kg$ and $5\,kg$
c.
$5\,kg$ and $12\,kg$ Correct Answer
d.
$5\,kg$ and $13\,kg$

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Q10 mcq
A charged particle moves through a magnetic field perpendicular to its direction. Then
a.
the momentum changes but the kinetic energy is constant Correct Answer
b.
both momentum and kinetic energy of the particle are not constant
c.
both, momentum and kinetic energy of the particle are constant
d.
kinetic energy changes but the momentum is constant

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Q11 mcq
In an a.c. circuit the voltage applied is $E = E_{0}sin\omega t$ . The resulting current in the circuit is $I = I_{0}sin(\omega t - \frac{\pi}{2})$ . The power consumption in the circuit is given by
a.
$P = \frac{E_{0}I_{0}}{\sqrt{2}}$
b.
$P =$ zero
c.
$P = \frac{E_{0}I_{0}}{2}$
d.
$P\sqrt{2}E_{0}I_{0}$
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Q12 mcq
For the given uniform square lamina $ABCD$ , whose centre is $O$ ,
a.
$\sqrt{2I}_{AC} = I_{EF}$
b.
$I_{AD} = 3I_{EF}$
c.
$I_{AC} = I_{EF}$
d.
$I_{AC} = \sqrt{2}I_{EF}$
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Q13 mcq
A parallel plate condenser with a dielectric of dielectric constant $K$ between the plates has a capacity $C$ and is charged to a potential $\,V\,volts$ . The dielectric slab is slowly removed from between the plates and then reinserted. The net work done by the system in this process is
a.
$1/2(\,K -1)CV^{2}$
b.
$CV^{2}(\,K -1)/K$
c.
$(K -1)CV^{2}$
d.
zero
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Q14 mcq
A particle is projected at $60^{\circ }$ to the horizontal with a kinetic energy $K$ . The kinetic energy at the highest point is
a.
$K$
b.
Zero
c.
$K/2$
d.
$K/4$
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Q15 mcq
The resistance of a wire is $5\,ohm$ at $50^{\circ }C$ and $6\,ohm$ at $100^{\circ }C$ . The resistance of the wire at $0^{\circ }C$ will be
a.
$2\,ohm$
b.
$1\,ohm$
c.
$4\,ohm$
d.
$3\,ohm$
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Q16 mcq
A circular disc of radius $R$ is removed from a bigger circular disc of radius $2R$ such that the circumferences of the discs coincide. The centre of mass of the new disc is $\alpha /R$ from the centre of the bigger disc. The value of $\alpha$ is
a.
$1/3$
b.
$1/2$
c.
$1/6$
d.
$1/4$
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Q17 mcq
A point mass oscillates along the $x$ -axis according to the law $x = x_{0}cos(\omega t - \pi /4)$ . If the acceleration of the particle is written as $a = A cos(\omega t +\delta )$
a.
$A = x_{0},\delta = -\pi /4$
b.
$A = x_{0}\omega ^{2},\delta = -\pi /4$
c.
$A = x_{0}\omega ^{2},\delta = -\pi /4$
d.
$A = x_{0}\omega ^{2},\delta = 3\pi /4$
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Q18 mcq
The half-life period of a radio-active element $X$ is same as the mean life time of another radioactive element $Y$ . Initially they have the same number of atoms. Then
a.
$X$ will decay faster than $Y$
b.
$Y$ will decay faster than $X$
c.
$X$ and $Y$ have same decay rate initially
d.
$X$ and $Y$ decay at same rate always.
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Q19 mcq
In a Young's double slit experiment the intensity at a point where the path difference is $\frac{\lambda}{6}$ ( $\lambda$ being the wavelength of the light used) is $I$ . If $I_{0}$ denotes the maximum intensity, $\frac{I}{I_{0}}$ is equal to
a.
$\frac{1}{\sqrt{2}}$
b.
$\frac{\sqrt{3}}{2}$
c.
$1/2$
d.
$3/4$
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Q20 mcq
Photon of frequency $v$ has a momentum associated with it. If $c$ is the velocity of light, the momentum is
a.
$v/c$
b.
$hvc$
c.
$hv/c^{2}$
d.
$hv/c$
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Q21 mcq
A particle of mass $m$ executes simple harmonic motion with amplitude ' $a$ ' and frequency ' $v$ '. The average kinetic energy during its motion from the position of equilibrium to the end is
a.
$\pi ^{2}ma^{2}v^{2}$
b.
$\frac{1}{4}\pi ^{2}ma^{2}v^{2}$
c.
$4\pi ^{2}ma^{2}v^{2}$
d.
$2\pi ^{2}ma^{2}v^{2}$
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Q22 mcq
The potential at a point $x$ (measured in $\mu m$ ) due to some charges situated on the $x$ -axis is given by $V(x) = 20/(x^{2} -4)\,Volts$ . The electric field $E$ at $x = 4\,\mu m$ is given by
a.
$5/3\,Volt/\mu m$ and in the $-ve x$ direction
b.
$5/3\,Volt/\mu m$ and in the $+ve x$ direction.
c.
$10/9\,Volt/\mu m$ and in the $-ve x$ direction
d.
$10/9\,Volt/\mu m$ and in the $+ve x$ direction.
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Q23 mcq
A round uniform body of radius $R$ , mass $M$ and moment of inertia ' $I$ ', rolls down (without slipping) an inclined plane making an angle $\theta$ with the horizontal. Then its acceleration is
a.
$\frac{g sin\theta}{1+^{I}}$ $MR2$
b.
$\frac{g sin\theta}{1+^{MR2}}$ $I$
c.
$\frac{g sin\theta}{1-^{I}}$ $MR2$
d.
$\frac{g sin\theta}{1-^{MR2}}$ $I$
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Q24 mcq
A battery is used to charge a parallel plate capacitor till the potential difference between the plates becomes equal to the electromotive force of the battery. The ratio of the energy stored in the capacitor and the work done by the battery will be
a.
$1$
b.
$2$
c.
$\frac{1}{4}$
d.
$\frac{1}{2}$
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Q25 mcq
A particle just clears a wall of height $b$ at distance $a$ and strikes the ground at a distance $c$ from the point of projection. The angle of projection is
a.
$tan^{-1} \frac{b}{ac}$
b.
$45^{\circ }$
c.
$tan^{-1} \frac{bc}{a(c-a)}$
d.
$tan^{-1} \frac{bc}{a}$
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Q26 mcq
The velocity of a particle is $v = v_{0}+ gt + ft$ . If its position is $x = 0$ at $t = 0$ , then its displacement after unit time $(t= 1)$ is
a.
$v_{0}+ 2g + 3f$
b.
$v_{0}+ g/2 + f/3$
c.
$v_{0}+ g + f$
d.
$v_{0}+ g/2 + f$
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Q27 mcq
A charged particle with charge $q$ enters a region of constant, uniform and mutually orthogonal fields $\vec{E}$ and $\vec{B}$ witha velocity $\vec{v}$ perpendicular to both $\vec{E}$ and $\vec{B}$ , and comes out without any change in magnitude or direction of $\vec{v}$ . Then
a.
$\vec{v}= \vec{E}\times \vec{B}/B^{2}$
b.
$\vec{v}= \vec{B}\times \vec{E}/B^{2}$
c.
$\vec{v}= \vec{E}\times \vec{B}/E^{2}$
d.
$\vec{v}= \vec{B}\times \vec{E}/E^{2}$
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Q28 mcq
A sound absorber attenuates the sound level by $20\,dB$ . The intensity decreases by a factor of
a.
$1000$
b.
$10000$
c.
$10$
d.
$100$
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Q29 mcq
Angular momentum of the particle rotating with a central force is constant due to
a.
Constant Force
b.
Constant linear momentum.
c.
Zero Torque
d.
Constant Torque
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Q30 mcq
A current $I$ flows along the length of an infinitely long, straight, thin walled pipe. Then
a.
the magnetic field is zero only on the axis of the pipe
b.
the magnetic field is different at different points inside the pipe
c.
the magnetic field at any point inside the pipe is zero
d.
the magnetic field at all points inside the pipe is the same, but not zero
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Q31 mcq
If $C_{p}$ and $C_{v}$ denote the specific heats of nitrogen per unit mass at constant pressure and constant volume respectively, then
a.
$C_{p}-C_{v} = R/28$
b.
$C_{p}-C_{v} = R/14$
c.
$C_{p}-C_{v} = R$
d.
$C_{p}-C_{v} = 28R$
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Q32 mcq
Two identical conducting wires $AOB$ and $COD$ are placed at right angles to each other. The wire $AOB$ carries an electric current $I_{1}$ and $COD$ carries a current $I_{2}$ . The magnetic field on a point lying at a distance ' $d$ ' from $O$ , in a direction perpendicular to the plane of the wires $AOB$ and $COD$ , will be given by
a.
$1/2$ $\frac{\mu _{0}}{2\pi}(\frac{I+I}{d}^{1}^{2} )$
b.
$\frac{\mu _{0}}{2\pi d}(I^{2}_{1} + I^{2}_{2})^{1/2}$
c.
$\frac{\mu _{0}}{2\pi d}(I_{1}+ I_{2})$
d.
$\frac{\mu _{0}}{2\pi d}(I^{2}_{1} + I^{2}_{2})$
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Q33 mcq
A block of mass ' $m$ ' is connected to another block of mass ' $M$ ' by a spring (massless) of spring constant ' $k$ '. The blocks are kept on a smooth horizontal plane. Initially the blocks are at rest and the spring is unstretched. Then a constant force ' $F$ ' starts acting on the block of mass ' $M$ ' to pull it. Find the force on the block of mass ' $m$ '
a.
$\frac{mF}{M}$
b.
$\frac{(M+m)F}{m}$
c.
$\frac{mF}{(m+M)}$
d.
$\frac{MF}{(m+M)}$
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Q34 mcq
In gamma ray emission from a nucleus
a.
both the neutron number and the proton number change
b.
there is no change in the proton number and the neutron number.
c.
only the neutron number changes
d.
only the proton number changes
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Q35 mcq
A Carnot engine, having an efficiency of $\eta = 1/10$ as heat engine, is used as a refrigerator. If the work done on the system is $10\,J$ , the amount of energy absorbed from the reservoir at lower temperature is
a.
$99\,J$
b.
$90\,J$
c.
$1\,J$
d.
$100\,J$
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Q36 mcq
One end of a thermally insulated rod is kept at a temperature $T_{1}$ and the other at $T_{2}$ . The rod is composed of two sections of lengths $\ell _{1}$ and $\ell _{2}$ and thermal conductivities $k_{1}$ and $k_{2}$ respectively. The temperature at the interface of the two sections is
Question 36 image
a.
$(k_{2}\ell _{2}T_{1}+ k_{1}\ell _{1}T_{2})/ (k_{1}\ell _{1}+ k_{2}\ell _{2})$
b.
$(k_{2}\ell _{1}T_{1}+ k_{1}\ell _{1}T_{2})/ (k_{2}\ell _{1}+ k_{1}\ell _{2})$
c.
$(k_{1}\ell _{2}T_{1}+ k_{2}\ell _{1}T_{2})/ (k_{1}\ell _{2}+ k_{2}\ell _{1})$
d.
$(k_{1}\ell _{1}T_{1}+ k_{2}\ell _{2}T_{2})/ (k_{1}\ell _{1}+ k_{2}\ell _{2})$
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Q37 mcq
If $g_{E}$ and $g_{m}$ are the accelerations due to gravity on the surfaces of the earth and the moon respectively and if Millikan's oil drop experiment could be performed on the two surfaces, one will find the ratio $\frac{\,electronic charge on the moon\,}{\,electronic charge on the earth\,}$ to be
a.
$1$
b.
$0$
c.
$g_{E}/g_{m}$
d.
$g_{m}$ / $g_{E}$
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Q38 mcq
A long straight wire of radius ' $a$ ' caries a steady current $i$ . The current is uniformly distributed across its cross section. The ratio of the magnetic field at $\frac{a}{2}$ and $2a$ is
a.
$\frac{1}{4}$
b.
$4$
c.
$1$
d.
$\frac{1}{2}$
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Q39 mcq
A $2\,kg$ block slides on a horizontal floor with a speed of $4\,m/s$ . It strikes a uncompressed spring, and compresses it till the block is motionless. The kinetic friction force is $15\,N$ and spring constant is $10, 000. N/m$ . The spring compresses by
a.
$5.5\,cm$
b.
$2.5\,cm$
c.
$11.0\,cm$
d.
$8.5\,cm$
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Q40 mcq
When a system is taken from state $i$ to state $f$ along the path $iaf$ , it is found that $Q= 50\,cal$ and $W = 20\,cal$ . Along the path' $ibf Q = 36\,cal$ . $W$ along the path $ibf$ is
Question 40 image
a.
$6\,cal$
b.
$16\,cal$ .
c.
$66\,cal$ .
d.
$14\,cal$ .
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Q41 mcq
Which of the following sets of quantum numbers represents the highest energy of an atom?
a.
$n = 3, \,l = 2, \,m = 1, \,s = +1/2$
b.
$n = 3, \,l = 2, \,m = 1, \,s = +1/2$
c.
$n = 4, \,l = 0, \,m = 0, \,s = +1/2$
d.
$n = 3, \,l = 0, \,m = 0, \,s = +1/2$
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Q42 mcq
The IUPAC name of is
a.
$1, 1-$ diethyl $-2, 2-$ dimethylpentane
b.
$4, 4-$ dimethyl $-5, 5-$ diethylpentane
c.
$5, 5-$ diethyl $-4, 4-$ diemthylpentane
d.
$3-$ ethyl $-4, 4-$ dimethylheptane
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Q43 mcq
A $5.25%$ solution of a substance is isotonic with a $1.5%$ solution of urea $($ molar mass $= 60\,g\,mol^{-1}$ ) in the same solvent. If the densities of both the solutions are assumed to be equal to $1.0\,g\,cm^{-3}$ , molar mass of the substance will be
a.
$90.0\,g\,mol^{-1}$
b.
$115.0\,g\,mol^{-1}$
c.
$105.0\,g\,mol^{-1}$
d.
$210.0\,g\,mol^{-1}$
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Q44 mcq
Which of the following is the correct order of decreasing $SN^{2}$ reactivity?
a.
$RCH_{2}X > R_{3}CX > R_{2}CHX$
b.
$RCH_{2}X > R_{2}CHX > R_{3}CX$
c.
$R_{3}CX > R_{2}CHX > RCH_{2}X$
d.
$R_{2}CHX > R_{3}CX > RCH_{2}X (X =$ a halogen $)$
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Q45 mcq
$||$ The actinoids exhibits more number of oxidation states in general than the lanthanoids. This is because
a.
the $5f$ orbitals are more buried than the $4f$ orbitals
b.
there is a similarity between $4f$ and $5f$ orbitals in their angular part of the wave function
c.
the actinoids are more reactive than the lanthanoids
d.
the $5f$ orbitals extend further from the nucleus than the $4f$ orbitals
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Q46 mcq
If in a $p -n$ junction diode, a square input signal of $10\,V$ is applied as shown Then the output signal across $R_{L}$ will be
Question 46 image
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Q47 mcq
Regular use of which of the following fertilizer increases the acidity of soil?
a.
Potassium nitrate
b.
Urea
c.
Superphosphate of lime
d.
Ammonium sulphate
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Q48 mcq
In which of the following ionization processes, the bond order has increased and the magnetic behaviour has changed?
a.
$C_{2} \longrightarrow C^{+}_{2}$
b.
$NO\longrightarrow NO^{+}$
c.
$O_{2} \longrightarrow O^{+}_{2}$
d.
$N_{2} \longrightarrow N^{+}_{2}$
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Q49 mcq
The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizinig order of the polarizing power of the cationic species, $K^{+}, Ca^{2+}, Mg^{2+}, Be^{2+}$ ?
a.
$Mg^{2+}, Be^{2+}, K^{+}, Ca^{2+}$
b.
$Be^{2+}, K^{+}, Ca^{2+}, Mg^{2+}$
c.
$K^{+}, Ca^{2+}, Mg^{2+}, Be^{2+}$
d.
$Ca^{2+}, Mg^{2+}, Be^{2+}, K^{+}$
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Q50 mcq
The reaction of toluene with $Cl_{2}$ in presence of $FeCl_{3}$ gives predominantly
a.
benzoyl chloride
b.
benzyl chloride
c.
$o-$ and $p-$ chlorotoluene
d.
$m-$ chlorotoluene
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Q51 mcq
Consider the reaction, $2A + B \rightarrow \rightarrow$ Products When concentration of $B$ alone was doubled, the half-life did not change. When the concentration of $A$ alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is
a.
$L\,mol^{-1}\,s^{-1}$
b.
no unit
c.
$mol\,L^{-1}\,s^{-1}$
d.
$s^{-1}$
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Q52 mcq
In the following sequence of reactions, the compound ' $D$ ' is
a.
butanal
b.
$n-$ butyl alcohol
c.
$n-$ propyl alcohol
d.
propanal
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Q53 mcq
Assuming that water vapour is an ideal gas, the internal energy $(\Delta U)$ when $1\,mol$ of water is vapourised at $1\,bar$ pressure and $100^{\circ }C$ , (Given: Molar enthalpy of vapourization of water at $1\,bar$ and $373\,K = 41\,kJ\,mol^{-1}$ and $R = 8.3\,J\,mol^{-1}\,K^{-1}$ ) will be
a.
$4.100\,kJ\,mol^{-1}$
b.
$3.7904\,kJ\,mol^{-1}$
c.
$37.904\,kJ\,mol^{-1}$
d.
$41.00\,kJ\,mol^{-1}$
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Q54 mcq
In the chemical reaction, $CH_{3}CH_{2}NH_{2}-CHCl_{3}+ 3KOH\longrightarrow (A) + (B) + 3H_{2}O$ , the compound $(A)$ and $(B)$ are respectively
a.
$C_{2}H_{5}CN$ and $3KCl$
b.
$CH_{3}CH_{2}CONH_{2}$ and $3KCl$
c.
$C_{2}H_{5}NC$ and $K_{2}CO_{3}$
d.
$C_{2}H_{5}NC$ and $3KCl$
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Q55 mcq
Which of the following molecules is expected to rotate the plane of plane polarized light?
Question 55 image
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Q56 mcq
Presence of a nitro group in a benzene ring
a.
activates the ring towards electrophilic substitution
b.
renders the ring basic
c.
deactivates the ring towards nucleophilic substitution
d.
deactivates the ring towards electrophilic substitution
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Q57 mcq
Which of the following species exhibits the diamagnetic behaviour?
a.
$O^{2-}_{2}$
b.
$O^{+}_{2}$
c.
$O_{2}$
d.
$NO$
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Q58 mcq
Identify the incorrect statement among the following
a.
Ozone reacts with $SO_{2}$ to give $SO_{3}$
b.
Silicon reacts with $NaOH_{(aq)\,}$ in the presence of air to give $Na_{2}SiO_{3}$ and $H_{2}O$
c.
$Cl_{2}$ reacts with excess of $NH_{3}$ to give $N_{2}$ and $HCl$
d.
$Br_{2}$ reacts with hot and strong $NaOH$ solution to give $NaBr, NaBrO_{4}$ and $H_{2}O$
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Q59 mcq
In a sautrated solution of the sparingly soluble strong electrolyte $AgIO_{3}$ (Molecular mass $= 283$ ) the equilibrium which sets in is $AgIO_{3(s)} \rightleftharpoons Ag^{+}_{(aq)} + IO^{-}_{3(aq)}$ If the solubility product constant $K_{sp}$ of $AgIO_{3}$ at a given temperature is $1.0 \times 10^{-8}$ , what is the mass of $AgIO_{3}$ contained in $100\,ml$ of its saturated solution?
a.
$28.3 \times 10^{-2}\,g$
b.
$2.83 \times 10^{-3}\,g$
c.
$1.0 \times 10^{-7}\,g$
d.
$1.0 \times 10^{-4}\,g$
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Q60 mcq
Identify the incorrect statement among the following
a.
$d-$ Block elements show irregular and erratic chemical properties among themselves
b.
$La$ and $Lu$ have partially filled $d$ orbitals and no other partially filled orbitals
c.
The chemistry of various lanthanoids is very similar
d.
$4f$ and $5f$ orbitals are equally shielded
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Q61 mcq
Identify the correct statement regarding a spontaneous process
a.
For a spontaneous process in an isolated system, the change in entropy is positive
b.
Endothermic processes are never spontaneous
c.
Exothermic processes are always spontaneous
d.
Lowering of energy in the reaction process is the only criterion for spontaneity
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Q62 mcq
The energies of activation for forward and reverse reactions for $A_{2}+B_{2} \rightleftharpoons 2AB$ are $180\,kJ\,mol^{-1}$ and $200\,kJ\,mol^{-1}$ respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by $100\,kJ\,mol^{-1}$ . The enthalpy change of the reaction $(A_{2}+ B_{2} \longrightarrow 2AB)$ in the presence of catalyst will be (in $kJ\,mol^{-1}$ )
a.
$300$
b.
$120$
c.
$280$
d.
$20$
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Q63 mcq
Which of the following reactions will yield $2, 2-$ dibromopropane?
a.
$CH_{3}-C \equiv CH + 2HBr\longrightarrow$
b.
$CH_{3}CH \equiv CHBr + HBr\longrightarrow$
c.
$CH \equiv CH + 2HBr\longrightarrow$
d.
$CH_{3}-CH = CH_{2}+ HBr\longrightarrow$
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Q64 mcq
The first and second dissociation constants of an acid $H_{2}A$ are $1.0 \times 10^{-5}$ and $5.0 \times 10^{-10}$ respectively. The overall dissociation constant of the acid will be
a.
$5.0 \times 10^{-5}$
b.
$5.0 \times 10^{15}$
c.
$5.0 \times 10^{-15}$
d.
$0.0 \times 10^{5}$
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Q65 mcq
Which one of the following conformation of cyclohexane is chiral?
a.
Twist boat
b.
Rigid
c.
Chair
d.
Boat
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Q66 mcq
In the reaction. $2Al_{(s)}+ 6HCl_{(s)} \longrightarrow 2Al^{3+}_{(aq)} + 6Cl^{-}_{(aq)} + 3H_{2(g),}$
a.
$6\,L\,HCl_{(aq)}$ is consumed for every $3\,L\,H_{2(g)}$ produced
b.
$33.6\,L\,H_{2(g)}$ is produced regardless of temperature and pressure for every mole $Al$ that reacts
c.
$67.2\,L\,H_{2(g)}$ at STP is produced for every mole $Al$ that reacts
d.
$11.2\,H_{2(g)}$ at STP is produced for every mole $HCl_{(aq)}$ consumed
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Q67 mcq
Which of the following nuclear reactions will generate an isotope?
a.
neutron particle emission
b.
positron emission
c.
$\alpha$ -particle emission
d.
$\beta$ -particle emission
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Q68 mcq
In conversion of lime-stone to lime, $CaCO_{3}(\,s)\longrightarrow CaO(s) + CO_{2}(\,g)$ the vales of $\Delta H^{\circ }$ and $\Delta S^{\circ }$ are $+179.1\,kJ\,mol^{-1}$ and $160.2\,J/K$ respectively at $298\,K$ and $1\,bar$ . Assuming that $\Delta H^{\circ }$ do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is
a.
$1008\,K$
b.
$1200$
c.
$845\,K$
d.
$1118\,K$
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Q69 mcq
The equivalent conductances of two strong electrolytes at infinite dilution in $H_{2}O$ (where ions move freely through a solution) at $25^{\circ }C$ are given below: $\wedge ^{\circ }CH_{3}COONa = 91.0\,S\,cm^{2}$ /equiv $\wedge ^{\circ }_{HCl} = 426.2\,S\,cm^{2}$ / equiv What additional information/quantity one needs to calculate $\wedge ^{\circ }$ of an aqueous solution of acetic acid?
a.
$\wedge ^{\circ }$ of $NaCl$
b.
$\wedge ^{\circ }$ of $CH_{3}COOK$
c.
The limiting equivalent conductance of $H^{+} (\wedge ^{\circ }_{H^{+}})$
d.
$\wedge ^{\circ }$ of chloroacetic acid $(C/CH_{2}COOH)$
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Q70 mcq
A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of $290\,mm$ at $300\,K$ . The vapour pressure of propyl alcohol is $200\,mm$ . If the mole fraction of ethyl alcohol is $0.6$ , its vapour pressure (in $mm$ ) at the same temperature will be
a.
$350$
b.
$300$
c.
$700$
d.
$360$
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Q71 mcq
Carbon, silicon and germanium have four valence electrons each. At room temperature which one of the following statements is most appropriate?
a.
The number of free conduction electrons is significant in $C$ but small in $Si$ and $Ge$ .
b.
The number of free conduction electrons is negligible small in all the three.
c.
The number of free electrons for conduction is significant in all the three.
d.
The number of free electrons for conduction is significant only in $Si$ and $Ge$ but small in $C$ .
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Q72 mcq
Equal masses of methane and oxygen are mixed in an empty container at $25^{\circ }C$ . The fraction of the total pressure exerted by oxygen is
a.
$\frac{2}{3}$
b.
$\frac{1}{3} \times \frac{273}{298}$
c.
$\frac{1}{3}$
d.
$\frac{1}{2}$
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Q73 mcq
The stability of dihalides of $Si, Ge, Sn$ and $Pb$ increases steadily in the sequence
a.
$GeX_{2} \ll SiX_{2} \ll SnX_{2} \ll PbX_{2}$
b.
$SiX_{2} \ll GeX_{2} \ll PbX_{2} \ll SnX_{2}$
c.
$SiX_{2} \ll GeX_{2} \ll SnX_{2} \ll PbX_{2}$
d.
$PbX_{2} \ll SnX_{2} \ll GeX_{2} \ll SiX_{2}$
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Q74 mcq
The compound formed as a result of oxidation of ethyl benzene by $KMnO_{4}$ is
a.
benzophenone
b.
acetophenone
c.
benzoic acid
d.
benzyl alcohol
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Q75 mcq
A radioactive element gets spilled over the floor of a room. Its half-life period is $30$ days. If the initial activity is ten times the permissible value, after how many days will it be safe to enter the room?
a.
$1000$ days
b.
$300$ days
c.
$10$ days
d.
$100$ days
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Q76 mcq
Which of the following hydrogen bonds is the strongest?
a.
$O -H … … N$
b.
$F -H … … F$
c.
$O -H … … . O$
d.
$O -H … … F$
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Q77 mcq
The $pKa$ of a weak acid $(HA)$ is $4.5$ . The $pOH$ of an aqueous buffered solution of $HA$ in which $50%$ of the acid is ionized is
a.
$4.5$
b.
$2.5$
c.
$9.5$
d.
$7.0$
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Q78 mcq
The density (in $g\,mL^{-1}$ ) of a $3.60\,M$ sulphuric acid solution that is $29%\,H_{2}SO_{4}$ (Molar mass $= 98\,g mol^{-1}$ ) by mass will be
a.
$1.64$
b.
$1.88$
c.
$1.22$
d.
$1.45$
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Q79 mcq
The cell, $Zn Zn^{2+}(1M)\parallel Cu^{2+}(1M) Cu(E^{0}_{cell\,} = 1.10\,V)$ , was allowed to be completely discharged at $298\,K$ . The relative concentration of $Zn^{2+}$ to $Cu^{2+} [\frac{[Zn^{2+}]}{[Cu^{2+}]} ]$ is
a.
antilog $(24.08)$
b.
$37.3$
c.
$10^{37.3}$
d.
$9.65 \times 10^{4}$
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Q80 mcq
Which one of the following has a square planar geometry?
a.
$[CoCl_{4}]^{2-}$
b.
$[FeCl_{4}]^{2-}$
c.
$[NiCl_{4}]^{2-}$
d.
$[PtCl_{4}]^{2-}$
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Q81 mcq
$1 1 1$ If $D= 1 1 +x 1$ for $x\neq 0,y\neq 0$ then $D$ is $1 1 1 +y$
a.
divisible by neither $x$ nor $y$
b.
divisible by both $x$ and $y$
c.
divisible by $x$ but not $y$
d.
divisible by $y$ but not $x$
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Q82 mcq
If $\hat{u}$ and $\hat{v}$ are unit vectors and $\theta$ is the acute angle between them, then $2\hat{u}\times 3\hat{v}$ is a unit vector for
a.
exactly two values of $\theta$
b.
more than two values of $\theta$
c.
no value of $\theta$
d.
exactly one value of $\theta$
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Q83 mcq
The function $f :R\sim {0} \rightarrow \rightarrow R$ given by $f(x) = \frac{1}{x} - \frac{2}{e^{2}^{x}-1}$ can be made continuous at $x= 0$ by defining $f(0)$ as
a.
$2$
b.
$-1$
c.
$0$
d.
$1$
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Q84 mcq
The function $f(x) = tan^{-1}(sinx+ cosx)$ is an increasing function in
a.
$( \frac{\pi}{4} , \frac{\pi}{2} )$
b.
$(-\frac{\pi}{2}, \frac{\pi}{4})$
c.
$(0, \frac{\pi}{2} )$
d.
$(-\frac{\pi}{2}, \frac{\pi}{2})$
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Q85 mcq
In a geometric progression consisting of positive terms, each term equals the sum of the next two terms. Then the common ratio of this progression equals
a.
$\frac{1}{2}(1 -)\sqrt{5}$
b.
$\frac{1}{2}\sqrt{5}$
c.
$\sqrt{5}$
d.
$\frac{1}{2}( -1)\sqrt{5}$
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Q86 mcq
The largest interval lying in $(-\frac{\pi}{2}, \frac{\pi}{2})$ for which the function $[f(x) = 4^{-x^{2}} + cos^{-1} ( \frac{x}{2} -1)+ log(cosx)]$ is defined, is
a.
$[0,\pi ]$
b.
$(-\frac{\pi}{2}, \frac{\pi}{2})$
c.
$[-\frac{\pi}{4} , \frac{\pi}{2} )$
d.
$[0, \frac{\pi}{2})$
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Q87 mcq
Two aeroplanes I and II bomb a target in succession. The probabilities of I and II scoring a hit correctly are $0.3$ and $0.2$ , respectively. The second plane will bomb only if the first misses the target. The probability that the target is hit by the second plane is
a.
$0.06$
b.
$0.14$
c.
$0.2$
d.
None of these
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Q88 mcq
$|$ $| |$ If $sin^{-1} (\frac{x}{5})+ cosec^{-1}(\frac{5}{4} )= \frac{\pi}{2}$ then a value of $x$ is
a.
$1$
b.
$3$
c.
$4$
d.
$5$
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Q89 mcq
The secondary structure of a protein refers to
a.
$\alpha$ -helical backbone
b.
hydrophobic interactions
c.
sequence of $\alpha$ -amino acids
d.
fixed configuration of the polypeptide backbone
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Q90 mcq
The normal to a curve at $P(x,y)$ meets the $x$ -axis at $G$ . If the distance of $G$ from the origin is twice the abscissa of $P$ , then the curve is a
a.
ellipse
b.
parabola
c.
circle
d.
pair of straight lines
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Q91 mcq
If $p$ and $q$ are positive real numbers such that $p^{2} +q^{2} = 1$ , then the maximum value of $(p+q)$ is
a.
$2$
b.
$1/2$
c.
$\frac{1}{\sqrt{2}}$
d.
$\sqrt{2}$
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Q92 mcq
In the binomial expansion of $(a- b)^{n},n\geq 5$ , the sum of $5^{th\,}$ and $6^{th\,}$ terms is zero, then $\frac{a}{b}$ equals
a.
$\frac{5}{n-4}$
b.
$\frac{6}{n-5}$
c.
$\frac{n-5}{6}$
d.
$\frac{n-4}{5}$
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Q93 mcq
Consider a family of circles which are passing through the point $(-1, 1)$ and are tangent to $x-$ axis. If $(h,k)$ are the co-ordinates of the centre of the circles, then the set of values of $k$ is given by the interval
a.
$0 < k < 1/2$
b.
$k\geq 1/2$
c.
$-1/2 \leq k\leq 1/2$
d.
$k\leq 1/2$
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Q94 mcq
For the hyperbola $\frac{x^{2}}{cos^{2}\alpha} - \frac{y^{2}}{sin^{2}\alpha} = 1$ , which of the following remains constant when $\alpha$ varies?
a.
eccentricity
b.
directrix
c.
abscissae of vertices
d.
abscissae of foci
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Q95 mcq
The sum of the series $\frac{1}{2!} - \frac{1}{3!} + \frac{1}{4!} -…$ upto infinity is
a.
$e^{-2}$
b.
$e^{-1}$
c.
$e^{-1/2}$
d.
$e^{1/2}$
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Q96 mcq
Let $F(x) =f(x) +f(\frac{1}{x} )$ , where $f(x) =\int _{1}^{x} \frac{logt}{1+t} dt$ . Then $F(e)$ equals
a.
$\frac{1}{2}$
b.
$0$
c.
$1$
d.
$2$
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Q97 mcq
A pair of fair dice is thrown independently three times. The probability of getting a score of exactly $9$ twice is
a.
$1/729$
b.
$8/9$
c.
$8/729$
d.
$8/243$
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Q98 mcq
Let $f :R\rightarrow \rightarrow R$ be a function defined by $f(x) = Min{x+ 1, |x| + 1}$ . Then which of the following is true?
a.
$f(x) \geq 1$ for all $x\in R$
b.
$f(x)$ is not differentiable at $x= 1$
c.
$f(x)$ is differentiable everywhere
d.
$f(x)$ is not differentiable at $x= 0$
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Q99 mcq
If $|z+ 4| \leq 3$ , then the maximum value of $|z+ 1|$ is
a.
$4$
b.
$10$
c.
$6$
d.
$0$
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Q100 mcq
The area enclosed between the curves $y^{2} =x$ and $y= |x|$ is
a.
$2/3$
b.
$1$
c.
$1/6$
d.
$1/3$
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Q101 mcq
Which one of the following is the strongest base in aqueous solution?
a.
Trimethylamine
b.
Aniline
c.
Dimethylamine
d.
Methylamine
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Q102 mcq
Let $P = (-1, 0),Q= (0, 0)$ and $R= (3, 3)\sqrt{3}$ be three points. The equation of the bisector of the angle $PQR$
a.
$\sqrt{3}x+y= 0$
b.
$x+ \frac{\sqrt{3}}{2}y= 0$
c.
$\frac{\sqrt{3}}{2} x+y= 0$
d.
$x+ \sqrt{3}y= 0$
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Q103 mcq
A value of $C$ for which the conclusion of Mean Value Theorem holds for the function $f(x) = log_{e}x$ on the interval $[1, 3]$ is
a.
$2 log_{3}e$
b.
$\frac{1}{2}log_{e} 3$
c.
$log_{3}e$
d.
$log_{e}3$
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Q104 mcq
The resultant of two forces $P\,N$ and $3\,N$ is a force of $7\,N$ . If the direction of $3\,N$ force were reversed, the resultant would be $\sqrt{19}\,N$ . The value of $P$ is
a.
$5\,N$
b.
$6\,N$
c.
$3\,N$
d.
$4\,N$
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Q105 mcq
If one of the lines of $my^{2} +(1 - m^{2})xy- mx^{2} = 0$ is a bisector of the angle between the lines $xy= 0$ , then $m$ is
a.
$-1/2$
b.
$-2$
c.
$1$
d.
$2$
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Q106 mcq
$-$ Let $-a = \hat{i}+ \hat{j}+ \hat{k}, b = \hat{i}- \hat{j}+ 2\hat{k}$ and $-c = x\hat{i}+ (x -2)\hat{j}- \hat{k}$ . If the vector $-c$ lies in the plane of $a-$ and $-b$ , then $x$ equals
a.
$0$
b.
$1$
c.
$-4$
d.
$-2$
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Q107 mcq
Let $L$ be the line of intersection of the planes $2x+ 3y+z= 1$ and $x+ 3y+ 2z= 2$ . If $L$ makes an angles $\alpha$ with the positive $x$ -axis, then $cos\alpha$ equals
a.
$\frac{1}{\sqrt{3}}$
b.
$\frac{1}{2}$
c.
$1$
d.
$\frac{1}{\sqrt{2}}$
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Q108 mcq
If a line makes an angle of $\frac{\pi}{4}$ with the positive directions of each of $x$ -axis and $y$ -axis, then the angle that the line makes with the positive direction of the $z-$ axis is
a.
$\frac{\pi}{6}$
b.
$\frac{\pi}{3}$
c.
$\frac{\pi}{4}$
d.
$\frac{\pi}{2}$
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Q109 mcq
A tower stands at the centre of a circular park. $A$ and $B$ are two points on the boundary of the park such that $AB(=a)$ subtends an angle of $60^{\circ }$ at the foot of the tower, and the angle of elevation of the top of the tower from $A$ or $B$ is $30^{\circ }$ . The height of the tower is
a.
$\frac{2a}{\sqrt{3}}$
b.
$2a\sqrt{3}$
c.
$\frac{a}{\sqrt{3}}$
d.
$a\sqrt{3}$
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Q110 mcq
The sum of the series $^{20}C_{0}-^{20}C_{1}+^{20}C_{2}-^{20}C_{3}+ … -… +^{20}C_{10}\,is\,$
a.
$-^{20}C_{10}$
b.
$\frac{1}{2}^{20}C_{10}$
c.
$0$
d.
$^{20}C_{10}$
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Q111 mcq
The solution for $x$ of the equation $\int _{\sqrt{2}}^{x} \frac{dt}{t\sqrt{t^{2}-1}} = \frac{\pi}{2}$ is
a.
$2$
b.
$\pi$
c.
$\frac{\sqrt{3}}{2}$
d.
None of these
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Q112 mcq
$\int \frac{dx}{cosx+ sin\sqrt{3}x}$ equals
a.
$\frac{1}{2}log tan( \frac{x}{2} + \frac{\pi}{12} )+c$
b.
$\frac{1}{2}log tan( \frac{x}{2} - \frac{\pi}{12})+c$
c.
$log tan(\frac{x}{2} + \frac{\pi}{12} )+ c$
d.
$log tan(\frac{x}{2} - \frac{\pi}{12} )+ c$
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Q113 mcq
If $(2, 3, 5)$ is one end of a diameter of the sphere $x^{2} +y^{2} +z^{2} -6x-12y-2z+ 20 = 0$ , then the coordinates of the other end of the diameter are
a.
$(4, 9, -3)$
b.
$(4, -3, 3)$
c.
$(4, 3, 5)$
d.
$(4, 3, -3)$
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Q114 mcq
The equation of a tangent to the parabola $y^{2} = 8x$ is $y=x+ 2$ . The point on this line from which the other tangent to the parabola is perpendicular to the given tangent is
a.
$(-1, 1)$
b.
$(0, 2)$
c.
$(2, 4)$
d.
$(-2, 0)$
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Q115 mcq
$5 5\alpha \alpha$ $[ ]$ Let $A= 0 \alpha 5\alpha$ . If $A^{2} = 25$ , then $|\alpha |$ equals $[ ]$ $0 0 5$
a.
$5^{2}$
b.
$1$
c.
$1/5$
d.
$5$
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Q116 mcq
The average marks of boys in a class is $52$ and that of girls is $42$ . The average marks of boys and girls combined is $50$ . The percentage of boys in the class is
a.
$40$
b.
$20$
c.
$80$
d.
$60$
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Q117 mcq
Let $A(h,k),B(1, 1)$ and $C(2, 1)$ be the vertices of a right angled triangle with $AC$ as its hypotenuse. If the area of the triangle is $1$ , then the set of values which ' $k$ ' can take is given by
a.
${1, 3}$
b.
${0, 2}$
c.
${-1, 3}$
d.
${-3, -2}$
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Q118 mcq
The differential equation of all circles passing through the origin and having their centres on the $x$ -axis is
a.
$x^{2} =y^{2} +xy\frac{dy}{dx}$
b.
$x^{2} =y^{2} + 3xy\frac{dy}{dx}$
c.
$y^{2} =x^{2} + 2xy \frac{dy}{dx}$
d.
$y^{2} =x^{2} -2xy\frac{dy}{dx}$
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Q119 mcq
The set $S = {1, 2, 3, … , 12)$ is to be partitioned into three sets $A,B,C$ of equal size. Thus, $A\cup B\cup C =S,A\cap B=B\cap C =A\cap C =\phi$ . The number of ways to partition $S$ is
a.
$\frac{12!}{3!(4!)^{3}}$
b.
$\frac{12!}{3!(3!)^{4}}$
c.
$\frac{12!}{(4!)^{3}}$
d.
$\frac{12!}{(3!)^{4}}$
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Q120 mcq
If the difference between the roots of the equation $x^{2} +ax+ 1 = 0$ is less than $\sqrt{5}$ , then the set of possible values of $a$ is
a.
$(-3, 3)$
b.
$(-3, \infty )$
c.
$(3, \infty )$
d.
$(-\infty , -3)$
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